ChemicalBook--->CAS DataBase List--->119-47-1

119-47-1

119-47-1 Structure

119-47-1 Structure
IdentificationMore
[Name]

2,2'-Methylenebis(6-tert-butyl-4-methylphenol)
[CAS]

119-47-1
[Synonyms]

2,2'-METHYLENEBIS(4-METHYL-6-TERT-BUTYLPHENOL)
2,2'-METHYLENE-BIS(4-METHYL-6-TERTIARYBUTYLPHENOL)
2,2'-METHYLENEBIS(6-T-BUTYL-4-METHYLPHENOL)
2,2'-METHYLENEBIS(6-T-BUTYL-P-CRESOL)
2,2'-METHYLENEBIS(6-TERT-BUTYL-4-METHYLPHENOL)
2,2-METHYLENEBIS-(6-TERT-BUTYL-4-METHYL-PHENOL)
2,2'-Methylene-bis(6-tert-butyl-para-cresol)
2,2'-METHYLENEBIS(6-TERT-BUTYL-P-CRESOL)
3,3'-DI-TERT-BUTYL-2,2'-DIHYDROXY-5,5'-DIMETHYLDIPHENYLMETHANE
6,6'-Di-tert-butyl-2,2'-methylenedi-p-cresol
6,6'-DI-TERT-BUTYL-4,4'-DIMETHYL-2,2'-METHYLENEDIPHENOL
ANTI OXIDANT 2246
AURORA KA-487
BIS(2-HYDROXY-3-TERT-BUTYL-5-METHYLPHENYL)METHANE
BIS-(3-TERT-BUTYL-2-HYDROXY-5-METHYLPHENYL)-METHAN
BIS(3-TERT-BUTYL-2-HYDROXY-5-METHYLPHENYL)METHANE
IONOL(R) 46
LABOTEST-BB LT00159284
RALOX(R) 46
TIMTEC-BB SBB007695
[EINECS(EC#)]

204-327-1
[Molecular Formula]

C23H32O2
[MDL Number]

MFCD00043641
[Molecular Weight]

340.5
[MOL File]

119-47-1.mol
Chemical PropertiesBack Directory
[Melting point ]

123-127 °C(lit.)
[Boiling point ]

187℃
[bulk density]

300kg/m3
[density ]

1.04g/cm3
[vapor pressure ]

<1 hPa
[refractive index ]

1.4480 (estimate)
[Fp ]

195°C(383°F)
[storage temp. ]

Store below +30°C.
[solubility ]

0.007mg/l practically insoluble
[form ]

White to off-white solid.
[pka]

11.32±0.48(Predicted)
[color ]

White to Off-White
[PH]

4-7 (H2O, 20℃)(aqueous suspension)
[Water Solubility ]

7μg/L at 20℃
[Henry's Law Constant]

1.2×106 mol/(m3Pa) at 25℃, HSDB (2015)
[Cosmetics Ingredients Functions]

ANTIOXIDANT
[InChI]

1S/C23H32O2/c1-14-9-16(20(24)18(11-14)22(3,4)5)13-17-10-15(2)12-19(21(17)25)23(6,7)8/h9-12,24-25H,13H2,1-8H3
[InChIKey]

KGRVJHAUYBGFFP-UHFFFAOYSA-N
[SMILES]

Cc1cc(Cc2cc(C)cc(c2O)C(C)(C)C)c(O)c(c1)C(C)(C)C
[LogP]

6.25 at 20℃
[CAS DataBase Reference]

119-47-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Phenol, 2,2'-methylenebis[6-(1,1-dimethylethyl)-4-methyl-(119-47-1)
[EPA Substance Registry System]

119-47-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)
GHS08
[Signal word ]

Warning
[Hazard statements ]

H361f-H413
[Precautionary statements ]

P201-P273-P308+P313
[Hazard Codes ]

Xi
[Risk Statements ]

R36:Irritating to the eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

1
[RTECS ]

PA3500000
[Autoignition Temperature]

350 °C
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29072900
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Repr. 1B
[Hazardous Substances Data]

119-47-1(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: 4880 mg/kg LD50 dermal Rabbit > 2000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Formaldehyde-->tert-Butanol-->Isobutylene
[Preparation Products]

Irganox 3052
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2,2'-Methylenebis(6-tert-butyl-4-methylphenol)(119-47-1).msds
Hazard InformationBack Directory
[Chemical Properties]

The pure product is a white powder that turns slightly yellowish-pink upon long-term exposure to air. It has a slight phenolic odor. It is easily soluble in organic solvents such as benzene and acetone, but insoluble in water. Its solubility in rubber is greater than 2%.
[Uses]

LOWINOX® 22M46 stabilizer is a non-discoloring antioxidant based on a sterically hindered alkylated bis-phenol.
[Definition]

ChEBI: 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) is a diarylmethane.
[General Description]

2,2′-Methylenebis(6-tert-butyl-4-methylphenol) is a phenolic antioxidant commonly used in increasing the oxidation stability in rubber and plastic industries.
[Flammability and Explosibility]

Notclassified
[Industrial uses]

2,2'-Methylenebis(4-methyl-6-tert-butylphenol) is used in the following products: adhesives and sealants, lubricants and greases, fuels, hydraulic fluids and metal working fluids.
[Source]

2,2'-Methylenebis(4-methyl-6-tert-butylphenol) is a natural product found in Streptomyces and Aspergillus fumigatus with data available.
[Properties and Applications]

TEST ITEMS

SPECIFICATION

APPEARANCE

COLORLESS CRYSTALLINE POWDER

CONTENT

98.0% min

MELTING POINT

124 °C +

MELTING RANGE

120-130 °C

VOLATILE

0.3% max

ASH

0.1% max

150um SIEVE RESIDUE

0.5% max

Spectrum DetailBack Directory
[Spectrum Detail]

2,2'-Methylenebis(6-tert-butyl-4-methylphenol)(119-47-1)MS
2,2'-Methylenebis(6-tert-butyl-4-methylphenol)(119-47-1)1HNMR
2,2'-Methylenebis(6-tert-butyl-4-methylphenol)(119-47-1)13CNMR
2,2'-Methylenebis(6-tert-butyl-4-methylphenol)(119-47-1)IR1
2,2'-Methylenebis(6-tert-butyl-4-methylphenol)(119-47-1)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

119-47-1(sigmaaldrich)
[TCI AMERICA]

2,2'-Methylenebis(6-tert-butyl-p-cresol),>99.0%(GC)(119-47-1)
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