| Identification | More | [Name]
4,4'-Diaminodicyclohexyl methane | [CAS]
1761-71-3 | [Synonyms]
4,4'-DIAMINODICYCLOHEXYLMETHANE
4,4'-METHYLENEBIS(AMINOCYCLOHEXANE)
4,4'-METHYLENEBIS(CYCLOHEXYLAMINE)
4,4-METHYLENEBIS(CYCLOHEXYLAMINE)
BIS(4-AMINOCYCLOHEXYL)METHANE
BIS-(P-AMINOCYCLOHEXYL)METHANE
PACM20
TIMTEC-BB SBB008433
1,4-bis(aminocyclohexyl)methane
4,4’-diaminodicyclohexylmethane,mixtureofisomers
4,4’-methylenebis(cyclohexanamine)
4,4’-methylenebis-cyclohexanamin
4,4’-methylenebis-Cyclohexanamine
4,4’-methylenebis-cyclohexylamin
4,4’-methylenedicyclohexanamine
4,4’-methylenedicyclohexaneamine
4,4’-methylenedicyclohexylamine
4,4'-Bis(aminocyclohexyl)methane
4,4'-Methylenebis(cyclohexanamine)
4,4'-Methylenedicyclohexanamine | [EINECS(EC#)]
217-168-8 | [Molecular Formula]
C13H26N2 | [MDL Number]
MFCD00001496 | [Molecular Weight]
210.36 | [MOL File]
1761-71-3.mol |
| Chemical Properties | Back Directory | [Melting point ]
60-65°C | [Boiling point ]
330-331°C | [density ]
0.95 g/mL at 25 °C(lit.)
| [vapor pressure ]
<0.1 mm Hg ( 38 °C)
| [refractive index ]
1.5032 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
powder to lump to clear liquid | [pka]
10.87±0.70(Predicted) | [color ]
White or Colorless to Almost white or Almost colorless | [Water Solubility ]
Insoluble (<0.1 g/100 mL) | [BRN ]
2079179 | [LogP]
2.03 at 25℃ | [CAS DataBase Reference]
1761-71-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Cyclohexanamine, 4,4'-methylenebis-(1761-71-3) | [EPA Substance Registry System]
1761-71-3(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
T+,N | [Risk Statements ]
R26:Very Toxic by inhalation.
R34:Causes burns.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2928 6.1/PG 2
| [WGK Germany ]
2
| [RTECS ]
GX1530000
| [F ]
10-34 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29213000 | [Toxicity]
LC50 inhalation in mouse: 400mg/m3/4H |
| Hazard Information | Back Directory | [General Description]
Yellowish white liquid or brown solid paste. | [Reactivity Profile]
4,4'-DIAMINODICYCLOHEXYL METHANE(1761-71-3) neutralizes acids in weakly exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. | [Air & Water Reactions]
Sensitive to decomposition in air and light . Insoluble in water. | [Health Hazard]
ACUTE/CHRONIC HAZARDS: This compound is corrosive. | [Fire Hazard]
This chemical is probably combustible. | [Chemical Properties]
Beige solidified mass or fragments | [Synthesis Reference(s)]
Journal of the American Chemical Society, 75, p. 1156, 1953 DOI: 10.1021/ja01101a044 | [Flammability and Explosibility]
Nonflammable | [Toxicology]
On resorption, predominant clinical signs of intoxication were hyperexcitability, excessive salivation, and convulsions in animals; repeated oral dosing (50 – 100 mg kg -1 d -1 in rats and mice for 10 and 16 d, respectively, 50 mg/kg in dogs for up to 82 weeks) resulted in gastrointestinal hemorrhagic inflammations, nephritis, and fatty changes to the liver. No changes in methemoglobin or in other hematological parameters were induced in cats on repeated doses of 50 and 100 mg kg -1 d -1, given twice per week over 2 months. Several in vitro and in vivo mutagenicity studies gave no evidence of a mutagenic or clastogenic potential.
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