ChemicalBook--->CAS DataBase List--->2414-98-4

2414-98-4

2414-98-4 Structure

2414-98-4 Structure
IdentificationMore
[Name]

Magnesium ethoxide
[CAS]

2414-98-4
[Synonyms]

MAGNESIUM DIETHOXIDE
MAGNESIUM ETHOXIDE
MAGNESIUM ETHYLATE
Ethanol,magnesiumsalt
magnesium ethanolate
MAGNESIUM ETHOXIDE MG(C2H5O)2
MAGNESIUM ETHYLATE 98%
Magnesiumethoxide,Mg21-22%
Magnesiumethoxide,98%
MAGNESIUM ETHOXIDE , WHITE POWDER
Diethoxymagnesium
Magnesium diethanolate
[EINECS(EC#)]

219-323-5
[Molecular Formula]

C4H10MgO2
[MDL Number]

MFCD00009060
[Molecular Weight]

114.43
[MOL File]

2414-98-4.mol
Chemical PropertiesBack Directory
[Appearance]

white to light grey powder
[Melting point ]

270°C
[bulk density]

480kg/m3
[density ]

1,01 g/cm3
[Fp ]

>43°C
[storage temp. ]

Store below +30°C.
[form ]

Powder
[color ]

White to slightly gray
[Specific Gravity]

1.01
[Stability:]

Stable, but reacts violently with water. Highly flammable. Incompatible with water, moisture and moist air, strong acids, oxidizing agents.
[Water Solubility ]

Insoluble in water.
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Sensitive ]

Air & Moisture Sensitive
[BRN ]

3678841
[InChI]

1S/2C2H5O.Mg/c2*1-2-3;/h2*2H2,1H3;/q2*-1;+2
[InChIKey]

XDKQUSKHRIUJEO-UHFFFAOYSA-N
[SMILES]

CCO[Mg]OCC
[CAS DataBase Reference]

2414-98-4(CAS DataBase Reference)
[EPA Substance Registry System]

2414-98-4(EPA Substance)
Questions And AnswerBack Directory
[Preparation]

Magnesium ethoxide can be prepared by reacting magnesium metal with ethanol using mercuric chloride or iodine as a catalyst.
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H251-H319
[Precautionary statements ]

P235-P305+P351+P338
[Hazard Codes ]

F,Xi
[Risk Statements ]

R11:Highly Flammable.
R14:Reacts violently with water.
R36:Irritating to the eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
[RIDADR ]

UN 3181 4.1/PG 2
[WGK Germany ]

1
[F ]

3-10-21
[Autoignition Temperature]

70 °C
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

4.2
[PackingGroup ]

II
[HS Code ]

29051990
[Storage Class]

4.2 - Pyrophoric and self-heating hazardous materials
[Hazard Classifications]

Eye Irrit. 2
Self-heat. 1
[Toxicity]

LD50 orally in Rabbit: > 3160 mg/kg
Hazard InformationBack Directory
[Chemical Properties]

white to light grey powder
[Uses]

Magnesium ethoxide is used as olefin polymerization catalyst carrier for polypropylene, polyethylene and precision ceramic materials.
[Flammability and Explosibility]

Highlyflammable
[reaction suitability]

reaction type: Grignard Reaction
[Purification Methods]

Dissolve ca 1g of solid in 12.8mL of absolute EtOH and 20mL of dry xylene and reflux in a dry atmosphere (use CaCl2 in a drying tube at the top of the condenser). Add 10mL of absolute EtOH and cool. Filter the solid under dry N2 and dry it in a vacuum. Alternatively dissolve it in absolute EtOH and pass it through molecular sieves (40 mesh) under N2, evaporate under N2, and store it in a tightly stoppered container. [Smith & Wiley J Am Chem Soc 68 889 1946, Beilstein 1 III 1283.]
Spectrum DetailBack Directory
[Spectrum Detail]

Magnesium ethoxide(2414-98-4)IR1
Magnesium ethoxide(2414-98-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Magnesium ethoxide(2414-98-4)
[Alfa Aesar]

Magnesium ethoxide, Mg 21-22%(2414-98-4)
[Sigma Aldrich]

2414-98-4(sigmaaldrich)
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