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17250-25-8

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17250-25-8 Structure

17250-25-8 Structure
IdentificationBack Directory
[Name]

HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
[CAS]

17250-25-8
[Synonyms]

Ir18.6%min
Einecs 241-282-7
carbonylhydrotris(triphenylphosphine)iridium
carbonylhydrotris(triphenylphosphine)-iridiu
Hydrocarbonyltris(triphenylphosphine)iridium
Iridium, carbonylhydrotris(triphenylphosphine)-
hydridocarbonyltris (triphenylphosphine) iridiuM
Hydridocarbonyltris-(triphenylphosphino)-iridium
Carbonyltris(triphenylphosphine)hydridoiridium(I)
CARBONYLHYDRIDOTRIS(TRIPHENYLPHOSPHINE)IRIDIUM(I)
HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
carbonyltris(triphenylphosphine)iridium(i) hydride
iridium(I)-tris(triphenylphosphine) carbonyl hydride
hydridocarbonyltris(triphenylphosphine)iridiuM(I),98%
Hydridocarbonyltris(triphenylphosphine)iridium(I),99%
HydridocarbonyltristriphenylphosphineiridiumIlightyellow
Carbonylhydridotris(triphenylphosphine)iridium(I), Ir 18.6% min
Carbonylhydridotris(triphenylphosphine)iridium(I) slowly decomposes in air
[EINECS(EC#)]

241-282-7
[Molecular Formula]

C55H45IrOP3
[MDL Number]

MFCD00015525
[MOL File]

17250-25-8.mol
[Molecular Weight]

1007.08
Chemical PropertiesBack Directory
[Appearance]

pale yellow powder
[Melting point ]

170°C (dec.)
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[solubility ]

Soluble in chloroform and toluene
[form ]

Powder
[color ]

light yellow
[Sensitive ]

Moisture Sensitive
[CAS DataBase Reference]

17250-25-8
[EPA Substance Registry System]

Iridium, carbonylhydrotris(triphenylphosphine)- (17250-25-8)
Hazard InformationBack Directory
[Chemical Properties]

pale yellow powder
[Uses]

Hydridocarbonyltris(triphenylphosphine)iridium (I) (CAS# 17250-25-8) is a useful reagent used for Si-C bond cleavage, and as a catalyst in the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[RIDADR ]

UN2813
[TSCA ]

Yes
[HS Code ]

2843.90.0000
[HazardClass ]

4.3
[PackingGroup ]

III
Questions And AnswerBack Directory
[Reaction]

  1. Catalyst for ring-opening isomerization of unsymmetrically substituted methylenecyclopropanes into 1,3-dienes
  2. Catalyst for asymmetric transfer hydrogenation of aromatic ketones under base-free conditions
  3. Catalyst for C-F bond activation for the C-S cross-coupling of aryl fluorides with diaryl disulfides to synthesize thioethers.
Reactions of 17250-25-8
Spectrum DetailBack Directory
[Spectrum Detail]

HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)(17250-25-8)1HNMR
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