ChemicalBook--->CAS DataBase List--->14126-40-0

14126-40-0

14126-40-0 Structure

14126-40-0 Structure
IdentificationBack Directory
[Name]

BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
[CAS]

14126-40-0
[Synonyms]

Nsc303234
triphenylphosphanium
Dichlorobis(triphenylphosphine) cobalt
Bis(triphenylphosphine)cobalt dichloride
DICHLOROBIS(TRIPHENYLPHOSPHINE)COBALT(II)
BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE
Dichlorobis(triphenylphosphine)cobalt(II)
[Molecular Formula]

C36H30Cl2CoP2
[MDL Number]

MFCD00010010
[MOL File]

14126-40-0.mol
[Molecular Weight]

654.41
Chemical PropertiesBack Directory
[Melting point ]

236 °C (dec.)(lit.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

Powder
[color ]

blue
[Sensitive ]

air sensitive
[InChI]

InChI=1S/2C18H15P.2ClH.Co/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
[InChIKey]

OPRPFIIIFJLFCE-UHFFFAOYSA-L
[SMILES]

P(C1=CC=CC=C1)(C1C=CC=CC=1)C1=CC=CC=C1.P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1.[Co](Cl)Cl
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22
[Safety Statements ]

36
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst used for hydrostannations.
  2. Catalyst used for alkyne-dihalomethaneamine couplings. – an efficient route for propargylamines.
  3. Cobalt-catalyzed transformation of alkynyl C-H bond: aldehyde-alkyne-amine coupling.
Reactions of 14126-40-0
Hazard InformationBack Directory
[Uses]

  • Catalyst in three-component coupling reactions
  • Catalyst for Epoxidation reactions
  • Catalyst in Hydrovinylation of Styrene
  • Catalyst in cross-coupling reactions
  • Catalyst for dimerization reactions
  • Catalyst in oxidation reactions
[reaction suitability]

core: cobalt
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE(14126-40-0)1HNMR
BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE(14126-40-0)IR1
BIS(TRIPHENYLPHOSPHINE)COBALT (II) CHLORIDE(14126-40-0)IR2
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