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Pyridine sulfur trioxide

CAS No.
26412-87-3
Chemical Name:
Pyridine sulfur trioxide
Synonyms
SULFUR TRIOXIDE PYRIDINE COMPLEX;sulfur trioxide pyridine;PYRIDINE SULFUR TRIOXIDE COMPLEX;NSC 75831;PyridineSO3;fur trioxide;Pyridine suL;Sulfur trioxide pyri;sulfonylideneoxidane;Pyridine sulfur trio
CBNumber:
CB9284694
Molecular Formula:
C5H5NO3S
Molecular Weight:
159.16
MDL Number:
MFCD00078270
MOL File:
26412-87-3.mol
MSDS File:
SDS
Last updated:2024-04-15 15:30:59

Pyridine sulfur trioxide Properties

Melting point ~160 °C
storage temp. Store below +30°C.
solubility Soluble in polar organic solvents.
form Powder
color White to beige
Water Solubility reacts
Sensitive Moisture Sensitive
BRN 3704116
InChI InChI=1S/C5H5N.O3S/c1-2-4-6-5-3-1;1-4(2)3/h1-5H;
InChIKey UDYFLDICVHJSOY-UHFFFAOYSA-N
SMILES C1=CC=NC=C1.S(=O)(=O)=O
CAS DataBase Reference 26412-87-3(CAS DataBase Reference)
FDA UNII SVL47N2N3Y
EPA Substance Registry System Pyridine sulfur trioxide (26412-87-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319
Precautionary statements  P264-P270-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  C
Risk Statements  22-34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
3-10-21
Autoignition Temperature >350 °C
TSCA  Yes
HazardClass  8
PackingGroup  II
HS Code  29420000
Toxicity LD50 orally in Rabbit: 500 - 2000 mg/kg
NFPA 704
1
2 0

Pyridine sulfur trioxide price More Price(30)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 84737 Sulfur trioxide pyridine complex technical, ≥45% SO 26412-87-3 100g $91.6 2024-03-01 Buy
Sigma-Aldrich 8.18112 Sulfur trioxide pyridine complex for synthesis 26412-87-3 100g $77.8 2024-03-01 Buy
Sigma-Aldrich 84737 Sulfur trioxide pyridine complex technical, ≥45% SO 26412-87-3 10g $21.5 2022-05-15 Buy
TCI Chemical P0998 Pyridine - Sulfur Trioxide Complex >95.0%(T) 26412-87-3 25g $73 2024-03-01 Buy
TCI Chemical P0998 Pyridine - Sulfur Trioxide Complex >95.0%(T) 26412-87-3 100g $163 2024-03-01 Buy
Product number Packaging Price Buy
84737 100g $91.6 Buy
8.18112 100g $77.8 Buy
84737 10g $21.5 Buy
P0998 25g $73 Buy
P0998 100g $163 Buy

Pyridine sulfur trioxide Chemical Properties,Uses,Production

Chemical Properties

white solid

Uses

Usually used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with DMSO.

Uses

Pyridine-Sulfur Trioxide Complex is used in the sulfation of squid ink polysaccharides (SIPs) as a potential candidate compound for the prevention of tumor metastasis. Pyridine-Sulfur Trioxide Complex is also used in the preparation and anticoagulation test of sulfated silk fibroin.

Uses

Sulfur trioxide-pyridine complex is used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with dimethyl sulfoxide. It is also used as a source of sulfur trioxide especially in the preparation of sulfate esters. Further, it is used as an activating electrophile in a Parikh-Doering oxidation. In addition to this, it is also used in the preparation and anticoagulation test of sulfated silk fibroin.

Purification Methods

Wash the solid with a little CCl4, then H2O to remove traces of pyridine sulfate, and dry it over P2O5. [Baumgarten Chem Ber 59 1166 1926, Olah et al. Synthesis 59 1979, Beilstein 20/5 V 184].

110-86-1
26412-87-3
Synthesis of Pyridine sulfur trioxide from Pyridine
Global( 520)Suppliers
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Shanghai Worldyang Chemical Co.,Ltd.
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View Lastest Price from Pyridine sulfur trioxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Pyridine sulfur trioxide pictures 2024-04-26 Pyridine sulfur trioxide
26412-87-3
US $5.00 / KG 1KG 99% 500mt/year Jinan Finer Chemical Co., Ltd
Sulfur Trioxide Pyridine Complex pictures 2024-04-15 Sulfur Trioxide Pyridine Complex
26412-87-3
US $0.00 / kg 1kg 99% 10000kg Shaanxi TNJONE Pharmaceutical Co., Ltd
Pyridine sulfur trioxide pictures 2023-10-30 Pyridine sulfur trioxide
26412-87-3
US $10.00 / kg 1kg 99% 20 tons Shandong Believe Chemical PTE.LTD
Pyridine,compd.withsulfurtrioxide(1:1) PYRIDINE SULFUR TRIOXIDE COMPLEX ( PSS ) Sulfur trioxide-pyridine complex, 98%, active SO3 ca 48-50% w/w sulphur trioxide--pyridine (1:1) Sulfur trioxide-pyridine complex, tech., 80% Sulfurtrioxide-pyridinecomplex,98% Sulfur trioxide pyridine complex, tech. (48.8-50.3% active SO3) Pyridine, compd. with sulfur trioxide sulfur trioride-pyridine Pyridine, compound with sulfur trioxide (1:1) Sulfur trioxide pyridine complex, (48.8 - 50.3% active sulfur trioxide), tech. Sulfur trioxide·pyridine salt Sulfur trioxide-pyridine complex, 98%, active SO3 ca 48-50% PyridineSO3 Sulfur trioxide pyridine complex ,98% [tech. (48.8-50.3% active SO3)] Active Sulfure Trioxide Sulfur trioxide pyri SULFUR TRIOXIDE PYRIDINE COMPLEX FOR SYN Sulfur trioxide pyridine coMplex, tech. (48.8-50.3% active SO3) 100GR Pyridine Sulfure Trixoxide CoMplex Salfurtrioxidepyri-dinecomplex Sulfurtrioxide,compd.withpyridine(1:1) VINYLBENZYLDIMETHYLAMINE N,N-DIMETHYLVINYLBENZYLAMINE POLY(4-VINYLPYRIDINE) SULFUR TRIOXIDE COMPLEX N-(4-VINYLBENZYL)-N,N-DIMETHYL AMINE SULFUR TRIOXIDE PYRIDINE COMPLEX POLYMER BOUND SULPHUR TRIOXIDE-PYRIDINE COMPLEX PYRIDINE SULFUR TRIOXIDE PYRIDINE SULFUR TRIOXIDE COMPLEX POLYMER BOUND PYRIDINE-SULPHURTRIOXIDECOMPLEX Sulfur trioxide pyridine coMplex, 98%, tech., active SO3 ca. 48 - 50% Sulfur trioxide pyridine coMplex, tech., active SO3 ca. 48 - 50% Sulfur trioxide pyridine coMplex 98% Sulfur trioxide pyridine coMplex technical, >=45% SO3 basis Pyridine sulphur trioxide NSC 75831 Pyridine sulfur trioxde Sulfur trioxide pyridine complex polymer-bound extent of labeling: >=2.0 mmol/g SO3 loading (DIMETHYLAMINOMETHYL)STYRENE Sulfur trioxide-pyridine complex, active SO3 48-50%, 98% sulfonylideneoxidane Sulfur trioxide pyridine complex≥ 98% (Assay) Sulfur trioxide pyridine complex, 48.8 to 50.3% active SO Sulfur trioxide-pyridine complex, Active SO fur trioxide Pyridine suL Pyridine-SulfurTrioxideComplex> Sulfur trioxide pyridine complex, 98%, for synthesis, active SO3 ca. 48 - 50% Pyridine sulfur trio sulfur trioxide pyridine SULFUR TRIOXIDE PYRIDINE COMPLEX PYRIDINE SULFUR TRIOXIDE COMPLEX PyridinesulfChemicalbookurtrioxide SUFUR TRIOXIDE PYRIDINE Pyridine sulfure Trioxide Thiopyridine trioxide 26412-87-3