ChemicalBook--->CAS DataBase List--->12068-69-8

12068-69-8

12068-69-8 Structure

12068-69-8 Structure
IdentificationMore
[Name]

BISMUTH SELENIDE
[CAS]

12068-69-8
[Synonyms]

BISMUTH(III) SELENIDE
BISMUTH SELENIDE
bismuthselenide(bi2se3)
dibismuth triselenide
vacuumdepositiongrade,99.999%(metalsbasis)
bismuth(iii) selenide, vacuum deposition grade
Bismuth(III) selenide, Vacuum Deposition Grade, 99.999% (metals basis)
2,4,5-Triselena-1,3-dibismabicyclo[1.1.1]pentane
[EINECS(EC#)]

235-104-7
[Molecular Formula]

Bi2Se3
[MDL Number]

MFCD00014200
[Molecular Weight]

654.84
[MOL File]

12068-69-8.mol
Chemical PropertiesBack Directory
[Melting point ]

710°C
[Boiling point ]

1007 °C
[density ]

6.82 g/mL at 25 °C(lit.)
[solubility ]

insoluble in H2O
[form ]

Pieces
[color ]

Gray
[Specific Gravity]

6.82
[Water Solubility ]

Insoluble in water. Decomposes when heated in air. Decomposes in nitric acid and aqua regiaSoluble in strong acids. Insoluble in water and organic solvents.
[Crystal Structure]

Cubic, Halite Structure - Space Group Fm3m
[Merck ]

14,1278
[Exposure limits]

ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
[CAS DataBase Reference]

12068-69-8(CAS DataBase Reference)
[EPA Substance Registry System]

Bismuth selenide (Bi2Se3) (12068-69-8)
Hazard InformationBack Directory
[Chemical Properties]

black crystal(s), 1–6mm pieces (fused) of 99.999% purity; rhomb and hexagonal; decomposes when heated in air, by conc HNO3 and by aqua regia; used in semiconductors and in the form of a 99 or 99.999% pure material used as a sputtering target to produce multilayer thin films and magneto?resistant films [HAW93] [MER06] [CER91]
[Uses]

In semiconductor research.
[General Description]

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Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R23/25:Toxic by inhalation and if swallowed .
R33:Danger of cumulative effects.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S20/21:When using, do not eat, drink or smoke .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3283 6.1/PG 3
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

6.1
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bismuth(III) selenide, Vacuum Deposition Grade, 99.999% (metals basis)(12068-69-8)
[Sigma Aldrich]

12068-69-8(sigmaaldrich)
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