| Identification | More | [Name]
2-METHYLACETANILIDE | [CAS]
120-66-1 | [Synonyms]
2-ACETAMIDOTOLUENE
2-ACETOTOLUIDINE
2'-METHYLACETANILIDE
2-METHYLACETANILIDE
ACETO-O-AMINOTOLUENE
ACETYL-O-TOLUIDINE
N-ACETYL-O-TOLUIDINE
N-O-TOLYL-ACETAMIDE
O-ACETOTOLUIDE
O-ACETOTOLUIDIDE
O-ACETOTOLUIDINE
O-METHYLACETANILIDE
O-TOLYLACETAMIDE
Acetamide,N-(2-methylphenyl)-
Acet-o-toluidide
n-(2-methylphenyl)-acetamid
N-(2-Methylphenyl)acetamide
N-(2-Methyl-phenyl)acetamide
2-Methylacetanilide, 98+%
N-acetyl-2-toluidine | [EINECS(EC#)]
204-414-4 | [Molecular Formula]
C9H11NO | [MDL Number]
MFCD00014961 | [Molecular Weight]
149.19 | [MOL File]
120-66-1.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO OFF-WHITE CRYSTALLINE POWDER | [Melting point ]
109-112 °C | [Boiling point ]
296 °C | [density ]
1.16
| [refractive index ]
1.5279 (estimate) | [Fp ]
296°C | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
It is slightly soluble in acetone, chloroform, toluene, benzene. | [form ]
Solid | [pka]
15.13±0.70(Predicted) | [color ]
Needles | [Detection Methods]
HPLC,NMR | [Merck ]
14,74 | [BRN ]
2207054 | [InChI]
InChI=1S/C9H11NO/c1-7-5-3-4-6-9(7)10-8(2)11/h3-6H,1-2H3,(H,10,11) | [InChIKey]
BPEXTIMJLDWDTL-UHFFFAOYSA-N | [SMILES]
C(NC1=CC=CC=C1C)(=O)C | [CAS DataBase Reference]
120-66-1(CAS DataBase Reference) | [EPA Substance Registry System]
o-Acetotoluidide (120-66-1) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed. | [Safety Statements ]
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RTECS ]
AN2900000 | [Hazard Note ]
Harmful | [TSCA ]
Yes | [HS Code ]
29242990 | [Hazardous Substances Data]
120-66-1(Hazardous Substances Data) | [Toxicity]
mma-sat 1 mg/plate NTPTB* JAN 82 |
| Hazard Information | Back Directory | [General Description]
Colorless crystals. Insoluble in water. | [Reactivity Profile]
O-ACETOTOLUIDIDE(120-66-1) is an amide. Amides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). | [Air & Water Reactions]
Water insoluble. | [Health Hazard]
ACUTE/CHRONIC HAZARDS: Toxic. Hazardous decomposition products. | [Chemical Properties]
WHITE TO OFF-WHITE CRYSTALLINE POWDER | [Uses]
Acetanilide is used as an inhibitor of peroxides and?stabilizer for cellulose ester varnishes.?It is used as an intermediate for the synthesis of?rubber accelerators, dyes and dye intermediate and camphor. It is used as a precursor in penicillin synthesis and other pharmaceuticals including painkillers and intermediates. | [Uses]
o-Methylacetanilide is a substituted acetanilide that is used as precursor for various pharmaceuticals including their intermediates. | [Definition]
ChEBI: 2`-Methylacetanilide is a member of toluenes. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 106, p. 5759, 1984 DOI: 10.1021/ja00331a073
Organic Syntheses, Coll. Vol. 5, p. 650, 1973 | [Safety Profile]
Moderately toxic by ingestion.Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. | [Purification Methods]
Crystallise the toluidide from hot H2O (solubility 1g/210mL), EtOH or aqueous EtOH. UV: max 230 and 280nm (EtOH). [Beilstein 12 H 792, 12 I 376, 12 II 439, 12 III 1853, 12 IV 1755.] |
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Energy Chemical
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Maya High Purity Chemicals
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