ChemicalBook--->CAS DataBase List--->135-61-5

135-61-5

135-61-5 Structure

135-61-5 Structure
IdentificationBack Directory
[Name]

Naphthol AS-D
[CAS]

135-61-5
[Synonyms]

Naphta
CI 37520
Naphthoi
Diathol D
Azotol OT
Ultrazol D
Naftolo MD
NaphtazolD
Celcot RTO
Brenthol OT
Azoground D
Naphtazol D
Nalpha AS-D
NAPTHOL AS-D
Naphtoelan D
Naphtol AS-D
Dragonthol D
Naphthoide AD
NAPHTHOL AS-D
Solunaptol OT
Tulathol AS-D
Azonaphtol OT
Amarthol AS-D
Brentosyn OTN
AcnaNaphtholE
DaitoGrounderD
Naphtanilide D
Dycosthol AS-D
Hebeithol AS-D
Kako Grounder D
Naphthanil AS-D
Acna Naphthol E
Youhaothol AS-D.
Cibanaphthol RTO
Daito Grounder D
DDaito Grounder D
Acco Naf-Sol AS-D
C.I. Developer 21
Naphtol AS-D Supra
Acco Naphthol AS-D
Anthonaphthol AS-D
MitsuiNaphtho-zolD
Hiltonaphthol AS-D
Naphthol AS-D?SALE
Mitsui Naphthozol D
Dianix Developer ND
Naphthol AS-D Supra
Amanil Naphthol AS-D
Naphtanilide D Supra
Miketazol Developer NDF
Naphthol AS-D Dispersible
NAPHTHOL AS-D C.I.NO.37520
AZOIC COUPLING COMPONENT 18
C.I.Azoiccouplingcomponent18
3-HYDROXY-2-NAPHTHO-O-TOLUIDIDE
C.I. Azoic Coupling Component 18
135-61-5 C18H15NO2 Naphthol AS-D
Naphthol AS-D ISO 9001:2015 REACH
C.I. Azoic Coupling Component 110
2-Naphtho-o-toluidide, 3-hydroxy-
3-hydroxy-N-o-tolyl-2-naphthamide
2-Hydroxy-3-Naphthoyl-O-Toluidine
naphthol as-D type iii repurified
3-Hydroxy-2′-methyl-2-naphthanilid
C.1.AzoicCouplingComponent18(37520)
3-HYDROXY-2'-METHYL-2-NAPHTHANILIDE
3-HYDROXY-2-NAPHTHOIC ACID O-TOLUIDIDE
2-HYDROXY-3-NAPHTHOIC ACID O-TOLUIDIDE
3-Hydroxy-2'-methyl-2-naphthanilide>
C.I.Azoic Coupling Component 18:C.I.37520
3-HYDROXY-N-(2-METHYLPHENYL)-2-NAPHTHAMIDE
2-Hydroxy-3-naphthoic acid 2'-methylanilide
3-Hydroxy-n-o-tolylnaphthalene-2-carboxamide
1-(2',3'-Hydroxynaphthoylamino)-2-methylbenzene
3-hydroxy-4'-nitro-2-naphthanilide chloroacetate
Naphthol AS-D (3-Hydroxy-2'-methyl-2-naphthanilide)
3-hydroxy-n-(2-methylphenyl)-2-naphthalenecarboxamid
3-Hydroxy-N-(2-methylphenyl)-2-naphthalenecarboxamide
2-Naphthalenecarboxamide-N-(2-methylphenyl)-3-hydroxy
3-Hydroxynaphthalene-2-carbonyl (2-methylphenyl) amine
2-Naphthalenecarboxamide, 3-hydroxy-N-(2-methylphenyl)-
2-Hydroxy-3-naphthoic Acid o-Toluidide Naphthol AS-D Azoic Coupling Component 18 3-Hydroxy-N-(o-tolyl)-2-naphthamide
[EINECS(EC#)]

205-205-0
[Molecular Formula]

C18H15NO2
[MDL Number]

MFCD00021634
[MOL File]

135-61-5.mol
[Molecular Weight]

277.32
Chemical PropertiesBack Directory
[Melting point ]

196-198 °C
[Boiling point ]

399.7±35.0 °C(Predicted)
[density ]

1.277±0.06 g/cm3(Predicted)
[Colour Index ]

37520
[form ]

powder to crystal
[pka]

8.73±0.40(Predicted)
[color ]

White to Gray to Brown
[NIST Chemistry Reference]

2-Naphthalenecarboxamide, 3-hydroxy-n-(2-methylphenyl)-(135-61-5)
[EPA Substance Registry System]

2-Naphthalenecarboxamide, 3-hydroxy-N-(2-methylphenyl)- (135-61-5)
Safety DataBack Directory
[Hazard Codes ]

N
[Risk Statements ]

50/53
[Safety Statements ]

60-61
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

2
[TSCA ]

TSCA listed
[HS Code ]

2924.29.7790
[REACH Registrations]

Active
[HazardClass ]

9
[PackingGroup ]

III
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Carbon dioxide-->Phosphorus trichloride-->Chlorobenzene-->o-Toluidine-->3-Hydroxy-2-naphthoic acid-->3-Hydroxy-2-naphthoic acid-->o-Toluidine
[Preparation Products]

Pigment Red 13-->Chromate(3-), bis[3-(hydroxy-κO)-4-[[2-(hydroxy-κO)-3-[[(2-methylphenyl)amino]carbonyl]-1-naphthalenyl]azo-κN1]-7-nitro-1-naphthalenesulfonato(3-)]-, disodium hydrogen
Hazard InformationBack Directory
[Chemical Properties]

Beige powder. Soluble in solvent naphtha. Insoluble in water and soda ash solution.
[Uses]

Naphthol AS-D is a primary red base dye for cotton fibers, and is also mainly used as a base dye for cotton fabrics in dyeing and printing. Its properties are similar to Naphthol AS, and it can be mixed to adjust color. When combined with red base B, it dyes maroon; when combined with red base RL, it dyes magenta. When used as a base dye for cotton printing, it can be combined with different base dyes to obtain various colors such as orange, red, purple, and blue. It has low affinity for cotton and moderate coupling ability. It is also used for dyeing and printing viscose fibers such as vinylon, viscose, silk, and diacetate, as well as some synthetic fibers. It is also used in the production of insoluble azo dyes and in the manufacture of fast pigments, lake pigments, and organic pigment intermediates.
[Preparation]

O-Methylaniline and 3-Hydroxy-2-naphthoic acid condensation.
[Flammability and Explosibility]

Nonflammable
[Properties and Applications]

yellowish powder, melting point for 195 ~ 196 ℃. Insoluble in water solution and sodium carbonate, soluble in naphtha. In sodium hydroxide solution for yellow. Sensitive to air. Mainly used for cotton yarns, cotton fabric, PVA, viscose, silk and vinegar fiber dyeing, also can be used for direct printing, the cotton print and dye discharge printing, and can be used as a quick pigment and organic pigments intermediate. The affinity of cotton is low, medium coupled ability.
[Purification Methods]

Purify it by recrystallisation from xylene. This gives yellow-green fluorescent solutions at pH 8.2-9.5. [IR: Schnopper et al. Anal Chem 31 1542 1959.] The naphthol AS-D acetate is obtained with AcCl, m 168-169o, and with chloroacetyl chloride naphthol AS-D-chloroacetate is obtained [Moloney et al. J Histochem Cytochem 8 200 1960, Burstone Arch Pathology 63 164 1957]. [Beilstein 12 H 505.]
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