| Identification | More | [Name]
TRIMETHYLGERMANIUM CHLORIDE | [CAS]
1529-47-1 | [Synonyms]
CHLOROTRIMETHYLGERMANE
TRIMETHYLCHLOROGERMANE
TRIMETHYLGERMANIUM CHLORIDE
(CH3)3GeCl
Germane, chlorotrimethyl-
Trimethylgermyl chloride
Trimethylgermaniumchloride,min.98%
Trimethylchlorogermane, Trimethylgermanium chloride
Trimethylgermanium chloride, min. 98%
Trimethylgermanyl chloride | [EINECS(EC#)]
216-214-4 | [Molecular Formula]
C3H9ClGe | [MDL Number]
MFCD00000462 | [Molecular Weight]
153.2 | [MOL File]
1529-47-1.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless liquid | [Melting point ]
-13 °C (lit.) | [Boiling point ]
102 °C (lit.) | [density ]
1.24 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.433(lit.)
| [Fp ]
35 °F
| [storage temp. ]
Flammables area | [solubility ]
sol ether, THF, hexane, benzene, CH2Cl2, CHCl3. | [form ]
liquid | [color ]
colorless | [Specific Gravity]
1.249 | [Water Solubility ]
Immiscible with water.Miscible with ether, tetrahydrofuran, hexane, benzene, dichloromethane and chloroform. | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Sensitive ]
Moisture Sensitive | [BRN ]
3535109 | [CAS DataBase Reference]
1529-47-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
F,C | [Risk Statements ]
R11:Highly Flammable.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 2924 3/PG 2
| [WGK Germany ]
3
| [F ]
8-10-13-21 | [TSCA ]
No | [HS Code ]
2931.90.9051 | [HazardClass ]
3 | [PackingGroup ]
II |
| Hazard Information | Back Directory | [Chemical Properties]
clear colorless liquid | [Uses]
Trimethylgermanium chloride is used to prepare trimethyl(2-thienyl)germane. It is also used as alkylating and precursor to prepare Grignard reagent in organic synthesis. | [Application]
Trimethylgermanium chloride can be used as a precursor to germanium-masked dienolates for regioselective C-C bond formation, germanium enolates and α-germanate esters for aldol condensation reactions, Peterson-type reactions, and Claisen rearrangements. | [storage]
Trimethylgermanium chloride is air-stable, but moisture sensitive. Germanium compounds are reputed to be of lower toxicity than stannanes. Use in a fume hood. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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Maya High Purity Chemicals
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+86 (573) 82222445 (0)18006601000 452520369 |
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www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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