ChemicalBook--->CAS DataBase List--->2083-91-2

2083-91-2

2083-91-2 Structure

2083-91-2 Structure
IdentificationMore
[Name]

N,N-Dimethyltrimethylsilylamine
[CAS]

2083-91-2
[Synonyms]

DIMETHYLAMINOTRIMETHYLSILAN
(DIMETHYLAMINO)TRIMETHYLSILANE
N,N-DIMETHYLAMINOTRIMETHYLSILANE
N,N-DIMETHYLAMINOTRIMETHYLSILANE TMSDMA
N,N-DIMETHYLTRIMETHYLSILYLAMINE
N-TRIMETHYLSILYDIMETHYLAMINE
N-(TRIMETHYLSILYL)DIMETHYLAMINE
TMSDMA
CD5400
Dimethyl(trimethylsilyl)amine
Dimethyl-trimethylsilanyl-amine
N,N-Dimethyltrimethylsilamine
N,n-Pentamethylsilanamine
pentamethyl-silanamin
pentamethyl-Silanamine
Silanamine, pentamethyl-
Silanamine,pentamethyl-
pentamethylsilylamine
N,N-DIMETHYLTRIMETHYLSILYLAMINE 97%
(Dimethylamino)trimethylsilane~N-(Trimethylsilyl)dimethylamine
[EINECS(EC#)]

218-222-3
[Molecular Formula]

C5H15NSi
[MDL Number]

MFCD00008297
[Molecular Weight]

117.26
[MOL File]

2083-91-2.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless to pale yellow liquid
[Melting point ]

<0°C
[Boiling point ]

84 °C (lit.)
[density ]

0.732 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.397(lit.)
[Fp ]

−3 °F
[storage temp. ]

Flammables area
[form ]

clear liquid
[pka]

10.77±0.70(Predicted)
[color ]

Colorless to Light yellow
[Specific Gravity]

0.74
[Water Solubility ]

Decomposition
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Moisture Sensitive
[BRN ]

1731861
[InChI]

1S/C5H15NSi/c1-6(2)7(3,4)5/h1-5H3
[InChIKey]

KAHVZNKZQFSBFW-UHFFFAOYSA-N
[SMILES]

CN(C)[Si](C)(C)C
[CAS DataBase Reference]

2083-91-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Dimethylamino(trimethyl)silane(2083-91-2)
[EPA Substance Registry System]

2083-91-2(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
[Signal word ]

Danger
[Hazard statements ]

H225-H260-H314
[Precautionary statements ]

P210-P223-P231+P232-P280-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

F,C
[Risk Statements ]

R11:Highly Flammable.
R34:Causes burns.
[Safety Statements ]

S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2733 3/PG 2
[WGK Germany ]

3
[F ]

1-10
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29319090
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
Water-react 1
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Dimethylamine-->Hexamethyldisilazane-->N,N,N',N'-Tetramethyldiaminomethane-->Chlorotrimethylsilane
[Preparation Products]

Hexamethylphosphorous triamide-->Dimethylphosphoramidous dichloride-->dimethylnitramine-->Dimethyldifluorosilane-->Trimethylsilyl trifluoroacetate
Hazard InformationBack Directory
[Chemical Properties]

clear colorless to pale yellow liquid
[Uses]

N,N-Dimethyltrimethylsilylamine was used in the synthesis of phosphoramidite. It was also employed as a reagent in the preparation of iminium salts and amides as well as for the silylation of polymers. A combination of N-(trimethylsilyl)dimethylamine and MeI was also effective to give p-methylbenzoic acid with a 85% yield based on 90% conversion from the corresponding Me ester. DETA has been treated with N-(trimethylsilyl)-dimethylamine to yield mono-, di- and tri- silylated derivatives
[Application]

N,N-Dimethyltrimethylsilylamine can be used as a reactant to prepare some organic compounds, it can also be used as a silylating agent in chemical synthesis.
[Synthesis]

A process for producing N,N-Dimethyltrimethylsilylamine, which comprises: Trimethylchlorosilane and a solvent are added to a flask, and dimethylamine gas is introduced to obtain a crude product of N,N-dimethyltrimethylsilylamine; the crude product is distilled at atmospheric pressure and then rectified to obtain N,N-Dimethyltrimethylsilylamine.
Spectrum DetailBack Directory
[Spectrum Detail]

N,N-Dimethyltrimethylsilylamine(2083-91-2)1HNMR
N,N-Dimethyltrimethylsilylamine(2083-91-2)13CNMR
N,N-Dimethyltrimethylsilylamine(2083-91-2)IR1
N,N-Dimethyltrimethylsilylamine(2083-91-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N,N-Dimethyltrimethylsilylamine, 97%(2083-91-2)
[Alfa Aesar]

N-(Trimethylsilyl)dimethylamine, 96%(2083-91-2)
[Sigma Aldrich]

2083-91-2(sigmaaldrich)
[TCI AMERICA]

N-(Trimethylsilyl)dimethylamine,>95.0%(GC)(2083-91-2)
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