ChemicalBook--->CAS DataBase List--->290-87-9

290-87-9

290-87-9 Structure

290-87-9 Structure
IdentificationMore
[Name]

1,3,5-Triazine
[CAS]

290-87-9
[Synonyms]

1,3,5-TRIAZINE
DL-CYANIDINE
S-TRIAZINE
S-TRIAZINE (1,3,5)
TRIAZINE
1,3,5-Triazin
Cyanidine
sym-Triazine
Triazin(sym.)
Vedita 250
vedita250
1,3,5-Triazine (s-Triazine)
s-Triazin
MelaminePure
1,2,4-mercapto-2-methyl-6-oxo-3-hydroxy-5-triazine
[EINECS(EC#)]

206-028-1
[Molecular Formula]

C3H3N3
[MDL Number]

MFCD00006044
[Molecular Weight]

81.08
[MOL File]

290-87-9.mol
Chemical PropertiesBack Directory
[Melting point ]

77-83 °C (dec.)(lit.)
[Boiling point ]

114°C
[density ]

1,38 g/cm3
[refractive index ]

1.5060 (estimate)
[Fp ]

114°C
[storage temp. ]

2-8°C
[solubility ]

methanol: 0.1 g/mL, clear
[form ]

powder to crystal
[pka]

2.07±0.10(Predicted)
[color ]

White to Orange to Green
[Sensitive ]

Moisture Sensitive
[Merck ]

9602
[BRN ]

104790
[CAS DataBase Reference]

290-87-9(CAS DataBase Reference)
[NIST Chemistry Reference]

1,3,5-Triazine(290-87-9)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Exclamation Mark (GHS07)
GHS05,GHS07
[Signal word ]

Danger
[Hazard statements ]

H302-H315-H318-H335
[Precautionary statements ]

P280-P301+P312+P330-P302+P352-P305+P351+P338+P310
[Hazard Codes ]

Xn,C
[Risk Statements ]

R22:Harmful if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R34:Causes burns.
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S39:Wear eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
[RIDADR ]

UN2928
[WGK Germany ]

3
[RTECS ]

XY2957000
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29339900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

6-chloro-N2-phenyl-1,3,5-triazine-2,4-diamine-->2-Amino-1,3,5-triazine-->Methylamine nitrate-->Benzyl formimidate-hydrochloride-->Ethyl phenyl sulfone-->N-Methylformamide
[Preparation Products]

Metsulfuron methyl-->Tribenuron methyl-->2-Amino-4-methoxy-6-methyl-1,3,5-triazine-->Cinosulfuron-->4-Aminopyrimidine-5-carboxamide-->Terbutryn-->Formamidine hydrochloride-->9H-Pyrimido[4,5-b]indole-->1-Methyl-1,2,4-triazole-->2,4-Dichloro-1,3,5-triazine-->1,4,6-Triazaindene
Hazard InformationBack Directory
[Chemical Properties]

White crystal
[Application]

1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.
[Uses]

1,3,5-Triazine is a reagent in oxidation reactions, in synthesis of heterocycles. Triazine derivatives are used as herbicides, pharmaceuticals, complexation agents, peptidomimetic building blocks, and dyes.
[Uses]

1,3,5-Triazine is a useful replacement for HCN in the Gattermann reaction for the synthesis of aromatic aldehydes. It reacts with nucleophiles, e.g. amines, which is utilized in quinazoline synthesis.
[Definition]

1,3,5-Triazine, also known as s-triazine, is a six-membered ring organic compound, which is one of the isomers of triazine.
[Preparation]

Symmetrical 1,3,5-triazines are prepared by trimerization of certain nitriles such as cyanogen chloride or cyanimide. Benzoguanamine (with one phenyl and 2 amino substituents) is synthesised from benzonitrile and dicyandiamide. In the Pinner triazine synthesis (named after Adolf Pinner) the reactants are an alkyl or aryl amidine and phosgene. Insertion of an N-H moiety into a hydrazide by a copper carbenoid, followed by treatment with ammonium chloride also gives the triazine core.
Amine-substituted triazines called Guanamines are prepared by the condensation of cyanoguanidine with the corresponding nitrile:
(H2N)2C=NCN + RCN → (CNH2)2(CR)N3
Spectrum DetailBack Directory
[Spectrum Detail]

1,3,5-Triazine(290-87-9)MS
1,3,5-Triazine(290-87-9)1HNMR
1,3,5-Triazine(290-87-9)13CNMR
1,3,5-Triazine(290-87-9)IR1
1,3,5-Triazine(290-87-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1,3,5-Triazine, 97%(290-87-9)
[Sigma Aldrich]

290-87-9(sigmaaldrich)
[TCI AMERICA]

1,3,5-Triazine,>95.0%(GC)(N)(290-87-9)
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