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109-65-9

109-65-9 Structure

109-65-9 Structure
IdentificationMore
[Name]

1-Bromobutane
[CAS]

109-65-9
[Synonyms]

1-BROMOBUTANE
BUTYL BROMIDE
N-BUTYL BROMIDE
1-Brombutan
1-bromo-butan
1-butylbromide
bromo butane
Butane,1-bromo-
butylbromide(1-bromobutane)
n-Butylbromid
n-C4H9Br
n-bromobutane
1-BROMOBUTANE, REAGENTPLUS, >=99%
1-BROMOBUTANE REAGENTPLUS(TM) 99%
1-BROMOBUTANE REAGENTPLUSTM >=99%
1-BROMOBUTANE, REAGENTPLUS, 99%
1-Bromobutane, 98+%
1-Bromobutane, 99+%
n-BUTYL BROMIDE pure
[EINECS(EC#)]

203-691-9
[Molecular Formula]

C4H9Br
[MDL Number]

MFCD00000260
[Molecular Weight]

137.02
[MOL File]

109-65-9.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to slightly yellow liquid
[mp ]

-112 °C
[bp ]

100-104 °C(lit.)
[density ]

1.276 g/mL at 25 °C(lit.)
[vapor density ]

4.7 (vs air)
[vapor pressure ]

150 mm Hg ( 50 °C)
[refractive index ]

n20/D 1.439(lit.)
[Fp ]

23 °C
[storage temp. ]

Flammables area
[Stability:]

Stable. Flammable-note low flash point. Incompatible with strong oxidizing agents, strong bases.
[Water Solubility ]

0.608 g/L (30 ºC)
[Merck ]

14,1553
[BRN ]

1098260
[CAS DataBase Reference]

109-65-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Butane, 1-bromo-(109-65-9)
[EPA Substance Registry System]

109-65-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xi,N
[Risk Statements ]

R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R10:Flammable.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S60:This material and/or its container must be disposed of as hazardous waste .
S37/39:Wear suitable gloves and eye/face protection .
[RIDADR ]

UN 1126 3/PG 2
[WGK Germany ]

2
[RTECS ]

EJ6225000
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29033036
[Safety Profile]

Moderately toxic by intraperitoneal route. Mddly toxic by inhalation. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Violent reaction with bromobenzene + sodium above 30℃. Can react with oxidizing materials. To fight fire, use CO2, dry chemical, mist or spray. See also BROMIDES.
[Hazardous Substances Data]

109-65-9(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrogen bromide-->1-Butanol-->Phosphorus
[Preparation Products]

n-Butyllithium-->Dibutylamine -->Butyl isocyanate-->Fluorescent Brightener 185-->Hexyl alcohol-->Valeric acid-->Dibutyltin oxide-->2-Methylhexanoic acid-->1-Butyl-3-methylimidazolium hexafluorophosphate-->4-N-BUTOXYPHENOL-->Tributylphosphane-->N-OCTANE-->Butylbenzene-->1-Butyl-3-methylimidazolium tetrafluoroborate-->DIMETHIRIMOL-->Acetamiprid-->Oxybuprocaine hydrochloride-->METHYL 4-METHYLTHIOPHENE-2-CARBOXYLATE-->Valeronitrile-->1-Butylpiperazine-->4-BUTOXYANILINE-->Butanethiol-->HALOFANTRINE-->2-(BUTYLAMINO)ETHANOL-->4-Methyl-2-thiophenecarboxylic acid-->Ethyl 4-(butylamino)benzoate-->Ethyl 2-acetylhexanoate-->1-Butyl-3-methylimidazolium bromide-->Dibutyl sulfide-->Benzonatate-->CIS-3-OCTEN-1-OL-->4-N-BUTOXYBENZOIC ACID-->Butoxybenzene
Hazard InformationBack Directory
[General Description]

A clear colorless liquid. Flash point 65°F. Denser than water and insoluble in water. Vapors heavier than air.
[Reactivity Profile]

1-BROMOBUTANE(109-65-9) is incompatible with strong bases and oxidizers [USCG, 1999].
[Air & Water Reactions]

Highly flammable. Insoluble in water.
[Hazard]

Flammable, dangerous fire risk.
[Health Hazard]

Irritating to the eyes, nose, throat, and upper respiratory tract. Symptoms of exposure include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. Irritating to the skin.
[Potential Exposure]

Butyl bromide is a highly flammable, colorless liquid with a pleasant odor. Molecular weight 5 137.04. Specific gravity (H2O:1) 5 1.28 @ 20C; boiling point 5 101.3C; freezing/melting point 5 2112.4; vapor pressure 5 42 mmHg @ 25C; vapor density (air 5 1) 5 4.68; flash point 5 17.2C (n-); 21C (sec-isomer). Autoignition temperature 5 269C. Explosive limits: LEL: 2.5% @ 100C; UEL: 6.6% @ 100C. Hazard identification (based on NFPA-704 M Rating System): Health 1; flammability 3; reactivity 0 ?. Insoluble in water
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit
[Shipping]

UN1126 & UN23391- & 2-Bromobutane, Hazard Class: 3; Labels: 3—Flammable liquid.
[Incompatibilities]

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. May accumulate static electrical charges and cause ignition of its vapors.
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1-Bromobutane(109-65-9).msds
Spectrum DetailBack Directory
[Spectrum Detail]

1-Bromobutane(109-65-9)IR1
1-Bromobutane(109-65-9)MS
1-Bromobutane(109-65-9)13CNMR
1-Bromobutane(109-65-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1-Bromobutane, 99%(109-65-9)
[Alfa Aesar]

1-Bromobutane, 98+%(109-65-9)
[Sigma Aldrich]

109-65-9(sigmaaldrich)
[TCI AMERICA]

1-Bromobutane,>98.0%(GC)(109-65-9)
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