| Identification | More | [Name]
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline | [CAS]
13080-86-9 | [Synonyms]
2,2'-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE
2,2-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE
4,4'-(4,4'-ISOPROPYLIDENEDIPHENYL-1,1'-DIYLDIOXY)DIANILINE
4,4'-ISOPROPYLIDENEBIS[(4-AMINOPHENOXY)BENZENE]
4,4'-[ISOPROPYLIDENEBIS(P-PHENYLENEOXY)]DIANILINE
BAPP
2,2’-bis(4-aminophenoxyphenyl)propane
4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bis-benzenamin
4,4’-((1-methylethylidene)bis(4,1-phenyleneoxy)bisbenzenamine)
4,4’-(4,4’-isopropylidenediphenyl-1,1’-diyldioxy)
4,4’-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis-benzenamin
4,4’-[(1-methylethylidene)bis(4,1-phenyleneoxy)]bis-Benzenamine
4,4’-isopropylidenebis(4,1-phenyleneoxy)dianiline
2,2'-Bis(4-[4-amonophenoxy]phenyl)propane
2,2’-Bis[4-(4-aminophenoxy)Phenyl]Propane(BAPP)
Benzenamine, 4,4'-[(1-methylethylidene) bis(4,1-phenyleneoxy)]bis-
2,2''-BIS[4-(4-AMINOPHENOXY)PHENYL]PROPANE 99.0%
2,2'-Bis[4-(4-aminophenoxy)pheny]propane
4-BAPOPP
2,2-Bis[p-(p-aminophenoxy)phenyl]propane | [EINECS(EC#)]
235-985-8 | [Molecular Formula]
C27H26N2O2 | [MDL Number]
MFCD00039152 | [Molecular Weight]
410.51 | [MOL File]
13080-86-9.mol |
| Chemical Properties | Back Directory | [Melting point ]
127-130 °C(lit.)
| [Boiling point ]
587.1±50.0 °C(Predicted) | [density ]
1.178±0.06 g/cm3(Predicted) | [vapor pressure ]
0-0Pa at 20-25℃ | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [form ]
Solid:particulate/powder | [pka]
5.16±0.10(Predicted) | [Appearance]
White to off-white Solid | [Water Solubility ]
Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO). | [Henry's Law Constant]
2.0×108 mol/(m3Pa) at 25℃, Zhang et al. (2010) | [InChI]
InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3 | [InChIKey]
KMKWGXGSGPYISJ-UHFFFAOYSA-N | [SMILES]
C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C | [LogP]
4.3-4.9 at 35℃ and pH7 | [CAS DataBase Reference]
13080-86-9(CAS DataBase Reference) | [EPA Substance Registry System]
13080-86-9(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H315-H319-H335 | [Precautionary statements ]
P261-P264-P270-P301+P312-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3
| [RTECS ]
CY1062500
| [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29222990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Description]
2,2-Bis[4-(4-aminophenoxy)phenyl]propane (BAPP), also known as 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline, is a diamino monomer with a diphenoxy-phenyl core. Since the molecule has two amine groups at both ends, it can be cross-linked with carboxylic acids or carboxylic dianhydrides to synthesize polyimides. It is commonly as a monomer for the preparation of polyimides in application of batteries, fuel cells, low dielectric materials and OLEDs.
| [Chemical Properties]
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is white solid
| [Uses]
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is used for preparation polyimide and epoxy resin material.
| [Application]
2,2-Bis[4-(4-aminophenoxy)phenyl] propane (BAPP) can be used for:
(1) Preparation of polyimides. The glass transition temperature of this new polyimide is about 225-230°C. It has the typical yield of thermoplastic polymers. It has a typical thermoplastic polymer yield behaviour, which is very different from other polyimides. The elongation at break was 6% and 29% for polyamide and polyimide, respectively.
(2) Curing epoxy resin (ER) and poly(?-caprolactone) (PCL) for the preparation of crystalline thermoset blends.
(3) Constructing dental resin composites. | [Synthesis]
2,2‐Bis[4‐(4‐aminophenoxy)phenyl] propane (BAPP), as a monomer to prepare polyimide, was synthesized from Bisphenol A and p‐chloronitrobenzene via the nucleophilic substitution reaction[1]. | [References]
[1] CUILI KONG. Synthesis, Structures and Properties of Polyimide Based on 2,2′‐Bis(4‐aminophenoxy phenyl) Propane[J]. Journal of Macromolecular Science, Part A, 2006. DOI:10.1080/10601320600941086. |
| Spectrum Detail | Back Directory | [Spectrum Detail]
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)MS
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)1HNMR
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)13CNMR
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)IR1
4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline(13080-86-9)IR2
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| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|