| Identification | More | [Name]
Indium chloride | [CAS]
10025-82-8 | [Synonyms]
INDIUM CHLORIDE
INDIUM(II) CHLORIDE
INDIUM(III) CHLORIDE
INDIUM TRICHLORIDE
InCl3
Indium chloride (InCl3)
indiumchloride(incl3)
IndiumchlorideanhydrousPURATREM
Indium(Ⅲ) chloride
INDIUM(III) CHLORIDE, 99.999%
Indium(III) chloride, anhydrous, powder, 99.999+% metals basis
INDIUM(III) CHLORIDE ANHYDROUS
Indium(III) chloride, 99.995%
Indium(III)chloride,anhydrous(99.999%-In)PURATREM
indium(iii) chloride, ultra dry
Indium (III) chloride
Indium trichloride
Indium(III) chloride, anhydrous, 99.99% (metals basis)
Indium(III) chloride, anhydrous, 98+%
Indium(III) chloride, ultra dry, 99.999% (metals basis) | [EINECS(EC#)]
233-043-0 | [Molecular Formula]
Cl3In | [MDL Number]
MFCD00011058 | [Molecular Weight]
221.18 | [MOL File]
10025-82-8.mol |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns.
R29:Contact with water liberates toxic gas.
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
NL1400000
| [F ]
3-10 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28273990 | [Hazardous Substances Data]
10025-82-8(Hazardous Substances Data) | [Toxicity]
MLD s.c. in rats: 10.2 mg/kg; MLD i.v. in rabbits: 0.64 mg/kg, McCord et al., J. Ind. Hyg. Toxicol. 24, 243 (1942) |
| Hazard Information | Back Directory | [Hazard]
See indium. | [Chemical Properties]
white crystalline powder | [Uses]
Catalyzes the enantioselective ring-opening of meso-aziridines with thiols.1,2 A highly efficient catalyst in water for the preparation of furyl glycosides.3 | [Uses]
In electroplating using a solution of the salt with dextrose and NaCN. This solution is stable, though it turns dark on standing and deposits a mud which, however, contains no indium. | [General Description]
Indium(III) chloride (InCl3) is an indium halide that is a Lewis acid in a variety of organic reactions. | [Purification Methods]
The anhydrous salt forms yellow deliquescent crystals which can be sublimed at 600o in the presence of Cl2/N2 (1:1) [does not melt]. It is resublimed in the presence of Cl2/N2 (1:10) and finally heated to 150o to expel excess Cl2. It is soluble in H2O and should be stored in a tightly closed container. [Baxter & Alter J Am Chem Soc 55 1943 1933.] |
| Questions And Answer | Back Directory | [Description]
Indium chloride is a useful catalyst for aqueous organic reactions including C-C bond formation, aldol reaction, Friedel-Crafts acylation, Diels-Alder reaction and reduction1-4. It is an efficient, mild, Lewis acid for organic synthesis. It is an efficient catalyst for thioacetalization and its chemoselectivity. It can also catalyze the enantioselective ring-opening of meso-aziridines with thiols. Moreover, it can act as a highly efficient catalyst in water for the preparation of furyl glycosides.
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