ChemicalBook--->CAS DataBase List--->18364-47-1

18364-47-1

18364-47-1 Structure

18364-47-1 Structure
IdentificationMore
[Name]

N-Methyl-3-pyridinamine
[CAS]

18364-47-1
[Synonyms]

3-METHYLAMINOPYRIDINE
METHYL-PYRIDIN-3-YL-AMINE
n-methyl-3-pyridinamine
3-Pyridinamine,N-methyl-
3-AMINOMETHYL PYRIDINE 97%
[Molecular Formula]

C6H8N2
[MDL Number]

MFCD01418130
[Molecular Weight]

108.14
[MOL File]

18364-47-1.mol
Chemical PropertiesBack Directory
[Melting point ]

201 °C
[Boiling point ]

110°C/7mmHg(lit.)
[density ]

1.06g/ml
[refractive index ]

1.5840 to 1.5880
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[form ]

Liquid
[pka]

pK1:8.70(+1) (30°C)
[color ]

Yellow
[λmax]

299nm(H2O)(lit.)
[InChI]

InChI=1S/C6H8N2/c1-7-6-3-2-4-8-5-6/h2-5,7H,1H3
[InChIKey]

DBGFNLVRAFYZBI-UHFFFAOYSA-N
[SMILES]

C1=NC=CC=C1NC
[CAS DataBase Reference]

18364-47-1(CAS DataBase Reference)
[NIST Chemistry Reference]

N-Methyl-3-pyridinamine(18364-47-1)
Safety DataBack Directory
[Risk Statements ]

43
[Safety Statements ]

36/37
[HazardClass ]

6.1
[HS Code ]

29333990
Hazard InformationBack Directory
[Chemical Properties]

Liquid
[Synthesis]

N-Methyl-3-pyridinamine is an organic intermediate. It can be used as a raw material to prepare 4-methyl-N-(pyridin-3-yl)benzenesulfonamide, which is then methylated to prepare N,4-dimethyl-N-(pyridin-3-yl)benzenesulfonamide, and then deprotected to obtain N-Methyl-3-pyridinamine.
[References]

[1] Journal of Organic Chemistry, 2011, vol. 76, # 4, p. 1180 - 1183
[2] Patent: US2010/305124, 2010, A1. Location in patent: Page/Page column 16
[3] Journal of the Chemical Society, 1957, p. 442,443
[4] Roczniki Chemii, 1935, vol. 15, p. 365,370
[5] Chem. Zentralbl., 1936, vol. 107, # I, p. 1219
Questions And AnswerBack Directory
[Application]

3-Methylaminopyridine is an organic intermediate that can be prepared from 3-aminopyridine as a raw material. 4-Methyl-N-(pyridin-3-yl)benzenesulfonamide can be prepared first, then methylated to prepare N,4-dimethyl-N-(pyridin-3-yl)benzenesulfonamide, and then deprotected to obtain 3-methylaminopyridine.
Spectrum DetailBack Directory
[Spectrum Detail]

N-Methyl-3-pyridinamine(18364-47-1)1HNMR
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