ChemicalBook--->CAS DataBase List--->2680-03-7

2680-03-7

2680-03-7 Structure

2680-03-7 Structure
IdentificationMore
[Name]

N,N-Dimethylacrylamide
[CAS]

2680-03-7
[Synonyms]

DMAA
N,N-Dimethyl-2-propenamide
N,N-DIMETHYLACRYLAMIDE
NNDMA
TIMTEC-BB SBB008330
Acrylamide, N,N-dimethyl-
Acylamide, N,N-dimethyl
Dimethylamid kyseliny akrylove
dimethylamidkyselinyakrylove
n,n-dimethyl-2-propenamid
n,n-dimethyl-acrylamid
Propenamide, N,N-dimethyl-
sipomernndma
N,N-Dimethylacrylamide (99.5%)
N,N-Dimethylacrylamide,99.5%,stab.with100ppmMEHQ
2-Propenamide, N,N-dimethyl-
N,N-DIMETHYL ACRYLAMIDE (DMAA)
DIMETHYLACRYLAMIDE
N''N'' DIMETYL ACRYLAMIDE
1-(Dimethylamino)-2-propene-1-one
[EINECS(EC#)]

220-237-5
[Molecular Formula]

C5H9NO
[MDL Number]

MFCD00008626
[Molecular Weight]

99.13
[MOL File]

2680-03-7.mol
Chemical PropertiesBack Directory
[Melting point ]

100 °C
[Boiling point ]

80-81 °C/20 mmHg (lit.)
[density ]

0.962 g/mL at 25 °C(lit.)
[vapor pressure ]

65Pa at 20℃
[refractive index ]

n20/D 1.473(lit.)
[Fp ]

161 °F
[storage temp. ]

Keep in dark place,Sealed in dry,2-8°C
[form ]

Liquid
[pka]

-0.77±0.70(Predicted)
[color ]

Colorless to Light yellow
[Water Solubility ]

Slightly soluble in water (1.000 g/L at 20°C).
[FreezingPoint ]

-40℃
[Sensitive ]

Light Sensitive
[BRN ]

1742219
[Exposure limits]

ACGIH: TWA 5 mg/m3
NIOSH: TWA 5 mg/m3
[Cosmetics Ingredients Functions]

NOT REPORTED
[InChI]

1S/C5H9NO/c1-4-5(7)6(2)3/h4H,1H2,2-3H3
[InChIKey]

YLGYACDQVQQZSW-UHFFFAOYSA-N
[SMILES]

CN(C)C(=O)C=C
[LogP]

-0.3 at 23℃
[CAS DataBase Reference]

2680-03-7(CAS DataBase Reference)
[NIST Chemistry Reference]

2-propenamide, N,N-dimethyl(2680-03-7)
[EPA Substance Registry System]

2680-03-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
[Signal word ]

Danger
[Hazard statements ]

H301+H311-H318
[Precautionary statements ]

P264-P270-P280-P301+P310-P302+P352+P312-P305+P351+P338
[Hazard Codes ]

T,Xn
[Risk Statements ]

R21/22:Harmful in contact with skin and if swallowed .
R23:Toxic by inhalation.
R36:Irritating to the eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 2810 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

AU3230000
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29211990
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 3 Oral
Eye Dam. 1
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Dimethylamine
[Preparation Products]

Molosultap-->1-Boc-3-hydroxymethyl-piperazine-->Cartap hydrochloride-->3-Hydrazinyl-N,N-dimethylpropanamide-->4 7-Dimethoxy-1-indanone 97-->4-Biphenylylmethyl acrylate-->2H-1-Benzopyran-2-one, 6-chloro-4-hydroxy-3-Methyl--->Bromamide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

N,N-dimethyl acrylamide(2680-03-7).msds
Hazard InformationBack Directory
[Description]

N, N-dimethylacrylamide (DMAA) is an easily polymerized, nonionic monomer. The high reactivity and low initiation temperature of DMAA makes it appropriate for copolymerization. Copolymers of DMAA with N, N-dimethyl-N, and  N-diallyl ammonium chloride (DMDAAC) can be used as polymeric flocculants for water treatment. The unique structure of DMAA shows amelioration in hydrogels for specific applications. DMAA, along with other hydrogels, has a three-dimensional network structure that is capable of retaining water. In addition, DMAA hydrogel can be applied to remove toxic metal ions from wastewater because of its characteristic properties such as chemical stability and high adsorption capacity. DMAA can also be used for flocculation due to its ability to augment the molecular weight of the copolymers[1].
[Chemical Properties]

Colorless liquid
[Uses]

N,N-Dimethylacrylamide is a useful monomer for synthetic fibers and plastics. It is also used in the synthesis of photoresponsive polymers and copolymers by grafting polysiloxane on the side chain of DMA by homopolymerization or grafting cellulose to form cellulose polymers and copolymerization of methyl methacrylate with DMA or copolymerization of DMA with styrene and butadiene.
[Synthesis Reference(s)]

Journal of the American Chemical Society, 79, p. 875, 1957 DOI: 10.1021/ja01561a024
[General Description]

N,N-Dimethylacrylamide (DMA) is a nonionic acrylic monomer that can make swellable polymeric particles.
[References]

[1] Ayatzhan Akhmetzhan. “A Short Review on the N,N-Dimethylacrylamide-Based Hydrogels.” Gels 7 4 (2021).
Spectrum DetailBack Directory
[Spectrum Detail]

N,N-Dimethylacrylamide(2680-03-7)MS
N,N-Dimethylacrylamide(2680-03-7)1HNMR
N,N-Dimethylacrylamide(2680-03-7)13CNMR
N,N-Dimethylacrylamide(2680-03-7)IR1
N,N-Dimethylacrylamide(2680-03-7)IR2
N,N-Dimethylacrylamide(2680-03-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

N,N-Dimethylacrylamide, 99.5%, stab. with 100ppm 4-methoxyphenol(2680-03-7)
[Sigma Aldrich]

2680-03-7(sigmaaldrich)
[TCI AMERICA]

N,N-Dimethylacrylamide  (stabilized with MEHQ),>98.0%(T)(2680-03-7)
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