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13716-12-6

13716-12-6 Structure

13716-12-6 Structure
IdentificationMore
[Name]

Tri-tert-butylphosphine
[CAS]

13716-12-6
[Synonyms]

TRI-T-BUTYLPHOSPHINE
TRI-TERT-BUTYL-PHOSPHANE
TRI-TERT-BUTYLPHOSPHINE
Phosphine, tris(1,1-dimethylethyl)-
tris(1,1-dimethylethyl)phosphine
TRI-TERT-BUTYLPHOSPHINE, 1M IN TOLUENE
TRI-TERT-BUTYLPHOSPHINE, TECH., 90%
TERT-BUTYLPHOSPHINE, ELEC. GR., 99.9995%
Tri-t-butylphosphine,99%
Tri-t-butylphosphine,99%(10wt%inhexane)
Tri-t-butylphosphine,99%(10wt%inhexane)(Sure/Sealbottle)
Tri-t-butylphosphine,min.98%
tri-tert-butylphosphine solution
TRI-T-BUTYLPHOSPHINE (10% WT. IN HEXANE)
TRI-T-BUTYLPHOSPHINE (10 WT% IN HEXANE) WITH SURE/SEAL
Tri-tert-butylphosphine,99% ,(10 wt% in hexane)
Tri-t-butylphosphine, min. 98%
Tris(tert-butyl)phosphine
[EINECS(EC#)]

237-266-4
[Molecular Formula]

C12H27P
[MDL Number]

MFCD00015006
[Molecular Weight]

202.32
[MOL File]

13716-12-6.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[mp ]

30-35 °C(lit.)
[bp ]

102-103 °C13 mm Hg(lit.)
[density ]

0.861 g/mL at 25 °C
[Fp ]

1 °F
[storage temp. ]

Flammables area
[Water Solubility ]

insoluble
[Sensitive ]

Air & Moisture Sensitive
[Detection Methods]

GC
[CAS DataBase Reference]

13716-12-6(CAS DataBase Reference)
[NIST Chemistry Reference]

Tri-tert-butylphosphine(13716-12-6)
[Storage Precautions]

Air sensitive;Moisture sensitive;Store under inert gas
[Storage Precautions]

Air sensitive;Moisture sensitive;Store under inert gas;Store under argon gas
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

R17:Spontaneously flammable in air.
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S25:Avoid contact with eyes .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S27:Take off immediately all contaminated clothing .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2846 4.2/PG 1
[WGK Germany ]

3
[F ]

10-19-23
[HazardClass ]

4.2
[PackingGroup ]

I
[HS Code ]

29319090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethyl acetate-->Diethyl ether-->Tetrahydrofuran-->Dichloromethane-->Hexane-->Magnesium-->Phosphorus trichloride-->Cuprous chloride-->TERT-BUTYLLITHIUM-->2-Chloro-2-methylpropane-->Lithium bromide
[Preparation Products]

1-(4-Pyridyl)piperazine
Questions And AnswerBack Directory
[Reaction]

Useful as a ligand in a variety of palladium-catalyzed C-N, C-O and C-C bond-forming reactions under mild conditions.

Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tri-tert-butylphosphine, 99%(13716-12-6)
[Alfa Aesar]

Tri-tert-butylphosphine, 96%(13716-12-6)
[Sigma Aldrich]

13716-12-6(sigmaaldrich)
[TCI AMERICA]

Tri-tert-butylphosphine,>95.0%(GC)(T)(13716-12-6)
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