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4-Methylpyridine

CAS No. 108-89-4
Chemical Name: 4-Methylpyridine
Synonyms: GAMMAP;ba35846;Ba 35846;picoline-4;p-Picoline;γ-Picoline;4-PICOLINE;g-picoline;sigma-Picoline;GAMMA-PICOLINE
CBNumber: CB3778430
Molecular Formula: C6H7N
Formula Weight: 93.13
MOL File: 108-89-4.mol
4-Methylpyridine Property
Melting point : 2.4 °C(lit.)
Boiling point : 145 °C(lit.)
density : 0.957 g/mL at 25 °C(lit.)
vapor density : 3.2 (vs air)
vapor pressure : 4 mm Hg ( 20 °C)
refractive index : n20/D 1.504(lit.)
Fp : 134 °F
storage temp. : Flammables area
solubility : alcohol: soluble(lit.)
form : Liquid
pka: 6.02(at 20℃)
color : Clear light yellow
explosive limit: 1.3-8.7%(V)
Water Solubility : soluble
Sensitive : Air Sensitive & Hygroscopic
Merck : 14,7402
BRN : 104586
CAS DataBase Reference: 108-89-4(CAS DataBase Reference)
NIST Chemistry Reference: Pyridine, 4-methyl-(108-89-4)
EPA Substance Registry System: Pyridine, 4-methyl-(108-89-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : T
Risk Statements : 10-20/22-24-36/37/38
Safety Statements : 26-36-45
RIDADR : UN 1992 3/PG 3
WGK Germany : 1
RTECS : UT5425000
TSCA : Yes
HazardClass : 3
PackingGroup : III
HS Code : 29333955
Hazardous Substances Data: 108-89-4(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P312 Call a POISON CENTER or doctor/physician if you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

4-Methylpyridine Chemical Properties,Usage,Production

Chemical Properties
Clear light yellow liquid
Definition
ChEBI: A methylpyridine in which the methyl substituent is at position 4.
General Description
Colorless moderately volatile liquid.
Air & Water Reactions
Highly flammable.
Reactivity Profile
4-Methylpyridine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Health Hazard
ACUTE/CHRONIC HAZARDS: Moderate fire risk.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
4-Methylpyridine Preparation Products And Raw materials
Raw materials
Sodium hydroxide Ammonia
Preparation Products
4-Pyridyl acetone 4-METHYL-PYRIDINE-2-CARBOXYLIC ACID ETHYL 4-PYRIDYLACETATE 2-Picoline 4-PYRIDINECARBOXALDEHYDE N-OXIDE 4,4'-Vinylenedipyridine Isoniazid 4-Piperidineethanol 3-Nitroisonicotinic acid 1,2-BIS(4-PYRIDYL)ETHANE Imazapyr acid 2-BROMOPROPENE 4-Pyridinealdoxime PYRIDINE-4-ACETIC ACID Milrinone 2-CYANO-4-METHYLPYRIDINE 2,6-DIAMINO-4-METHYL PYRIDINE 4-Methyl-3-nitropyridine 4-Vinylpyridine
4-Methylpyridine Suppliers      Global( 208)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
Mei Lan Industrial (Shanghai) Co., Ltd. 021-61500788
021-58957967 wouchina@126.com China 2727 55
Wuhan EnTai Technology Development Co,.Ltd 86-27-82330560
86-27-82330547 2536851935@qq.com China 358 69
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96831 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40403 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30314 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 sales@tcishanghai.com.cn China 22833 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 3437 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44197 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 sales@ouhechem.com China 10816 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273 sales@jingyan-chemical.com China 10094 60
 
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