ChemicalBook--->CAS DataBase List--->122-37-2

122-37-2

122-37-2 Structure

122-37-2 Structure
IdentificationMore
[Name]

4-Hydroxydiphenylamine
[CAS]

122-37-2
[Synonyms]

4-ANILINO-1-HYDROXYBENZENE
4-ANILINOPHENOL
4-HYDROXYDIPHENYLAMINE
4-(N-PHENYLAMINO)PHENOL
4-(phenylamino)-phenol
P-ANILINOPHENOL
P-HYDROXYDIPHENYLAMINE
4-(phenylamino)-pheno
4-hydroxy-diphenylamin
Diphenylamine, 4-hydroxy-
N-Phenyl-p-aminophenol
p-(Phenylamino)phenol
p-anilino-pheno
para-Hydroxydifenylamin
Phenol, p-anilino-
Phenol,4-(phenylamino)-
Phenyl-p-aminophenol
p-Hydroxydifenylamin
p-Oxydiphenylamine
VTI 1
[EINECS(EC#)]

204-538-9
[Molecular Formula]

C12H11NO
[MDL Number]

MFCD00020142
[Molecular Weight]

185.22
[MOL File]

122-37-2.mol
Chemical PropertiesBack Directory
[Definition]

Gray solid leaflets. Insoluble in water; soluble in alcohol, ether, acetone, chloroform, alkali, and benzene.
[Melting point ]

67-73°C
[Boiling point ]

190°C
[density ]

1.0936 (rough estimate)
[refractive index ]

1.5300 (estimate)
[Fp ]

209°C
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[pka]

10.46±0.13(Predicted)
[color ]

Gray, solid leaflets
[BRN ]

511942
[CAS DataBase Reference]

122-37-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Phenol, 4-(phenylamino)-(122-37-2)
[EPA Substance Registry System]

122-37-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R22:Harmful if swallowed.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S36/39:Wear suitable protective clothing and eye/face protection .
[RIDADR ]

UN2811
[RTECS ]

SJ6950000
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29222990
[Toxicity]

LD50 oral in rat: 3300mg/kg
Hazard InformationBack Directory
[Hazard]

Irritant.
[Uses]

4-Hydroxydiphenylamine is used as a reactant in the preparation of iron methylisopropylglyoxime dimethylpyridine/dimethylaminopyridine/phenylaminophenol/imidazolidone complexes.
[Safety Profile]

Poison by intravenous route.Moderately toxic by ingestion. A severe eye irritant. Seealso AROMATIC AMINES. When heated todecomposition it emits toxic fumes of NOx.
[Purification Methods]

Crystallise the amine from chlorobenzene/pet ether, pentane (m 72o) or *C6H6/pet ether (m 70o). [Beilstein 13 III 1019, 13 IV 1052.]
Spectrum DetailBack Directory
[Spectrum Detail]

4-Hydroxydiphenylamine(122-37-2)MS
4-Hydroxydiphenylamine(122-37-2)1HNMR
4-Hydroxydiphenylamine(122-37-2)13CNMR
4-Hydroxydiphenylamine(122-37-2)IR1
4-Hydroxydiphenylamine(122-37-2)IR2
4-Hydroxydiphenylamine(122-37-2)IR3
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

4-Hydroxydiphenylamine, 98%(122-37-2)
[Sigma Aldrich]

122-37-2(sigmaaldrich)
[TCI AMERICA]

4-Hydroxydiphenylamine,>95.0%(T)(122-37-2)
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