ChemicalBook--->CAS DataBase List--->24017-47-8

24017-47-8

24017-47-8 Structure

24017-47-8 Structure
IdentificationBack Directory
[Name]

Triazophos
[CAS]

24017-47-8
[Synonyms]

TRY
ABLE
SPARK
TRELKA
TRIUMPH
FULSTOP
hoe2960
HOE 2960
MSS CMPP
TF563500
Hostahion
hoe2960oj
Hostation
Methoxone
Trazophos
Triazofos
ai3-27764
TRIAZOPHOS
HOSTATHION
Triazofosz
TRIAZAPHOS
HOSTATHIONE
HOE 2960 OJ
TRIPHOS(TM)
Hostathion[R]
Triazophos 85%
Phentriazophos
TRIAZOPHOS 85%TC
triazophos (bsi,iso)
triazofosz(hungarian)
Triazofos: (Triazophos)
phentriazophos Hostathion
Triazophos Solution, 100ppm
Triazophos(100ug/mlinToluene)
TRIAZOPHOS TECHNICAL MIXTURE, APPROX. 70
phenyl-1,2,4-triazolyl-3-(o,o-diethyl thionophosphate)
1-Phenyl-1,2,4-triazolyl-3-(O,O-diethylthionophosphate)
1-Phenyl-3-(O,O-diethyl-thionophosphoryl)-1,2,4-triazole
diethyl o-(1-phenyl-1h-1,2,4-triazol-3-yl) phosphorothioate
O,O-diethyl-O-(1-phenyl-1,2,4-triazol-3-yl)phosphorothioate
O,O-DIETHYL-(1-PHENYL-1H-1,2,4-TRIAZOL-3-YL)HOSPHOROTHIOATE
O,O-DIETHYL O-1-PHENYL-1H-1,2,4-TRIAZOL-3-YL PHOPHOROTHIOATE
o,o-Diethyl o-(1-phenyl-1H-1,2,4-triazol-3-yl) thiophosphate
O,O-diethyl-O-(1-phenyl-1,2,4-triazole-3-yl)-phosphorothioate
o,o-diethyl o-(1-phenyl-1h-1,2,4-triazol-3-yl) phosphorothioate
phosphorothioicacid,o,o-diethylo-(1-phenyl-1,2,4-triazolyl)ester
Diethoxy-[(1-phenyl-1,2,4-triazol-3-yl)oxy]-sulfanylidenephosphorane
Phosphorothioic acid, O,O-diethyl O-(1-phenyl-1,2,4-triazolyl) ester
phosphorothioicacid,0,0-diethyl0-(1-phenyl-1h-1,2,4-triazol-3-yl)ester
Thiophosphoric acid O,O-diethyl O-(1-phenyl-1H-1,2,4-triazol-3-yl) ester
Phosphorothioic acid, O,O-diethyl O-(1-phenyl-1H-1,2,4-triazol-3-yl) ester
O,O-diethyl-O-1-phenyl-1H,2,4-triazol-3-yl phosphorothioate,triazophos (ISO)
triazophos (ISO) O,O-diethyl-O-1-phenyl-1H,2,4-triazol-3-yl phosphorothioate
Phosphorothioicacid,esters,O,O-diethyl-O-(1-phenyl-1H-1,2,4-triazol-3-yl)ester
[EINECS(EC#)]

245-986-5
[Molecular Formula]

C12H16N3O3PS
[MDL Number]

MFCD00055327
[MOL File]

24017-47-8.mol
[Molecular Weight]

313.31
Chemical PropertiesBack Directory
[Melting point ]

0-5°C
[Boiling point ]

260°C
[density ]

1.247
[vapor pressure ]

3.9×10-4 Pa (30 °C)
[Fp ]

25 °C
[storage temp. ]

APPROX 4°C
[solubility ]

DMSO (Slightly), Methanol (Slightly)
[form ]

liquid
[pka]

-0.15±0.50(Predicted)
[color ]

Light yellow to brown
[Water Solubility ]

30-40 mg/L at 20 ºC
[BRN ]

682554
[Henry's Law Constant]

3.2×102 mol/(m3Pa) at 25℃, HSDB (2015)
[Stability:]

Hygroscopic
[Major Application]

agriculture
environmental
[InChI]

1S/C12H16N3O3PS/c1-3-16-19(20,17-4-2)18-12-13-10-15(14-12)11-8-6-5-7-9-11/h5-10H,3-4H2,1-2H3
[InChIKey]

AMFGTOFWMRQMEM-UHFFFAOYSA-N
[SMILES]

CCOP(=S)(OCC)Oc1ncn(n1)-c2ccccc2
[NIST Chemistry Reference]

Triazophos(24017-47-8)
[EPA Substance Registry System]

Triazophos (24017-47-8)
Safety DataBack Directory
[Hazard Codes ]

T;N,N,T
[Risk Statements ]

21-23/25-50/53-38-10
[Safety Statements ]

1/2-36/37-45-60-61
[RIDADR ]

3018
[WGK Germany ]

3
[RTECS ]

TF5635000
[HazardClass ]

6.1(a)
[PackingGroup ]

II
[HS Code ]

29339900
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 1 Inhalation
Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
[Hazardous Substances Data]

24017-47-8(Hazardous Substances Data)
[Toxicity]

LD50 in rats (mg/kg): 82 orally, 1100 dermally (Thier); LD50 in rats (mg/kg): 107 i.p.; in rabbits (mg/kg): 280 dermally (Hay)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Dichloromethane-->Toluene-->Potassium carbonate-->Sodium bicarbonate-->Urea-->Xylene-->Formic acid-->4-Chlorobenzaldehyde-->EMULSIFIER-->Trimethylamine-->Phenylhydrazine-->Triethylamine hydrochloride-->Diethyl chlorothiophosphate-->Phenylhydrazine hydrochloride-->1-Phenylsemicarbazide
[Preparation Products]

Trichlorfon+Triazophos,E.C.-->Abametin+Triazophos,E.C.
Hazard InformationBack Directory
[General Description]

Yellowish oil. Used to control insects, mites, and nematodes. Not registered as a pesticide in the U.S.
[Reactivity Profile]

Organophosphates, such as Triazophos, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
[Health Hazard]

This is an organophosphate pesticide. Triazophos is a cholinesterase inhibitor and acts on the central nervous system. Organic phosphorus insecticides are absorbed by the skin as well as by the respiratory and gastrointestinal tracts.
[Fire Hazard]

This is an organophosphate pesticide. Some of these materials may burn but none of them ignite readily. Container may explode in heat of fire. Fire may produce irritating or poisonous gases. Degraded by acids and alkalis.
[Chemical Properties]

The industrial product is a yellow liquid with a solubility of 30-40 mg/kg in water. It is easily soluble in acetone, ethyl acetate, and toluene.
[Definition]

ChEBI: Triazophos is an organic thiophosphate and an organothiophosphate insecticide. It has a role as an EC 3.1.1.7 (acetylcholinesterase) inhibitor, an acaricide, an agrochemical and a nematicide. It is functionally related to a 1-phenyl-1H-1,2,4-triazol-3-ol.
[Agricultural Uses]

Insecticide: Triazophos is a broad-spectrum insecticide and acaricide used to control sucking and chewing pests on a variety of crops, including cotton, rice, corn, beets and fruit trees. Not currently registered for use in the U.S. Not approved for use in EU countries . There are more than 30 global suppliers .
[Trade name]

HILAZPOPHOS®; HOE 2960 OJ®; HOE 002960®; HOSTATHION®; SUTATHION®
[Mechanism of action]

Non-systemic, broad-spectrum with contact and stomach action. Acetylcholinesterase (AchE) inhibitor.
[Synthesis]

I. Phenylhydrazine hydrochloride and urea were mixed and heated to 150-160 ℃ with stirring, the reaction produced ammonia to get a yellow melt. Cooling, washing, filtration, recrystallization with alcohol to get 1-phenylaminourea (melting point 172 ℃). 1-
[Metabolic pathway]

The main route of biotransformation of triazophos is degradation to 1- pheny1-3-hydroxy-1,2,4-triazole, probably either via hydrolysis of triazophos oxon or through oxidative cleavage of triazophos itself. The triazole ring of this metabolite is opened to give 1-phenylsemicarbazide and semicarbazide, both of which are conjugated in the rat and also degraded to urea as the main urinary metabolite.
[Degradation]

Triazophos is stable to light but is hydrolysed by acids and alkalis (PM).
[Pesticide Type]

Insecticide; Acaricide; Nematicide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Triazophos(24017-47-8).msds
Questions And AnswerBack Directory
[Description]

Triazophos is a Yellowish-brown-oil chemical pesticide used as an insecticide, nematicide and acaricide. The chemical is an organophosphorus compound and ingestion and other exposures to the chemical can cause various symptoms. The type and severity of symptoms varies depending on the amount of chemical involved and the nature of the exposure. The chemical may be absorbed through the skin. More detailed information about the symptoms, causes, and treatments of Chemical poisoning--Triazophos is available below. It is stable to sunlight and its molecular weight313.312 g/mol. For solublity, It solubles in organic solvents and in acetone, dichloromethane, methanol, isopropanol, ethyl acetate and plyethyleneglycols >500; n-hexane 11.1 (all in g/L at 20 degree).
[Methods of Manufacturing]

Triazophos is produced by reaction of 1-phenyl-3-hydroxy-1H-1,2,4-triazole, suspended in acetone, with diethoxythiophosphoryl chloride in the presence of triethylamine.
Physical and chemical properties
The pure product is a pale yellow-brown oily liquid; melting point: 0-5 °C; vapor pressure: 0.39 Mpa; relative density: 1.24; it decomposes at 185 °C before reaching the boiling point and can be degraded by acids and alkalis.
[Uses]

Triazophos is a broad-spectrum insecticide and miticide and has a certain degree of nematicidal effects. It has excellent preventive effects on many pests of the major crops including grain, cotton and vegetables, such as stem borers, rice planthoppers, spider mites, cotton bollworms, nematodes, and it is especially effective on the lepidoptera.
[Storage and transportation]

It should be protected from the sun, rain and heat sources and kept away from food, seeds and feeds.
[References]

1.http://www.sld.chemchina.com/slden/cpyfw/ppysb/jscg/webinfo/2012/06/1342611935442261.htm
2.https://pubchem.ncbi.nlm.nih.gov/compound/Triazophos
3.https://fr.wikipedia.org/wiki/Triazophos
24017-47-8 suppliers list
Company Name: Anhui Shengli Pesticide & Chemistry Co., Ltd  Gold
Telephone: 0563-4308780
Website: www.shengli-chem.com
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Chemsky (shanghai) International Co.,Ltd  
Telephone: 021-50135380
Website: www.shchemsky.com
Company Name: Syntechem Co.,Ltd  
Telephone:
Website: www.syntechem.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: Chengdu Ai Keda Chemical Technology Co., Ltd.  
Telephone: 4008-755-333 18080918076
Website: http://www.aikeshiji.com
Company Name: Shanghai Aladdin Bio-Chem Technology Co.,LTD  
Telephone: 400-6206333 13167063860
Website: www.aladdin-e.com/
Company Name: VOT INTERNATIONAL BUSINESS CO.,LTD  
Telephone: 0536-2456718
Website: www.chemicalbook.com/ShowSupplierProductsList15857/0_EN.htm
Company Name: Nanjing Sunlida Biological Technology Co., Ltd.  
Telephone: 025-57798810 18652991625
Website:
Company Name: TianJin Alta Scientific Co., Ltd.  
Telephone: 022-65378550-8551
Website: www.altascientific.cn
Company Name: Shanghai Worldyang Chemical Co.,Ltd.  
Telephone: 021-56795766
Website: www.worldyachem.com
Company Name: Wuxi Zhongkun Biochemical Technology Co., Ltd.  
Telephone: 0510-85629785 18013409632;
Website: www.reading-chemicals.com
Company Name: Hangzhou J&H Chemical Co., Ltd.  
Telephone: 0571-87396432
Website: www.jhechem.com
Company Name: Hubei Jusheng Technology Co.,Ltd  
Telephone: 027-59599241 18871490274
Website: http://www.jushengtech.com
Company Name: Taizhou Ruixin Chemical Co., Ltd.  
Telephone: 0576-89085261 15867635987
Website: http://www.runsunchemical.com
Company Name: Raw material medicin reagent co.,Ltd  
Telephone:
Website: http://www.njromanme.com
Company Name: Grader reagent  
Telephone: 18221735425
Website: www.shxinping.net
Company Name: Amadis Chemical Company Limited  
Telephone: 571-89925085
Website: http://www.amadischem.com
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