| Identification | More | [Name]
Methyl 3-amino-2-thiophenecarboxylate | [CAS]
22288-78-4 | [Synonyms]
3-AMINO-2-METHOXYCARBONYLTHIOPHENE
3-AMINO-2-THIOPHENECARBOXYLIC ACID METHYL ESTER
3-AMINOTHIOPHENE-2-CARBOXYLIC ACID METHYL ESTER
AKOS 92421
AKOS B020093
ASINEX-REAG BAS 05504796
LABOTEST-BB LT00112337
M3AT2C
METHYL 3-AMINO-2-THIOPHENECARBOXYLATE
METHYL-3-AMINO-2-THIOPHENE FORMATE
METHYL 3-AMINOTHIOPHENE-2-CARBOXYLATE
RARECHEM AM UC 0123
3-amino-2-thiophenecarboxylicacimethylester
ina-5545-2
Methyl3-amino-2-thenoate
METHYL 3-AMINO-2-THIOPHENECARBOXYLATE, 9 9%
Methyl 3-aminothiophene-2-carboxylate, 98+%
3-AMINO-2-THIOPHENE METHYLFORMATE
Name: 3-Aminothiophene-2-carboxylic acid methyl ester
Methyl-3-Aminothiophene-2-Carb | [EINECS(EC#)]
244-895-8 | [Molecular Formula]
C6H7NO2S | [MDL Number]
MFCD00009765 | [Molecular Weight]
157.19 | [MOL File]
22288-78-4.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powder | [Melting point ]
62-64 °C (lit.) | [Boiling point ]
100-102 °C/0.1 mmHg (lit.) | [density ]
1.274 (estimate) | [refractive index ]
1.5500 (estimate) | [Fp ]
100-102°C/0.1mm | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Soluble in alcohol, toluene, xylene and other solvents | [form ]
Fine Crystalline Powder | [pka]
1.86±0.10(Predicted) | [color ]
Beige to beige-brown | [Water Solubility ]
Slightly soluble in water. | [Detection Methods]
HPLC,NMR | [BRN ]
1365614 | [InChI]
InChI=1S/C6H7NO2S/c1-9-6(8)5-4(7)2-3-10-5/h2-3H,7H2,1H3 | [InChIKey]
TWEQNZZOOFKOER-UHFFFAOYSA-N | [SMILES]
C1(C(OC)=O)SC=CC=1N | [CAS DataBase Reference]
22288-78-4(CAS DataBase Reference) | [EPA Substance Registry System]
22288-78-4(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S22:Do not breathe dust . | [WGK Germany ]
3
| [RTECS ]
XM8347500
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HazardClass ]
IRRITANT | [HS Code ]
29349900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Acrylonitrile-->Methyl thioglycolate-->1.3-Dichloropropene-->3-Chloroacrylonitrile-->3-Aminothiophene-2-carboxylic acid-->Methyl 3-oxotetrahydrothiophene-2-carboxylate-->3-Pyridinecarboxaldehyde-->2-Chloroacrylonitrile | [Preparation Products]
Methyl 3-chlorothiophene-2-carboxylate-->Methyl 3-aminosulfonylthiophene-2-carboxylate-->3-Chlorothiophene-2-carboxamide-->3-(1H-Pyrrol-1-yl)thiophene-2-carboxylic acid-->Methyl 3-[(2-bromoacetyl)amino]thiophene-2-carboxylate-->2,4-Dichlorothieno[3,2-d]pyrimidine-->2,4-Dichlorothieno[3,2-d]pyrimidine-->3-(Acetylamino)thiophene-2-carboxylic acid-->2,4-Dihydroxythieno[3,2-d]pyrimidine-->3-AMino-4-broMo-thiophene-2-carboxylicacidMethylester-->methyl 3-(phenylsulfonamido)thiophene-2-carboxylate-->2-Thiophenecarboxylic acid, 3-[[(5-bromo-2,3-dihydro-7-benzofuranyl)sulfonyl]amino]--->3,8-Diaza-5-methylene-6,12-dithiatricyclo[7.3.0.0(3,7)]dodeca-1(9),7(8),10-trien-2-one-->Methyl 3-(benzoylamino)-2-thiophenecarboxylate |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powder | [Uses]
Methyl 3-amino-2-thiophenecarboxylate was used in:
- the synthesis of 4-nitro and 4-aminothienyl ureas
- total synthesis of quinazolinocarboline alkaloids
- preparation of thienopyrimidinone analogs
| [General Description]
Methyl 3-amino-2-thiophenecarboxylate reacts with hydrazonoyl chlorides in the presence of triethylamine to yield corresponding N-arylamidrazones. | [Safety]
Methyl 3-amino-2-thiophenecarboxylate is irritating to the eyes and skin. Contact may cause skin irritation and severe eye irritation. Inhalation may cause respiratory irritation. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
|