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1345-07-9

1345-07-9 Structure

1345-07-9 Structure
IdentificationMore
[Name]

BISMUTH SULFIDE
[CAS]

1345-07-9
[Synonyms]

BISMUTH (III) SULFIDE
BISMUTH SULFIDE
bismuth(3+)sulfide
bismuthsesquisulfide
bismuthsulfide(bi2s3)
dibismuth trisulphide
bismuth trisul fide
bismuthous sulfide
Bismuth(III) sulfide, 99.999%
BISMUTH SULFIDE TECHNICAL
BISMUTH SULFIDE, 99.999%
Bismuth(III)sulfide(99.9%-Bi)
Bismuth(III)sulfide(99.999%-Bi)PURATREM
BISMUTH (LLL) SULFIDE
Bismuth(III) sulfide, 99.9% (metals basis)
Bismuth sulfide, 99.999% (metals basis)
Bismuth(III) sulfide, 99.999% (metals basis)
[EINECS(EC#)]

215-716-0
[Molecular Formula]

Bi2S3
[MDL Number]

MFCD00014204
[Molecular Weight]

514.16
[MOL File]

1345-07-9.mol
Chemical PropertiesBack Directory
[Appearance]

Blackish brown powder
[Melting point ]

685°C (dec.)
[density ]

7.7 g/mL at 25 °C(lit.)
[solubility ]

insoluble in H2O; soluble in acid solutions
[form ]

Lump
[color ]

Gray
[Specific Gravity]

7.7
[Water Solubility ]

Insoluble in water. Soluble in acids.
[Specific Heat Capacity]

Cp(crystal):0.237669J/(g·K),at 25℃
[Crystal Structure]

Sb2S3 type
[crystal system]

Nogata
[Merck ]

13,1288
[Solubility Product Constant (Ksp)]

pKsp: 97
[Space group]

Pbnm
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.11371.12970.39819090900.5009
[InChI]

1S/2Bi.3S
[InChIKey]

ZABYETDLLXARHZ-UHFFFAOYSA-N
[SMILES]

S=[Bi]S[Bi]=S
[CAS DataBase Reference]

1345-07-9(CAS DataBase Reference)
[EPA Substance Registry System]

Bismuth sulfide (Bi2S3) (1345-07-9)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

2
[RTECS ]

EB3105000
[TSCA ]

Yes
[REACH Registrations]

Active
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
[Toxicity]

mouse,LD50,oral,10gm/kg (10000mg/kg),Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 30(6), Pg. 16, 1986.
Hazard InformationBack Directory
[Chemical Properties]

Blackish brown powder
[Physical properties]

Brownish black orthogonal crystal; density 6.78 g/cm3; hardness 2 Mohs; melts at 850°C; insoluble in water; soluble in acids.
[Occurrence]

Bismuth sulfide occurs in nature as the mineral bismuthinite (bismuth glance). It is used as a starting material to produce many other bismuth compounds.
[Uses]

Bismuth(III) sulfide is used as a starting material to produce other bismuth compounds. It is used in glass industry as a colorant, electronic ceramics, scintillator BGO and in superconductors.
[Preparation]

The compound occurs in nature as mineral bismuthinite. It can be prepared in the laboratory by passing hydrogen sulfide into a solution of bismuth chloride or any soluble bismuth salt:
2BiCl3 + 3H2S → Bi2S3 + 6HCl
Alternatively, bismuth sulfide may be obtained by melting a mixture of bismuth and sulfur.
2Bi + 3S → Bi2S3
[General Description]

Bismuth(III) sulphide can be precipitated by hydrogen sulphide from bismuth solutions. 1
[Flammability and Explosibility]

Nonflammable
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bismuth(III) sulfide, 99.999% (metals basis)(1345-07-9)
[Sigma Aldrich]

1345-07-9(sigmaaldrich)
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