ChemicalBook >> CAS DataBase List >>1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- CAS No.
- 54125-02-9
- Chemical Name:
- 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- Synonyms
- DK814;DANISHEFSKY'S DIENE;Danishefsky-Kitahara diene.;1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE;TRANS-1-METHOXY-3-TRIMETHYLSILOXY- &;1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE;1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE;1-Methoxy-3-trimethylsiloxy-1,3-butadiene ,95%;1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE, 98+%;TRANS-1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
- CBNumber:
- CB2162111
- Molecular Formula:
- C8H16O2Si
- Molecular Weight:
- 172.3
- MDL Number:
- MFCD00008498
- MOL File:
- 54125-02-9.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Boiling point | 68-69 °C/14 mmHg (lit.) |
|---|---|
| Density | 0.885 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 113 °F |
| storage temp. | 2-8°C |
| Specific Gravity | 0.89 |
| Water Solubility | Miscible with most organic solvents. Immiscible with water. |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Moisture Sensitive |
| Merck | 14,6001 |
| BRN | 1616761 |
| CAS DataBase Reference | 54125-02-9(CAS DataBase Reference) |
| FDA UNII | 1ZOR63U51O |
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 212830 | trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95% | 54125-02-9 | 1g | $59.9 | 2024-03-01 | Buy |
| Sigma-Aldrich | 212830 | trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene 95% | 54125-02-9 | 5g | $190 | 2024-03-01 | Buy |
| Alfa Aesar | L06100 | 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 94% | 54125-02-9 | 1g | $46.65 | 2024-03-01 | Buy |
| Alfa Aesar | L06100 | 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 94% | 54125-02-9 | 5g | $174 | 2024-03-01 | Buy |
| Alfa Aesar | L14672 | 1-Methoxy-3-trimethylsiloxy-1,3-butadiene, 96% | 54125-02-9 | 1g | $66.65 | 2024-03-01 | Buy |
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Chemical Properties,Uses,Production
Uses
1-Methoxy-3-trimethylsiloxy-1,3-butadiene is employed as a reagent in Mannich-Michael reaction for the synthesis of piperidinones and enaminones. As Diels-Alder diene, it is used in the synthesis of pyridones and pyranones, sulfone analogues of griseofulvin (sulfogriseofulvins) and 4H-1-aminopyrroles and 4, 5H-pyrazoles.
General Description
trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene is a funtionalized Diels-Alder diene. Mukaiyama-Michael-type addition/heterocyclization of trans-1-methoxy-3-trimethylsiloxy-1,3-butadiene (Danishefsky′s diene) with 1,2-diaza-1,3-butadiene has been investigated. Asymmetric hetero-Diels-Alder cyclization of Danishefsky′s diene with benzaldehyde catalyzed by mesoporous inorganic/metalorganic hybrid materials has been reported.
Purification Methods
It may contain up to 1% of the precursor 4-methoxybut-4-ene-2-one. It is easily purified by distilling through a Vigreux column (p 11) in a vacuum and taking the middle fraction. [Danishefsky & Kitihara J Am Chem Soc 96 7807 1974, Danishefsky Acc Chem Res 14 400 1981.]
Synthesis of 1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE from Chlorotrimethylsilane and 4-METHOXY-3-BUTEN-2-ONE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
Global( 99)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15932 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 7019 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49390 | 58 |
| Career Henan Chemica Co | +86-0371-86658258 15093356674; | laboratory@coreychem.com | China | 30255 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| Finetech Industry Limited | +86-27-87465837 +8618971612321 | info@finetechnology-ind.com | China | 9651 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | CHINA | 52867 | 58 |
| LEAP CHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 24738 | 58 |
54125-02-9(1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE)Related Search:
Triethoxysilane
Octamethylcyclotetrasiloxane
Vinyltrimethoxysilane
ALLYLOXYTRIMETHYLSILANE
Ethoxytrimethylsilane
4-Methoxy-2-(trimethylsiloxy)-1,3-butadiene,1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE,TRANS-1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
2-(Trimethylsiloxy)-1,3-butadiene
METHOXYTRIMETHYLSILANE
DIMETHYLETHOXYSILANE
VINYLOXYTRIMETHYLSILANE
1of4
TRANS-1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
TRANS-1-METHOXY-3-(TRIMETHYLSILYLOXY)-1,3-BUTADIENE
DANISHEFSKY'S DIENE
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE
1-METHOXY-3-(TRIMETHYLSILOXY)BUTADIENE
1-METHOXY-3-TRIMETHYLSILYLOXY-1,3-BUTADIENE
TRANS-1-METHOXY-3-TRIMETHYLSILOXY- &
1-Methoxy-3-(trimethylsiloxy)butadiene(Danishefsky`sDiene)
Silane, (2E)-3-methoxy-1-methylene-2-propenyloxytrimethyl-
Danishefsky-Kitahara diene.
1-METHOXY-3-TRIMETHYLSILOXY-1,3-BUTADIENE, 98+%
1-Methoxy-3-trimethylsiloxy-1,3-butadiene ,95%
(1E)-3-(Trimethylsilyloxy)-1-methoxy-1,3-butadiene
(E)-1-Methoxy-3-(trimethylsiloxy)-1,3-butadiene
(E)-1-Methoxy-3-[(trimethylsilyl)oxy]-1,3-butadiene
[[(E)-3-Methoxy-1-methylene-2-propenyl]oxy]trimethylsilane
Methyl[(1E)-3-(trimethylsiloxy)-1,3-butadienyl] ether
(E)-(4-methoxybuta-1,3-dien-2-yloxy)trimethylsilane
[(E)-3-Methoxy-1-methylene-allyloxy]-trimethyl-silane
trans-1-Methoxy-3-trimethylsilyloxy-1,3-butadiene for synthesis
trans-1-Methoxy-3-trimethylsiloxy-1,3-butadiene,Danishefsky’s diene
Silane, [[(2E)-3-Methoxy-1-Methylene-2-propen-1-yl]oxy]triMethyl-
[(4-Methoxybuta-1,3-dien-2-yl)oxy]triMethylsilane
trans-1-Methoxy-3-triMethylsiloxy-1,3-butadiene 95%
(2E)-3-Methoxy-1-methylene-2-propen-1-yl]oxy]trimethylsilane
DK814
54125-02-9
C8H16O2Si1
CH33SiOCCH2CHCHOCH3
Building Blocks
Enol Ethers
Organic Building Blocks
Oxygen Compounds
Si-O Compounds
Silicon Compounds (for Synthesis)
Monoalkoxysilanes
Si (Classes of Silicon Compounds)
Vinylsilanes, Allylsilanes