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130-23-4

130-23-4 Structure

130-23-4 Structure
IdentificationMore
[Name]

1-Amino-8-naphthol-4,6-disulfonic acid
[CAS]

130-23-4
[Synonyms]

1 AMINO 8 HYDROXY 4:6 DISULFONIC ACID
1-AMINO-8-NAPHTHOL-4,6-DISULFONIC ACID
EUROPEAN K-ACID
K ACID
4-amino-5-hydroxynaphthalene-1,7-disulfonic acid
4-amino-5-hydroxynaphthalene-1,7-disulphonic acid
1-amino-8-naphtho-4,6-Disulfonic acid
1-Amino-8-Naphthol-4£6-disulfonic acid/European K Acid
8-AMINO-1-NAPHTHOL-3,5-DISULFONIC ACID
4-Amino-5-hydroxy-1,7-naphthalenedisulfonic acid
4-Amino-5-naphthol-1,7-disulfonic acid
KACID(1-AMINO-8NAPHTHO-4,6-DISULFONICACID)
[EINECS(EC#)]

204-982-3
[Molecular Formula]

C10H9NO7S2
[MDL Number]

MFCD00035711
[Molecular Weight]

319.31
[MOL File]

130-23-4.mol
Chemical PropertiesBack Directory
[density ]

1.880±0.06 g/cm3(Predicted)
[pka]

-0.83±0.40(Predicted)
[Water Solubility ]

20g/L at 26.4℃
[LogP]

-2.33
[Uses]

Azo dye intermediate.
[CAS DataBase Reference]

130-23-4(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P305+P351+P338
Raw materials And Preparation ProductsBack Directory
[Raw materials]

1-Naphthylamine-4,6,8-trisulfonic acid
[Preparation Products]

REACTIVE RED 15-->Direct Green 58-->1,7-Naphthalenedisulfonic acid, 4-(benzoylamino)-5-hydroxy-6-(1-naphthalenylazo)-, disodium salt-->1,7-Naphthalenedisulfonic acid, 4-amino-6-[[4-[(2,4-diaminophenyl)azo]phenyl]azo]-5-hydroxy-, disodium salt-->Reactive red 40-->Direct Green 55-->Reactive Red 200-->C.I. Direct green 60
Hazard InformationBack Directory
[Chemical Properties]

1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid [130-23-4]. (4-amino-5-hydroxynaphthalene-1,7-disulfonic acid), K acid, C10H9NO7S2, Mr 319.3: the acid sodium salt of 1-Amino-8-hydroxynaphthalene-4,6-disulfonic acid is very soluble in water, but the acid potassium salt is less soluble and is more easily salted out. K acid couples under acid and alkaline conditions in a similar manner to H acid.
[Production Methods]

1-Aminonaphthalene-4,6,8-trisulfonic acid paste is heated with sodium hydroxide liquor in an autoclave at 170℃ for 12 h, after which the mixture is added to excess dilute hydrochloric acid. After heating to remove sulfur dioxide, the product (including ca. 8 % of the isomeric 5-amino-2-hydroxynaphthalene-4,8-disulfonic acid) is completely precipitated by cooling and is isolated in 86 % yield. Purification of crude K acid may be effected by dissolving it in aqueous alkali and filtering off the less soluble 5,2,4,8-isomer before reprecipitating.
[Flammability and Explosibility]

Notclassified
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