ChemicalBook--->CAS DataBase List--->7440-74-6

7440-74-6

7440-74-6 Structure

7440-74-6 Structure
IdentificationMore
[Name]

Indium
[CAS]

7440-74-6
[Synonyms]

In
INDIUM
VRB-AG
IN000080
IN000180
IN005140
IN000266
IN005120
IN005110
IN005142
IN000264
IN000170
IN000150
IN000210
IN000200
IN000130
IN005105
IN000040
IN005125
IN000260
IN000350
IN000190
IN000270
IN005130
IN000050
IN000120
IN000110
IN000090
IN000230
IN000160
IN000268
IN000140
IN000100
IN000060
IN000070
IN000300
IN000250
INE 07PB
Indium rod
Indium(In)
INDIUM SHOT
indium atom
Indium slug
Indium lump
Indium wire
Indium foil
Indiumingot
INDIUM, BARS
Indium, drop
INDIUM RODS
'LGC' (2601)
indium piece
INDIUM METAL
Metal Indium
INDIUM POWDER
IndiuM pieces
IndiumshotNmm
INDIUM WIRES
Indium?spheres
XLD NOVOBIOCIN
Indium granular
INDIUM STANDARD
Indium granules
Indiumshot(99.9%)
Indium foil1000mm
Indium ingot (In)
IndiumpowderNmesh
Lithium isotope 6
INDIUM GRANULATED
INDIUM SHOT < 2MM
INDIUM AA STANDARD
Indium foil50x50mm
Indium foil25x25mm
IndiuM slug,1-3MM.
Indiumshot(99.99%)
Indium,Ingot99.99%
Indium powder (In)
Indium wireS50-0900
Indium foil50x100mm
INDIUM ICP STANDARD
Indium bars, 99.95%
Indiumshot(99.9999%)
Indiumwire(99.9985%)
Indium foil (99.99%)
In Standard Solution
Indium Nanoparticles
Indium foil100x150mm
Indium foil150x300mm
IndiumwireNmmdiacagm
INDIUM Metals ingots
99,99999%=7Nand/orMBE
INDIUM BAR 99.999+%
Indiumpiecesirregular
INDIUM METAL, 99.999%
indium for high purity
IndiumshotNmmteardrops
INDIUM, POWDER, 99.99%
INDIUM, PIECES, 99.99%
Indium, ingot, 99.999%
IndiuM wire,1.0MM dia.
10mg/l each of Bismuth
10ug/ml each of Bismuth
INDIUM ICP/DCP STANDARD
Thermal Analysis-Indium
Indium, powder, 99.999%
Indium, 99.999%, powder
IndiumfoilNmmthickcagxmm
Indiumwire,1.0mm,99.99%,
IndiuM Metal 99.99% Min
Indium, powder(~100mesh)
ETHANOL (DUTY PAID IN UK)
PROPAN-2-OL(ISO-PROPANOL)
Yttrium in Nitric Acid 2%
INDIUM GRANULAR 99+ 100 G
Indium shot, 4mm (0.2 in.)
Indium standard for ICP
Indium Wire/Φ1.0mm/99.999%
Indium Wire/Φ1.5mm/99.999%
Indium Wire/Φ2.0mm/99.999%
Rhodium in Nitric Acid 2%
Indium ISO 9001:2015 REACH
Indium & compounds (as In)
Indium, Shot, Teardrop 4mm
IndiuM, powder, 99.999% 5GR
Indium Wire/Φ0.50mm/99.999%
Indium shot (99.9999%) 4-8mm
Indium, foil, 0.127 mm thick
IndiuM Pieces (Metals Basis)
Indium, 0.5mm (0.02 in.) dia.
INDIUM, AAS STANDARD SOLUTION
INDIUM SINGLE ELEMENT STANDARD
Indium Nanoparticle Dispersion
indium coating quality balzers
Indium(III) nitrate solution
INDIUM PLASMA EMISSION STANDARD
INDIUM, PLASMA STANDARD SOLUTION
INDIUM AA SINGLE ELEMENT STANDARD
INDIUM ATOMIC ABSORPTION STANDARD
Indium, Shot, Teardrop 4mm 99.99%
INDIUM, WIRE, 2.0MM DIAM., 99.99%
INDIUM, ROD, 10MM DIAM., 99.9998%
INDIUM, WIRE, 1.0MM DIAM., 99.99%
INDIUM, WIRE, 1.5MM DIAM., 99.99%
INDIUM, WIRE, 0.5MM DIAM., 99.95%
Indium Foil/1.0x100x100mm/99.999%
INDIUM, FOIL, 0.5MM THICK, 99.99%
Indium rod, 2.54mm (0.10 in.) dia.
Indium wire, 2.0mm (0.08 in.) dia.
Indium Foil/0.10x100x100mm/99.999%
Indium Foil/0.25x100x100mm/99.999%
Indium Foil/0.50x100x100mm/99.999%
INDIUM, FOIL, 0.1MM THICK, 99.999%
INDIUM, FOIL, 1.0MM THICK, 99.999%
INDIUM, ROD, 6.0MM DIAM., 99.999+%
INDIUM, SHOT, 2-5MM DIAM., 99.999%
INDIUM, WIRE, 1.0MM DIAM., 99.999%
Indium Foil/0.05x100x100mm/99.999%
INDIUM, FOIL, 0.5MM THICK, 99.999%
INDIUM, FOIL, 0.25MM THICK, 99.99%
INDIUM SHOT 2 -5MM DIAM. 99.99%
INDIUM, WIRE, 2.0MM DIAM., 99.999%
INDIUM, WIRE, 0.5MM DIAM., 99.999%
Indium wire, 0.5mm (0.02 in.) dia.
Indium shot (99.9%) 4mm tear drops
Indium shot (99.99%) 4mm tear drops
INDIUM ATOMIC SPECTROSCOPY STANDARD
Indium foil, 1.0mm (0.04 in.) thick
INDIUM, FOIL, 0.25MM THICK, 99.999%
INDIUM, FOIL, 0.127MM THICK, 99.99%
Indium rod, 2.38mm (0.094 in.) dia.
Indium foil, 0.5mm (0.02 in.) thick
Indium foil, 2.0mm (0.08 in.) thick
INDIUM, POWDER, CA. 60 MESH, 99.999%
Indiumfoil0.05mm,99.99%,1000mmx20mm,
INDIUM, 99.99%, FOIL, 0.127 MM THICK
Indium foil, 0.25mm (0.01 in.) thick
Indium foil, 0.05mm (0.002 in.) thick
Indium foil, 0.127mm (0.005 in.) thick
LOWENSTEIN-JENSEN PYRUVATE MEDIUM 6.5ML
INDIUM COATING QUALITY BALZERS STICKS &
INDIUM ICP STANDARD TRACEABLE TO SRM FRO
Indium ingot, 99.999% trace metals basis
Indium pieces, 99.99% trace metals basis
ICP-MS Internal Standard 2 - 8 components
INDIUM: 99.999%, BARS, 283 G (90X25X22MM)
INDIUM ATOMIC ABSORPTION STANDARD SOLUTION
Indium, AAS standard solution, In 1000μg/mL
Indium wire, 1.0mm (0.04 in.) dia., Annealed
INDIUM PLASMA EMISSION SPECTROSCOPY STANDARD
mmIndium atomic absorption standard solution
IndiuM, 99.999%, (trace Metal basis), powder
Indium, plasma standard solution, In 10μg/mL
Indium, powder, (trace metal basis), 99.999%
Indium plasma standard solution, In 1000μg/mL
Multi-Element Internal Standard 7 components
Indium wire, 1.0mm (0.04 in.) dia, Puratronic?
Indium powder, -100 mesh, 99.9% (metals basis)
Indium shot, ≤5mm, 99.9999% trace metals basis
Indium, shot, 2-5mm diam., 99.9+% metals basis
Indium, powder, #100 mesh, 99.99% metals basis
Indium shot, 4-8mm, 99.9999% trace metals basis
Indium plasma standard solution, In 10,000μg/mL
Indium, wire, 0.25mm diam., 99.999% metals basis
Indiumrod,2.38mm(0.094in)dia,99.99%(metalsbasis)
IndiuM, foil, 0.127 MM thick, (trace Metal basis)
Indium ICP Standard@1000 μg/mL in 2-5% Nitric Acid
Indium wire, 1.5mm dia., 99.99% trace metals basis
Indium powder, -325 mesh, 99.99% trace metals basis
Indium wire, 0.5mm dia., 99.995% trace metals basis
Indium wire, 1.0mm dia., 99.995% trace metals basis
IndiumingotA1A,99.99999%(metalsbasis),16mmx10mmx9mm
Indium ICP Standard@10000 μg/mL in 2-5% Nitric Acid
Indium powder, -100 mesh, 99.99% trace metals basis
Indium powder, -60 mesh, 99.999% trace metals basis
Indium ICP-MS Standard@100 μg/mL in 2-5% Nitric Acid
Indium ICP-MS Standard@1000 μg/mL in 2-5% Nitric Acid
Indium wire, diam. 1.0 mm, 99.999% trace metals basis
Indium shot, tear drop, 4mm, 99.9% trace metals basis
Indium shot, tear drop, 4mm, 99.99% trace metals basis
IndiuM beads, diaM. 2-5 MM, 99.999% trace Metals basis
Indium beads, diam. 2-5 mm, >=99.9% trace metals basis
Indium rod, 2.54mm (0.10in) dia, 99.99% (metals basis)
Indium wire, 2.0mm (0.08in) dia, 99.99% (metals basis)
Indium ICP-MS Standard@10000 μg/mL in 2-5% Nitric Acid
Indium, plasma standard solution, Specpure, In 10g/ml
Indiumfoil,0,1mmx30mmx170mm,(+/-0,025mmthick),99,9975%,
Indiumshot,1mm(0.04in),Puratronic?,99.999%(metalsbasis)
Indium, AAS standard solution, Specpure(R), In 1000μg/ml
Indium foil, thickness 0.25 mm, 99.99% trace metals basis
Indium foil, thickness 0.5 mm, 99.999% trace metals basis
IndiuM, 99.99%, (trace Metal basis), foil, 0.127 MM thick
Indium, foil, 0.127 mm thick, (trace metal basis), 99.99%
Indium ingot, polycrystalline, 99.9999% trace metals basis
Indium ingot, polycrystalline, 99.9995% trace metals basis
Indium ingot/button, 31mm (1.2in) dia. 99% (metals basis)
[EINECS(EC#)]

231-180-0
[Molecular Formula]

In
[MDL Number]

MFCD00134048
[Molecular Weight]

114.82
[MOL File]

7440-74-6.mol
Chemical PropertiesBack Directory
[Appearance]

solid
[Melting point ]

156.6 °C (lit.)
[Boiling point ]

2000 °C
[density ]

7.3 g/mL at 25 °C(lit.)
[vapor pressure ]

<0.01 mm Hg ( 25 °C)
[Fp ]

2072°C
[storage temp. ]

Flammables area
[solubility ]

soluble in acid solutions
[form ]

wire
[color ]

White
[Specific Gravity]

7.31
[Stability:]

Stable. Incompatible with strong acids, strong oxidizing agents, sulfur.
[Resistivity]

8.37 μΩ-cm
[Water Solubility ]

insoluble
[Merck ]

14,4947
[Exposure limits]

ACGIH: TWA 2 ppm; STEL 4 ppm
OSHA: TWA 2 ppm(5 mg/m3)
NIOSH: IDLH 25 ppm; TWA 2 ppm(5 mg/m3); STEL 4 ppm(10 mg/m3)
[History]

Discovered by Reich and Richter, who later isolated the metal. Indium is most frequently associated with zinc materials, and it is from these that most commercial indium is now obtained; however, it is also found in iron, lead, and copper ores. Until 1924, a gram or so constituted the world’s supply of this element in isolated form. It is probably about as abundant as silver. About 4 million troy ounces ofindium are now produced annually in the Free World. Canada is presently producing more than 1,000,000 troy ounces annually. The present cost of indium is about $2 to $10/g, depending on quantity and purity. It is available in ultrapure form. Indium is a very soft, silvery-white metal with a brilliant luster. The pure metal gives a high-pitched “cry” when bent. It wets glass, as does gallium. Indium has found application in making low-melting alloys; an alloy of 24% indium–76% gallium is liquid at room temperature. Indium is used in making bearing alloys, germanium transistors, rectifiers, thermistors, liquid crystal displays, high definition television, batteries, and photoconductors. It can be plated onto metal and evaporated onto glass, forming a mirror as good as that made with silver but with more resistance to atmospheric corrosion. There is evidence that indium has a low order of toxicity; however, care should be taken until further information is available. Seventy isotopes and isomers are now recognized (more than any other element). Natural indium contains two isotopes. One is stable. The other, 115In, comprising 95.71% of natural indium is slightly radioactive with a very long half-life.
[LogP]

5.9 at 22℃
[CAS DataBase Reference]

7440-74-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Indium(7440-74-6)
[EPA Substance Registry System]

7440-74-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

C,Xn,F,Xi
[Risk Statements ]

R25:Toxic if swallowed.
R26:Very Toxic by inhalation.
R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R20:Harmful by inhalation.
R11:Highly Flammable.
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
[RIDADR ]

UN 3089 4.1/PG 2
[WGK Germany ]

3
[RTECS ]

NL1050000
[TSCA ]

Yes
[HS Code ]

8112 99 70
[HazardClass ]

8
[PackingGroup ]

III
[Hazardous Substances Data]

7440-74-6(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

INDIUM PHOSPHIDE-->INDIUM(III) IODIDE
Hazard InformationBack Directory
[General Description]

Soft, ductile, shiny, silver-white metal. Mp: 155.6°C; bp: 2080°C. Density 7.31 g cm-3.
[Reactivity Profile]

INDIUM is a non-combustible solid in bulk form but is flammable in the form of a dust. Reacts with strong oxidizing agents. Reacts explosively with dinitrogen tetraoxide dissolved in acetonitrile. Reacts violently with mercury(II)bromide at 350°C. Mixtures with sulfur ignite when heated.
[Hazard]

Metal and its compounds are toxic by inhalation.
[Description]

Indium lies in Group 13 (13th vertical column of the periodic table). it shows a wide variety of properties. It is considered to be metal of the 'poor metals' group.
Indium metal
Indium (symbol Ga; CAS# 7440-74-6) is widely used in the electronics industry, its radioisotopes are used for diagnostic imaging in medicine. Though this element is not essential for human nutrition, it is widely distributed in low concentrations in the environment (Smith et al., 1978).
Radioisotopes of indium have been used to label phagocytes and lymphocytes to localize inflammatory lesions (Dudley and Marrer, 1952; Abrams and Murrer, 1993). Despite early optimism, neither element has found wide use as a treatment for malignancies.
[Chemical Properties]

Indium is a rare, lustrous silver-white metal with atomic number 49 and In as its atomic symbol. It is widely distributed in the Earth’s crust in minute quantities (0.1 ppm) and is also found in the hydrosphere. Indium belongs to group IIIA in the periodic table. It was found and spectroscopically identified as a minor component in zinc ores and isolated in 1863 by Ferdinand Reich and Theodore Richter. Indium is so named for the indigo blue color that its salts lend to flames. Indium resembles tin in its physical and chemical properties and to some extent in its toxicological properties. It is extremely soft and malleable, with a Brinell test hardness of less than 1 and a Mohs scale hardness of 1.2. In the electromotive series, it appears between iron and tin and does not decompose inwater at boiling temperature. It is stable in air, but when heated, it burns with a nonluminous, blue-red flame yielding indium oxide. The surface of indium remains bright up to its melting point; above this, it forms an oxide film.
Indium is flammable in the form of dust, yielding indium oxide when exposed to heat or flame. Mixtures of indium with sulfur ignite when heated. Indium reacts explosively with dinitrogen tetroxide plus acetonitrile. Indium exhibits a violent reaction with mercury(II) bromide at 350°C. Indium is unaffected by water, is attacked by mineral acids, and is very resistant to alkalies.
[Physical properties]

Indium is silvery-white and malleable and looks much like aluminum and tin. However,it is softer than lead. Indium metal is so soft that it cannot be “wiped” onto other surfaces aswith a graphite pencil. Because it is noncorrosive and does not oxidize at room temperatures,it can be polished and will hold its shine better than silver. Its melting point is 156.60°C, itsboiling point is 2,075°C, and its density is 7.31 g/cm3.
[Isotopes]

There are a total of 73 isotopes of indium. All are radioactive with relativelyshort half-lives, except two that are considered stable. Isotope In-113 makes up just4.29% of the total indium found in the Earth’s crust. The isotope In-115, with a half-lifeof 4.41×10-14 years contributes the balance (95.71%) of the element’s existence in theEarth’s crust.
[Origin of Name]

Indium’s name is derived from the Latin word indicum, meaning “indigo,” which is the color of its spectral line when viewed by a spectroscope.
[Occurrence]

Indium is a rather rare metal. It is the 69th most abundant element, which is about asabundant as silver at 0.05 ppm. Although it is widely spread over the Earth’s crust, it is foundin very small concentrations and always combined with other metal ores. It is never found inits natural metallic state.
Indium is recovered as a by-product of smelting other metal ores such as aluminum,antimony, cadmium, arsenic, and zinc. About 1,000 kg of indium is recovered each year (ora concentration of 1 part indium per 1000 parts of dust) from the flue stacks (chimneys) ofzinc refineries.
Indium is found in metal ores and minerals located in Russia, Japan, Europe, Peru, andCanada, as well as in the western part of the United States.
[Characteristics]

Indium has one odd characteristic in that in the form of a sheet, like the metal tin, it willemit a shrieking sound when bent rapidly. Indium has some of the characteristics of othermetals near it in the periodic table and may be thought of as an “extension” of the secondseries of the transition elements. Although it is corrosion-resistant at room temperature, it willoxidize at higher temperatures. It is soluble in acids, but not in alkalis or hot water.
[Uses]

In bearing alloys; as a thin film on moving surfaces made from other metals. In dental alloys. In semiconductor research. In nuclear reactor control rods (in the form of an Ag-In-Cd alloy).
[Uses]

Indium element is used in the synthesis of therapeutic particles containing metal ions; characterized by the use of unique ligand sets capable of making the metal ion complex soluble in biolgical medi a to induce selective toxicity in diseased cells.
[Uses]

Indium’s low melting point is the major factor in determining its commercial importance.This factor makes it ideal for soldering the lead wires to semiconductors and transistors in theelectronics industry. The compounds of indium arsenide, indium antimonide, and indiumphosphide are used to construct semiconductors that have specialized functions in the electronicsindustry.
Another main use is as an alloy with other metals when it will lower the melting point ofthe metals with which it is alloyed. Alloys of indium and silver and indium and lead have theability to carry electricity better than pure silver and lead.
Indium is used as a coating for steel bearings to increase their resistance to wear. It alsohas the ability to “wet” glass, which makes it an excellent mirror surface that lasts longer than mercury mirrors. Sheets of indium foil are inserted into nuclear reactors to help control thenuclear fission reaction by absorbing some of the neutrons.
[Definition]

A soft silvery metallic element belonging to group 13 of the periodic table. It is found in minute quantities, primarily in zinc ores and is used in alloys, in several electronic devices, and in electroplating. Symbol: In; m.p. 155.17°C; b.p. 2080°C; r.d. 7.31 (25°C); p.n. 49; r.a.m. 114.818.
[Definition]

ChEBI: A metallic element first identified and named from the brilliant indigo (Latin indicum) blue line in its flame spectrum.
[Definition]

indium: Symbol In. A soft silvery elementbelonging to group 13 (formerlyIIIB) of the periodic table; a.n.49; r.a.m. 114.82; r.d. 7.31 (20°C);m.p. 156.6°C; b.p. 2080±2°C. It occursin zinc blende and some iron oresand is obtained from zinc flue dust intotal quantities of about 40 tonnesper annum. Naturally occurring indiumconsists of 4.23% indium–113(stable) and 95.77% indium–115 (halflife6 × 1014 years). There are a furtherfive short-lived radioisotopes.The uses of the metal are small –some special-purpose electroplatesand some special fusible alloys. Severalsemiconductor compounds areused, such as InAs, InP, and InSb.With only three electrons in its valencyshell, indium is an electron acceptorand is used to dope puregermanium and silicon; it forms stableindium(I), indium(II), and indium(III) compounds. The elementwas discovered in 1863 by FerdinandReich (1799–1882) and HieronymusRichter (1824–90).
[Production Methods]

Mineral sources are most commonly dark sphalerite (ZnS), marmatite, and christophite (FeS:ZnS). Indium also occurs in small quantities in tin ores, siderite, and manganese and tungsten ores.Gallium is often associated with indium in zinc and tin ores. Many sulfide ores of copper, iron, lead, cobalt, and bismuth contain small quantities of indium. Zinc smelter flue dusts, in some cases, contain more than 1% indium, and are the largest commercial source of the metal. Other commercial sources are plant residues and dross from the refining of zinc, lead, and cadmium. Indium is recovered from zinc processing residues by acid leaching followed by chemical separation from the accompanying elemental impurities such as zinc, cadmium, aluminum, arsenic, and antimony. Final purification by aqueous electrolysis of the salts at a controlled potential yields a product of 99.9% purity. Canada and Peru supply the greatest amounts of unwrought waste and scrap. Next in order are Japan, Germany, and the United Kingdom. The pattern of indium usage, and potential industrial hazard, is 30% in solders, low-melting alloys, and coatings; 30% in instrument applications and holding devices; 18% in electronic components; 6% in nuclear reactor controls; and 16% in research and other uses.
[Health Hazard]

Indium (In) and compounds cause injury to the lungs, liver and kidneys in animals.
There are no reports of toxicity in humans. When indium was applied to the skin there was no evidence of irritation.
[Industrial uses]

Indium (symbol In) is a silvery-white metal with a bluish hue, whiter than tin.It is very ductile and does not work-harden, because its recrystallization point is below normal room temperature, and it softens during rolling. The metal is not easily oxidized, but above its melting point, 157 C, it oxidizes and burns with a violet flame.
Indium is now obtained as a by-product from a variety of ores. Because of its bright color, light reflectance, and corrosion resistance, it is valued as a plating metal, especially for reflectors. It is softer than lead, but a hard surface is obtained by heating the plated part to diffuse the indium into the base metal. It has high adhesion to other metals. When added to chromium plating baths it reduces brittleness of the chromium.
The three largest uses of indium are in semiconductordevices, bearings, and low meltingpointalloys.
[Carcinogenicity]

Indium has not been tested for its ability to cause cancer in animals. However, the probable carcinogenic properties of indium are linked to alterations in the synthesis and maintenance of enzyme systems that metabolize organic carcinogens. A compromise in the ability of these metabolic systems would lead to altered cellular responses to organic carcinogenic substances.
[Purification Methods]

Before use, the metal surface is cleaned with dilute HNO3, followed by thorough washing with water and an alcohol rinse. [D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 856 1963.]
[Structure and conformation]

The space lattice of Indium belongs to the tetragonal system and its deformed face centered cubic D4h (4 atoms within a unit cell) has lattice constants of a=0.4588 nm, c=0.4938 nm, and In–In=0.324 nm.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

indium(7440-74-6).msds
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Indium, foil, 0.127 mm thick, 99.99%(7440-74-6)
[Alfa Aesar]

Indium, powder, 99+%(7440-74-6)
[Sigma Aldrich]

7440-74-6(sigmaaldrich)
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