| Identification | Back Directory | [Name]
Carbonyldihydrotris(triphenylphosphine)ruthenium | [CAS]
25360-32-1 | [Synonyms]
ruthenium(II)
Carbonyl(dihydrido)
tris(triphenylphosphine)
Carbonyldihydrotris(triphenylphosphine)ruthenium
Dihydridotris(triphenylphosphine)ruthenium carbonyl
Dihydridocarbonyltris(triphenylphosphine) ruthenium
Dihydridocarbonyltris-(triphenylphosphino)-ruthenium
Carbonyl(dihydrido)tris(triphenyl phosphine)ruthenium
Carbonyldihydridotris(triphenylphosphine)ruthenium(Ⅱ)
RUTHENIUM DIHYDRIDO CARBONYL TRIS (TRIPHENYLPHOSPHINE)
CARBONYLDIHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
CARBONYL(DIHYDRIDO)TRIS(TRIPHENYLPHOSPINERUTHENIUM(II))
CARBONYLDIHYDRIDO TRIS(TRIPHONYLPHOSPHANE)RUTHENIUM(II)
Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II),99%
Carbonyl(dihydrido)tris(triphenylphosphine)rutheniuM(II),98% | [Molecular Formula]
C55H45OP3Ru | [MDL Number]
MFCD00015870 | [MOL File]
25360-32-1.mol | [Molecular Weight]
915.94 |
| Chemical Properties | Back Directory | [Appearance]
White to off-white powder | [Melting point ]
161-163 °C(lit.)
| [storage temp. ]
Refrigerator | [form ]
Powder | [color ]
white to off-white | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Moisture Sensitive | [InChI]
1S/3C18H15P.CO.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;;;; | [InChIKey]
MLIYPCQSOXNTLJ-UHFFFAOYSA-N | [SMILES]
[RuH2].[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9 |
| Hazard Information | Back Directory | [Chemical Properties]
White to off-white powder | [Uses]
&bull Catalyst for conversion of 1,4-alkynediols into pyrroles &bull Catalyst for oxidation of primary alcohols to methyl esters &bull Catalyst for rearrangement of oximes to amides &bull Catalyst for C-C coupling via directed C-H activation &bull Cata | [reaction suitability]
core: ruthenium
reagent type: catalyst
reaction type: C-H Activation |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
20/21/22 | [Safety Statements ]
36 | [RIDADR ]
UN2813 | [WGK Germany ]
3
| [HazardClass ]
4.3 | [PackingGroup ]
III | [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.
- Catalytic C-C bond formation.
- Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.
- Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.
- Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.
- Precatalyst for hydrogen production by means of alcohol dehydrogenation.
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| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
T&W GROUP
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| Telephone: |
021-61551611 13296011611 |
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www.trustwe.com/ |
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