| Identification | More | [Name]
9-Fluorenemethanol | [CAS]
24324-17-2 | [Synonyms]
9-FLUORENEMETHANOL
9-FLUORENYLMETHANOL
9-FLUOROENYLMETHANOL
(9H-FLUOREN-9-YL)-METHANOL
9H-FLUORENE-9-METHANOL
9-(HYDROXYMETHYL)-FLUOREN
9-(HYDROXYMETHYL)FLUORENE
AKOS MSC-0133
(fluoren-9-yl)methanol
FLUORENE-9-METHANOL
FLUORENYL METHANOL
FM
FMOC-OH
FM-OH
FMOL
HOFM
TIMTEC-BB SBB008508
Fluorenemethanol
Fmoc-Oh(9-Fluorenylmethanol)
9-Fluorenylmethanol,98+% | [EINECS(EC#)]
246-167-5 | [Molecular Formula]
C14H12O | [MDL Number]
MFCD00001139 | [Molecular Weight]
196.24 | [MOL File]
24324-17-2.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO PALE YELLOW CRYSTALLINE POWDER | [Melting point ]
105-107 °C (lit.) | [Boiling point ]
293.14°C (rough estimate) | [density ]
1.0304 (rough estimate) | [refractive index ]
1.5385 (estimate) | [storage temp. ]
Store at 0-5°C | [solubility ]
Soluble in methanol. | [form ]
Crystalline Powder | [pka]
13.68±0.10(Predicted) | [color ]
White to pale yellow | [BRN ]
2330017 | [InChI]
InChI=1S/C14H12O/c15-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14-15H,9H2 | [InChIKey]
XXSCONYSQQLHTH-UHFFFAOYSA-N | [SMILES]
C1(CO)C2=C(C=CC=C2)C2=C1C=CC=C2 | [CAS DataBase Reference]
24324-17-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Fluorene-9-methanol(24324-17-2) | [EPA Substance Registry System]
24324-17-2(EPA Substance) |
| Questions And Answer | Back Directory | [Preparation]
In the presence of a catalyst, a hydrogen atom at the 9-position of fluorene is removed as a proton, and the resulting fluorene anion reacts with ethyl formate to produce 9-fluorenaldehyde. Using a reducing agent, 9-fluorenaldehyde is reduced to the crude product 9-Fluorenemethanol. |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H320-H402 | [Precautionary statements ]
P501-P273-P270-P264-P337+P313-P305+P351+P338-P301+P312+P330 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [TSCA ]
Yes | [HS Code ]
29062900 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO PALE YELLOW CRYSTALLINE POWDER | [Uses]
9-Fluorenylmethanol acts as a N-protecting reagent, which is used in the synthesis of peptide. It is also used in the preparation of deoxynucleoside 9-fluorenemethyl phosphorodithioates. Further, it is used to prepare 9-(fluoromethyl)fluorene. In addition to this, it is involved in the electropolymerization with boron trifluoride diethyl etherate to yield low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) film. | [Reactions]
Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film.
| [General Description]
Vibrational spectroscopy of jet-cooled 9-fluorenemethanol and its clusters 9-fluorenemethanol-H2O, 9-fluorenemethanol-CH3OH, 9-fluorenemethanol-C2H5OH and 9-fluorenemethanol-C3H7OH has been studied by IR-UV double-resonance method. Electropolymerization of 9-fluorenemethanol in boron trifluoride diethyl etherate leads to low-potential electrodeposition of semiconducting poly(9-fluorenemethanol) (PFMO) film. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|