ChemicalBook--->CAS DataBase List--->14126-40-0

14126-40-0

14126-40-0 Structure

14126-40-0 Structure
IdentificationBack Directory
[Name]

BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
[CAS]

14126-40-0
[Synonyms]

Nsc303234
triphenylphosphanium
Dichlorobis(triphenylphosphine) cobalt
Bis(triphenylphosphine)cobalt dichloride
DICHLOROBIS(TRIPHENYLPHOSPHINE)COBALT(II)
BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
Dichlorobis(triphenylphosphine)cobalt(II)
[Molecular Formula]

C36H30Cl2CoP2
[MDL Number]

MFCD00010010
[MOL File]

14126-40-0.mol
[Molecular Weight]

654.41
Chemical PropertiesBack Directory
[Melting point ]

236 °C (dec.)(lit.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

blue
[Sensitive ]

air sensitive
[InChI]

InChI=1S/2C18H15P.2ClH.Co/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
[InChIKey]

OPRPFIIIFJLFCE-UHFFFAOYSA-L
[SMILES]

P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Co](Cl)Cl
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319
[Precautionary statements ]

P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22
[Safety Statements ]

36
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst used for hydrostannations.
  2. Catalyst used for alkyne-dihalomethaneamine couplings. – an efficient route for propargylamines.
  3. Cobalt-catalyzed transformation of alkynyl C-H bond: aldehyde-alkyne-amine coupling.
Reactions of 14126-40-0
Hazard InformationBack Directory
[Uses]

  • Catalyst in three-component coupling reactions
  • Catalyst for Epoxidation reactions
  • Catalyst in Hydrovinylation of Styrene
  • Catalyst in cross-coupling reactions
  • Catalyst for dimerization reactions
  • Catalyst in oxidation reactions
[reaction suitability]

core: cobalt
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE(14126-40-0)1HNMR
BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE(14126-40-0)IR1
BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE(14126-40-0)IR2
14126-40-0 suppliers list
Company Name: Panjin Greenchem Technology Co., Ltd.  Gold
Telephone: 13121959385
Website:
Company Name: ShangHai DEMO Chemical Co.,Ltd  
Telephone: 400-021-7337 2355568890
Website: www.demochem.com
Company Name: Beijing HwrkChemical Technology Co., Ltd  
Telephone: 89508211 18501085097
Website: www.hwrkchemical.com
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: Innochem(Beijing) Technology Co.,Ltd.  
Telephone: 010-56541685 13070143590
Website: www.innochem.cn
Company Name: Shandong Xiya Chemical Co., Ltd  
Telephone: 13355009207 13355009207
Website: http://www.xiyashiji.com
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: T&W GROUP  
Telephone: 021-61551611 13296011611
Website: www.trustwe.com/
Company Name: Shanghai Jian Chao Chemical Technology Co., Ltd.  
Telephone: 150-2103-5486 18017383231
Website:
Company Name: Shanghai Aladdin Bio-Chem Technology Co.,LTD  
Telephone: 400-6206333 13167063860
Website: www.aladdin-e.com/
Company Name: Bide Pharmatech Ltd.  
Telephone: 400-164-7117 18317119277
Website: www.bidepharm.com
Company Name: Beijing Guofang Dingsheng Technology Co., Ltd.  
Telephone: 18610472091
Website: http://www.gfdschem.com
Company Name: Changsha Jing Kang New Material Technology Co., Ltd.  
Telephone: 0731-85118349 18874718518
Website: www.jbiochem.com
Company Name: Sigma-Aldrich  
Telephone: 021-61415566 800-8193336
Website: https://www.sigmaaldrich.cn
Company Name: Watson Biotechnology Co.,Ltd  
Telephone: 027-59207879 1972026995 18140587686
Website: http://www.watsonbiotech.cn
Company Name: Shanghai Uchem Inc.  
Telephone: 15618758386 15618758386
Website: https://www.chemicalbook.com/ShowSupplierProductsList15300/0_EN.htm
Company Name: Zhengzhou Alfachem Co., Ltd.  
Telephone: 0371-53765687 18937137882
Website: https://www.chemicalbook.com/supplier/10084342/
Tags:14126-40-0 Related Product Information
33309-88-5 19999-87-2 14264-16-5 14126-37-5 14588-08-0 32005-36-0 1291-32-3 69861-71-8 34409-44-4 138529-81-4 36620-11-8 28425-04-9 52611-08-2 14781-45-4 87648-10-0 725745-08-4 2136-75-6 7646-79-9