| Identification | More | [Name]
SILVER TRIFLUOROMETHANESULFONATE | [CAS]
2923-28-6 | [Synonyms]
AGOTF
SILVER (I) TRIFLUOROMETHANE SULFONATE
SILVER(I) TRIFLUOROMETHANESULPHONATE
SILVER TRIFLATE
SILVER TRIFLUOROMETANESULFONATE
SILVER TRIFLUOROMETHANESULFONATE
SILVER TRIFLUOROMETHANESULPHONATE
TRIFLUOROMETHANESULFONATE SILVER SALT
TRIFLUOROMETHANESULFONIC ACID SILVER SALT
trifluoro-methanesulfonicacisilver(1++)salt
Silver trifluormethanesulfonate
Silver(I) triflate~Trifluoromethanesulphonic acid silver(I) salt
SILVER TRIFLUOROMETHANESULFONATE, 99.95+ %
SILVER TRIFLUOROMETHANESULFONATE, 99+%
Silver(I)triflate
Trifluoromethanesulfonicacidsilver(I)salt
Silvertrifluoromethanesulfonate,99%(Silvertriflate)
Methanesulfonic acid, trifluoro-, silver(1+) salt
Silver trifluoromethanesulphonate 99%
Silvertrifluoromethanesulphonate99% | [EINECS(EC#)]
220-882-2 | [Molecular Formula]
CAgF3O3S | [MDL Number]
MFCD00013226 | [Molecular Weight]
256.94 | [MOL File]
2923-28-6.mol |
| Chemical Properties | Back Directory | [Appearance]
light beige crystalline powder | [Melting point ]
286 °C (lit.) | [storage temp. ]
Store below +30°C. | [solubility ]
Methanol (Slightly), Water (Slightly) | [form ]
Powder | [color ]
White to light beige | [Stability:]
Stable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents. | [Water Solubility ]
Soluble in water and also in most organic solvents. | [Hydrolytic Sensitivity]
6: forms irreversible hydrate | [Sensitive ]
Light Sensitive | [BRN ]
3598402 | [InChI]
InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1 | [InChIKey]
QRUBYZBWAOOHSV-UHFFFAOYSA-M | [SMILES]
C(F)(F)(F)S([O-])(=O)=O.[Ag+] | [CAS DataBase Reference]
2923-28-6(CAS DataBase Reference) | [Storage Precautions]
Light sensitive;Store under inert gas | [EPA Substance Registry System]
Methanesulfonic acid, trifluoro-, silver(1+) salt (2923-28-6) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H315-H318 | [Precautionary statements ]
P264-P280-P302+P352-P305+P351+P338-P332+P313-P362+P364 | [Hazard Codes ]
Xi,C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
3260 | [WGK Germany ]
3
| [F ]
8 | [Hazard Note ]
Corrosive | [TSCA ]
Yes | [HazardClass ]
8 | [HazardClass ]
CORROSIVE | [HS Code ]
28432900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Dam. 1
Skin Irrit. 2 |
| Hazard Information | Back Directory | [Chemical Properties]
light beige crystalline powder | [Uses]
Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes. | [General Description]
Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis. | [reaction suitability]
core: silver
reagent type: catalyst | [Purification Methods]
Recrystallise it twice from hot CCl4 [Alo et al. J Chem Soc, Perkin Trans 1 805 1986]. Store it in the dark. [Beilstein 3 IV 34.] |
| Questions And Answer | Back Directory | [Reactions]
- Silver precatalyst for the asymmetric allylation of aldehydes
- Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins
- Silver catalyst for the fluorination of boronic acids
- Silver catalyst for the fluorination of functionalized aryl stannanes
- Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds
- Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate
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