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Calcium tungstate

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CAS:7790-75-2
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CAS:7790-75-2
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CAS:7790-75-2
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Calcium tungstate manufacturers

  • Calcium tungstate
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  • 2023-12-23
  • CAS:7790-75-2
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  • 2023-09-23
  • CAS:7790-75-2
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  • 2023-09-06
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Calcium tungstate Basic information
Product Name:Calcium tungstate
Synonyms:ACID CALCIUM PHOSPHATE, MONOHYDRATE;Calcium orthotungstate;calcium wolframate, not of a kind used as a luminophore;calcium wolframate, of a kind used as a luminophore;Calciumtungstatewhitepowder;CALCIUM TUNGSTATE(VI);CALCIUM TUNGSTEN OXIDE;calcium wolframate
CAS:7790-75-2
MF:CaO4W
MW:287.92
EINECS:232-219-4
Product Categories:Inorganics;Tungstates;Ceramics;Metal and Ceramic Science;metal tungstate
Mol File:7790-75-2.mol
Calcium tungstate Structure
Calcium tungstate Chemical Properties
Melting point 1620°C
density 6.06 g/mL at 25 °C (lit.)
storage temp. -20°C
solubility Insoluble in H{2}O. Decomposes by hot HCl, HNO{3}
form Powder
Specific Gravity6.062
color white
Water Solubility insoluble H2O; decomposed by hot HCl, HNO3 [MER06]
Merck 14,1712
Solubility Product Constant (Ksp)pKsp: 8.06
Exposure limitsACGIH: TWA 3 mg/m3
NIOSH: TWA 5 mg/m3; STEL 10 mg/m3
CAS DataBase Reference7790-75-2(CAS DataBase Reference)
EPA Substance Registry SystemCalcium tungsten oxide (CaWO4) (7790-75-2)
Safety Information
WGK Germany 3
TSCA Yes
HS Code 28418030
MSDS Information
ProviderLanguage
Calcium tetraoxotungstate English
SigmaAldrich English
ALFA English
Calcium tungstate Usage And Synthesis
Chemical Properties-325 mesh, 10μm or less 99.9% pure; occurs in nature as mineral scheelite; white tetr powder(s), a=0.524 nm, c=1.138 nm; can be prepared by heating tungstic acid and CaO or CaCO3; used in tumor treatment and in luminous paint [KIR83] [STR93] [MER06]
UsesCalcium tungstate can be ued for preparing screens for x-ray observations and photographs; in luminous paints; in scintillation counters.
UsesCalcium tungsten oxide is used as a luminophore.
ApplicationCalcium tungstate is well known as the phosphor that emits light in λ: 310–700 nm under the excitation light in λ: 220–300 nm. The peak wavelength is positioned at 440 nm, causing it to give off a blue color.
Production MethodsA single crystal is grown from melt by the Czochralski method. Rare earth ions are easy to incorporate into the crystal during growth. Fluorescent films are deposited on a glass substrate through vacuum evaporation using a W filament heated at 2000℃ for about 3 min, followed by thermal annealing in oxygen at 550℃ for 2 h. The film becomes crystalline through this thermal annealing.
General DescriptionCalcium tungstate (CaWO4) is an optical material, which can be used as a laser host material for a variety of electronic applications. It has a scheelite structure with luminescence, and thermo-luminescence properties.
Flammability and ExplosibilityNot classified
Structure and conformationThe space lattice of CaWO4 belongs to the tetragonal system, and its Scheelite structure has lattice constants of a=0.524 nm and c=1.138 nm. The space group is I41/a, and there are four formula units per unit cell.
Tag:Calcium tungstate(7790-75-2) Related Product Information
Ammonium paratungstate Calcium carbonate Calcium carbide Calcium Propionate SILICOTUNGSTIC ACID HYDRATE Calcium chloride Calcium gluconate Phosphotungstic acid 44-hydrate Calcium dobesilate Calcium phosphate Tungstic acid POTASSIUM TUNGSTATE LITHIUM TUNGSTATE BARIUM TUNGSTATE MAGNESIUM TUNGSTATE STRONTIUM TUNGSTATE AMMONIUM TUNGSTATE 99.99% Sodium tungstate