ChemicalBook--->CAS DataBase List--->100-70-9

100-70-9

100-70-9 Structure

100-70-9 Structure
IdentificationMore
[Name]

2-Cyanopyridine
[CAS]

100-70-9
[Synonyms]

2-CYANOPYRIDINE
2-PICOLINONITRILE
2-PYRIDINECARBONITRILE
AKOS BBS-00004280
CYANOPYRIDINE(2-)
PICOLINIC ACID NITRILE
PICOLINONITRILE
PYRIDINE-2-CARBONITRILE
TIMTEC-BB SBB008920
2-pyridinecarboxylicacid,nitrile
2-Pyridyl nitrile
2-pyridylnitrile
Pyridin-2-Carbonitril
2-Pyridinrcarbonitrile
2-Cyanopyridine,>98%
picolylnitrile
2-CYANOPYRIDINE 99%
2-Cyanopyridine, Picolinonitrile
[EINECS(EC#)]

202-880-3
[Molecular Formula]

C6H4N2
[MDL Number]

MFCD00006218
[Molecular Weight]

104.11
[MOL File]

100-70-9.mol
Chemical PropertiesBack Directory
[Appearance]

The cyanopyridines are as follows: 2-cyano-: A white to tan liquid or solid. Almond odor. Boiling point=2213℃ ; freezing/melting point=27℃ ; flash point=89℃ . 3-cyano-: a colorless liquid or gray crystal- line solid.
[Melting point ]

24-27 °C(lit.)
[Boiling point ]

212-215 °C(lit.)
[density ]

1.081 g/mL at 25 °C(lit.)
[vapor pressure ]

11.96Pa at 25℃
[refractive index ]

n20/D 1.529(lit.)
[Fp ]

193 °F
[storage temp. ]

2-8°C
[solubility ]

67g/l
[form ]

Low Melting Crystalline Solid
[pka]

pK1:-0.26(+1) (25°C)
[color ]

White to brown
[PH]

8.4 (100g/l, H2O)
[Water Solubility ]

immiscible
[Detection Methods]

GC
[BRN ]

107710
[Henry's Law Constant]

1.4×102 mol/(m3Pa) at 25℃, HSDB (2015)
[Dielectric constant]

93.769999999999996
[Exposure limits]

NIOSH: IDLH 25 mg/m3
[InChI]

1S/C6H4N2/c7-5-6-3-1-2-4-8-6/h1-4H
[InChIKey]

FFNVQNRYTPFDDP-UHFFFAOYSA-N
[SMILES]

N#Cc1ccccn1
[LogP]

0.45 at 25℃
[CAS DataBase Reference]

100-70-9(CAS DataBase Reference)
[NIST Chemistry Reference]

2-Pyridinecarbonitrile(100-70-9)
[EPA Substance Registry System]

100-70-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)
GHS06
[Signal word ]

Danger
[Hazard statements ]

H302-H311
[Precautionary statements ]

P264-P270-P280-P301+P312-P302+P352+P312-P361+P364
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S24/25:Avoid contact with skin and eyes .
[RIDADR ]

3276
[WGK Germany ]

3
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29333999
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 4 Oral
[Hazardous Substances Data]

100-70-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

2-(2-Pyridinyl)-1,3,4-oxadiazole-->2-Iodopyridine-->4-Chloro-pyridine-2-carbonitrile-->2-Pyridinecarbaldehyde oxime-->Propanedinitrile, 2-(dimethylamino)--->2-(Hydroxymethyl)pyridine-->ZINC CYANIDE-->Trimethylacetonitrile-->POTASSIUM CYANIDE-->2-Bromopyridine-->2-Chloropyridine
[Preparation Products]

2,2'-Dipicolylamine-->Di-2-pyridyl ketone-->2-Picolylamine-->Pyridine-2-carboxamide-->2-Cyanopyridin-3-ylboronic acid-->Pyridine-2-carboximidamide hydrochloride-->2-Pyridylamid oxime
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Picolinonitrile(100-70-9).msds
Hazard InformationBack Directory
[Potential Exposure]

Limits in Air NIOSH IDLH525 mg/m3 NIOSH REL: (nitriles) 2 ppm, Ceiling Concentration, not to be exceeded in any 15-minute work period.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek Medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medi- cal attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3276 Nitriles, liquid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required, Potential Inhalation Hazard (Special Provision 5).
[Incompatibilities]

Oxidizing agents, such as perchlorates, peroxides, and permanganates. Nitriles may polymerize in the presence of metals and some metal compounds. They are incompatible with acids; mixing nitriles with strong oxidizing acids can lead to extremely violent reactions. Nitriles are generally incompatible with other oxidizing agents such as peroxides and epoxides. The combination of bases and nitriles can produce hydrogen cyanide. Nitriles are hydrolyzed in both aqueous acid and base to give car- boxylic acids (or salts of carboxylic acids). These reactions generate heat. Peroxides convert nitriles to amides. Nitriles can react vigorously with reducing agents. Acetonitrile and propionitrile are soluble in water, but nitriles higher than propionitrile have low aqueous solubility. They are also insoluble in aqueous acids .
[Description]

The cyanopyridines are as follows:2-cyano-: A white to tan liquid or solid with an almondodor. Boiling point=about 213℃; Freezing/Meltingpoint=27℃; Flash point=89℃.3-cyano-: A colorless liquid or gray crystalline solid.Molecular weight=104.12; Boiling point=83-84℃;Freezing/Melting point=47-49℃. Hazard Identification(based on NFPA-704 M Rating System): Health 3,Flammability 3, Reactivity 0. Soluble in water.4-cyano-: A beige solid. Freezing/Melting point=75.8℃
[Chemical Properties]

The cyanopyridines are as follows: 2-cyano-: A white to tan liquid or solid. Almond odor. Boiling point=2213℃ ; freezing/melting point=27℃ ; flash point=89℃ . 3-cyano-: a colorless liquid or gray crystal- line solid.
[Chemical Properties]

white to brown low melting crystalline solid
[Uses]

2-Cyanopyridine is a cyano substituted pyridine. 2-Cyanopyridine is a related compound of nicotine and is a component of tobacco smoke condensate.
[Definition]

ChEBI: A cyanopyridine carrying the cyano group at position 2.
[storage]

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area away from heat or flame and separate fromoxidizing materials
Spectrum DetailBack Directory
[Spectrum Detail]

2-Cyanopyridine(100-70-9)MS
2-Cyanopyridine(100-70-9)1HNMR
2-Cyanopyridine(100-70-9)13CNMR
2-Cyanopyridine(100-70-9)IR1
2-Cyanopyridine(100-70-9)IR2
2-Cyanopyridine(100-70-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Cyanopyridine, 99%(100-70-9)
[Alfa Aesar]

2-Cyanopyridine, 99%(100-70-9)
[Sigma Aldrich]

100-70-9(sigmaaldrich)
[TCI AMERICA]

2-Cyanopyridine,>99.0%(GC)(100-70-9)
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