| Identification | More | [Name]
Tri-tert-butylphosphine | [CAS]
13716-12-6 | [Synonyms]
TRI-T-BUTYLPHOSPHINE
TRI-TERT-BUTYL-PHOSPHANE
TRI-TERT-BUTYLPHOSPHINE
Phosphine, tris(1,1-dimethylethyl)-
tris(1,1-dimethylethyl)phosphine
TRI-TERT-BUTYLPHOSPHINE, 1M IN TOLUENE
TRI-TERT-BUTYLPHOSPHINE, TECH., 90%
TERT-BUTYLPHOSPHINE, ELEC. GR., 99.9995%
Tri-t-butylphosphine,99%
Tri-t-butylphosphine,99%(10wt%inhexane)
Tri-t-butylphosphine,99%(10wt%inhexane)(Sure/Sealbottle)
Tri-t-butylphosphine,min.98%
tri-tert-butylphosphine solution
TRI-T-BUTYLPHOSPHINE (10% WT. IN HEXANE)
TRI-T-BUTYLPHOSPHINE (10 WT% IN HEXANE) WITH SURE/SEAL
Tri-tert-butylphosphine,99% ,(10 wt% in hexane)
Tri-t-butylphosphine, min. 98%
Tris(tert-butyl)phosphine | [EINECS(EC#)]
237-266-4 | [Molecular Formula]
C12H27P | [MDL Number]
MFCD00015006 | [Molecular Weight]
202.32 | [MOL File]
13716-12-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to light yellow liqui | [Melting point ]
30-35 °C(lit.)
| [Boiling point ]
102-103 °C13 mm Hg(lit.)
| [density ]
0.861 g/mL at 25 °C
| [Fp ]
1 °F
| [storage temp. ]
Flammables area | [form ]
solid | [Specific Gravity]
0.68 | [Water Solubility ]
insoluble | [Hydrolytic Sensitivity]
9: reacts extremely rapidly with atmospheric moisture - may be pyrophoric - glove box or sealed system required | [Sensitive ]
Air & Moisture Sensitive | [Detection Methods]
GC | [BRN ]
1738613 | [InChI]
InChI=1S/C12H27P/c1-10(2,3)13(11(4,5)6)12(7,8)9/h1-9H3 | [InChIKey]
BWHDROKFUHTORW-UHFFFAOYSA-N | [SMILES]
P(C(C)(C)C)(C(C)(C)C)C(C)(C)C | [CAS DataBase Reference]
13716-12-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Tri-tert-butylphosphine(13716-12-6) | [Storage Precautions]
Air sensitive;Moisture sensitive;Store under inert gas;Store under argon gas |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS02,GHS05 | [Signal word ]
Danger | [Hazard statements ]
H250-H314 | [Precautionary statements ]
P231+P232-P260-P280-P303+P361+P353-P305+P351+P338-P370+P378 | [Hazard Codes ]
F,C | [Risk Statements ]
R17:Spontaneously flammable in air.
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S25:Avoid contact with eyes .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S27:Take off immediately all contaminated clothing .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2846 4.2/PG 1
| [WGK Germany ]
3
| [F ]
10-19-23 | [HazardClass ]
4.2 | [PackingGroup ]
I | [HS Code ]
29319090 | [Storage Class]
4.2 - Pyrophoric and self-heating hazardous materials | [Hazard Classifications]
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Pyr. Liq. 1
Skin Corr. 1B
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
Tri-tert-butylphosphine is used primarily in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions. | [reaction suitability]
reagent type: ligand
reaction type: Addition Reactions
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Sonogashira Coupling
reagent type: ligand
reaction type: Stille Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling | [Synthesis]
Under the protection of argon, the reaction solvent tetrahydrofuran was added to the dry reactor, and then calcium phosphide, tert-butyl bromide, and nickel catalyst were added sequentially, and then the reaction was heated up to 60-80 ºC, and then the re |
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J & K SCIENTIFIC LTD.
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Alfa Aesar
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Energy Chemical
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www.energy-chemical.com |
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Jia Xing Isenchem Co.,Ltd
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