ChemicalBook--->CAS DataBase List--->23747-48-0

23747-48-0

23747-48-0 Structure

23747-48-0 Structure
IdentificationBack Directory
[Name]

6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine
[CAS]

23747-48-0
[Synonyms]

FEMA 3306
FEMA NUMBER 3306
5-METHYL-6,7-DIHYDROC
LABOTEST-BB LT00441061
MAPLE LACTONE PYRAZINE
METHYL DIHYDROCYCLOPENTAPYRAZINE
5-METHYL-2,3-CYCLOPENTENOPYRAZINE
5-Methyl-5H-cyclopenta[b]pyrazine
5-METHYL-6,7-DIHYDROCYCLOPENTAPYRAZINE
5H-5-METHYL-6 7-DIHYDROCYCLOPENTA(B)- &
5-METHYL-6,7-DIHYDROCYCLOPENTA(B)PYRAZINE
5H-5-METHYL-6,7-DIHYDROCYCLOPENTAPYRAZINE
5H-5-Methyl-6,7-dihydrocylope ntapyrazine
6,7-dihydro-5-methyl-5h-cyclopentapyrazin
6,7-DIHYDRO-5-METHYL-5H-CYCLOPENTAPYRAZINE
6,7-Dihydro-5-methylcyclopentapyrazine, 98%
5H-5-METHYL-6,7-DIHYDROCYCLOPENTA[B]PYRAZINE
5H-Cyclopentapyrazine, 6,7-dihydro-5-methyl-
5-Methyl-6,7-dihydro-(5H)-cyclopentapyrazine
5-methyl-(5H)-6,7-dihydrocyclo- pentapyrazine
6,7-Dihydro-5-methyl-5H-cyclopenta[b]pyrazine
6,7-Dihydro-5-methyl-5h-cyclopenta 1,4-diazine
5-METHYL-6,7-DIHYDRO-5(H)-CYCLOPENTA(B)PYRAZINE
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine,98%
dihydromethylcyclopentapyrazine,6,7-dihydro-5-methyl-5H-cyclopentapyrazine
[EINECS(EC#)]

245-864-1
[Molecular Formula]

C8H10N2
[MDL Number]

MFCD00040997
[MOL File]

23747-48-0.mol
[Molecular Weight]

134.18
Chemical PropertiesBack Directory
[Appearance]

clear yellow to yellow-orange to brown liquid
[Melting point ]

121-123 °C
[Boiling point ]

96-99 °C20 mm Hg(lit.)
[density ]

1.055 g/mL at 25 °C(lit.)
[FEMA ]

3306 | 5H-5-METHYL-6,7-DIHYDROCYCLOPENTA(B)PYRAZINE
[refractive index ]

n20/D 1.527(lit.)
[Fp ]

174 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

clear liquid
[pka]

1.85±0.40(Predicted)
[color ]

Colorless to Light yellow to Light orange
[Odor]

nutty, roasted odor
[biological source]

synthetic
[Odor Type]

earthy
[Water Solubility ]

insoluble
[JECFA Number]

781
[Major Application]

flavors and fragrances
[InChI]

1S/C8H10N2/c1-6-2-3-7-8(6)10-5-4-9-7/h4-6H,2-3H2,1H3
[InChIKey]

YZEFQPIMXZVPKP-UHFFFAOYSA-N
[SMILES]

CC1CCc2nccnc12
[LogP]

1.33
[NIST Chemistry Reference]

5H-5-methyl-6,7-dihydrocyclopentapyrazine(23747-48-0)
[EPA Substance Registry System]

5H-Cyclopentapyrazine, 6,7-dihydro-5-methyl-(23747-48-0)
Hazard InformationBack Directory
[Chemical Properties]

clear yellow to yellow-orange to brown liquid
[Description]

5H-5-Methyl-6,7-dihydrocyclopenta(-b)pyrazine has an earthy, baked potato, peanut, roasted odor. It may be prepared from condensation of 2-hydroxy-3-methyl-2-cyclopentene-l-one and ethylene diamine; by condensing a cyclopentenolone with alkylenediamines, or alternatively, an aliphatic α-diketone with 1,2-diamino cyclopentane; the resulting product is dehydrogenated in the presence of palladium over activated charcoal or copper chromite.
[Occurrence]

Reported found in peanuts, filberts, asparagus, potato wheat and rye bread, cooked beef, pork, pork liver, beer, cocoa, coffee, green tea, barley, filberts, almond, sesame seed, malt and wort
[Uses]

5-Methyl-6,7-dihydrocyclopentapyrazine can be used for drug storage packaging and antibacterial composition.
[Definition]

ChEBI: 6,7-Dihydro-5-methyl-5H-cyclopenta[b]pyrazine is a member of pyrazines.
[Preparation]

From condensation of 2-hydroxy-3-methyl-2-cyclopentene-1-one and ethylene diamine; by condensing a cyclopentenolone with alkylenediamines, or alternatively, and aliphatic α-diketone with 1,2-diamino cyclopentane; the resulting product is dehydrogenated in the presence of palladium over activated charcoal or copper chromite.
[Aroma threshold values]

Aroma characteristics at 1.0%: sweet, nutty, roasted, toasted, grainy, coffee and corn with savory, meaty nuances.
[Taste threshold values]

Taste characteristics at 15 ppm: nut skin, brown, roasted, oily with a cocoa and coffee nuance, musty, nutty, and grainy
[General Description]

5H-5-Methyl-6,7-dihydrocyclopenta[b]pyrazine is the major flavor compound of palm sugar. It is also found in coffee and cooked meat.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

29339900
[Storage Class]

10 - Combustible liquids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine(23747-48-0).msds
Spectrum DetailBack Directory
[Spectrum Detail]

6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine(23747-48-0)MS
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine(23747-48-0)1HNMR
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine(23747-48-0)13CNMR
6,7-Dihydro-5-methyl-5(H)-cyclopentapyrazine(23747-48-0)IR1
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