ChemicalBook--->CAS DataBase List--->14165-55-0

14165-55-0

14165-55-0 Structure

14165-55-0 Structure
IdentificationMore
[Name]

GERMANIUM(IV) ETHOXIDE
[CAS]

14165-55-0
[Synonyms]

GERMANIUM ETHOXIDE
GERMANIUM ETHYLATE
GERMANIUM(IV) ETHOXIDE
GERMANIUM TETRAETHOXIDE
TETRAETHOXYGERMANE
TETRAETHOXYGERMANIUM
TETRAMETHOXYGERMANIUM
ethanol,germanium(4+)salt
germanicacidtetraethylester
Germanium(IV)-ethylat
tetraethylorthogermanate
Germanium (IV) ethoxide (99.99+%-Ge) PURATREM
Germanium(IV) ethylate~Tetraethoxygermanium
Germaniumethoxidemetalsbasiscolorlessliq
GermaniumethoxideTetraethoxygermane
germanium(4+) ethanolate
Germanium(IV) ethoxide, 99.95+% metals basis
Germanium(IV)ethoxide, 99.95+%
GermaniumEthylsulfate
TETRAETHYOXYGERMANE
[EINECS(EC#)]

238-007-8
[Molecular Formula]

C8H20GeO4
[MDL Number]

MFCD00015121
[Molecular Weight]

252.88
[MOL File]

14165-55-0.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to very light yellow liquid
[Melting point ]

-72°C
[Boiling point ]

185-6°C
[density ]

1.14 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.407(lit.)
[Fp ]

121 °F
[form ]

Liquid
[color ]

Colorless
[Specific Gravity]

1.134
[Water Solubility ]

Soluble in anhydrous alcohol and benzene. Hydrolyzes in water
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[BRN ]

3661173
[CAS DataBase Reference]

14165-55-0(CAS DataBase Reference)
[EPA Substance Registry System]

Ethanol, germanium(4+) salt (14165-55-0)
Safety DataBack Directory
[Hazard Codes ]

T,Xi
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[F ]

10-21
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

III
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to very light yellow liquid
[Uses]

It is a sol-gel intermediate for optical fibers and photosensitive.
[Purification Methods]

Distil it through a 10cm Vigreux column (p 11) under reduced pressure. Alternatively distil it through a Fenske glass helices (p 11) column fitted with a total condensation variable take-off stillhead. Fractionate it under reduced pressure using a reflux ratio of 10:1. [Johnson & Fritz J Am Chem Soc 75 718 1953, Bradley J Chem Soc 4916 1956, Beilstein 1 IV 1308.]
Spectrum DetailBack Directory
[Spectrum Detail]

GERMANIUM(IV) ETHOXIDE(14165-55-0)1HNMR
GERMANIUM(IV) ETHOXIDE(14165-55-0)IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Germanium(IV) ethoxide, 99.995% (metals basis)(14165-55-0)
[Sigma Aldrich]

14165-55-0(sigmaaldrich)
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