| Identification | More | [Name]
[1-(Ethoxycarbonyl)ethyl]triphenylphosphonium bromide | [CAS]
30018-16-7 | [Synonyms]
1-CARBETHOXYETHYL TRIPHENYLPHOSPHONIUM BROMIDE
(1-ETHOXYCARBONYLETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
CARBOETHOXYETHYL TRIPHENYLPHOSPHONIUM BROMIDE
(2-ethoxy-1-methyl-2-oxoethyl)triphenylphosphonium bromide
carbethoxy Ethyl Triphenyl Phosphonium Bromide
(1-ETHOXYCARBONYLETHYL)TRIPHENYLPHOSPHONIUM BROMIDE 96%
1-Carbethoxyethyl triphenylphosphonium bromide 98%
(1-carboethoxyethyl)triphenylphosphonium bromide
ethyl 1-(triphenylphosphonio)propionate bromide
CEETPPB
PHOSPHONIUM,(2-ETHOXY-1-METHYL-2-OXOETHYL)TRIPHENYL-,BROMIDE
1-CARBETHOXYETHYLIDENE TRIPHENYLPHOSPONIUM BROMIDE
1-(Ethoxycarbonyl)ethyltriphenylphosphonium bromide, 96 %
[1-(ETHOXYCARBONYL)ETHYL]TRIPHENYL PHOSPHONIUM BROMIDE, 95+% | [EINECS(EC#)]
250-002-2 | [Molecular Formula]
C23H24BrO2P | [MDL Number]
MFCD00031605 | [Molecular Weight]
443.31 | [MOL File]
30018-16-7.mol |
| Chemical Properties | Back Directory | [Appearance]
White to off-white powder | [Melting point ]
152 °C | [storage temp. ]
Refrigerator (+4°C) | [solubility ]
Chloroform, Methanol | [form ]
Solid | [color ]
Pale Yellow | [Water Solubility ]
soluble | [Sensitive ]
Hygroscopic | [BRN ]
3822244 | [InChI]
InChI=1S/C23H24O2P.BrH/c1-3-25-23(24)19(2)26(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22;/h4-19H,3H2,1-2H3;1H/q+1;/p-1 | [InChIKey]
RSYXORMKBUFAMS-UHFFFAOYSA-M | [SMILES]
[P+](C1C=CC=CC=1)(C1C=CC=CC=1)(C1C=CC=CC=1)C(C)C(=O)OCC.[Br-] | [CAS DataBase Reference]
30018-16-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,Xn | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R29:Contact with water liberates toxic gas.
R22:Harmful if swallowed. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S8:Keep container dry .
S37/39:Wear suitable gloves and eye/face protection . | [Hazard Note ]
Irritant/Hygroscopic | [REACH Registrations]
Active | [HS Code ]
29310099 |
| Hazard Information | Back Directory | [Chemical Properties]
White to off-white powder | [Uses]
suzuki reaction | [Synthesis]
1.0 g of triphenylphosphine was dissolved in 15 mL of ethyl acetate and 0.55 mL of ethyl 2-bromopropionate was added to this solution. The reaction mixture was stirred at room temperature for 24 hours. Upon completion of the reaction, the bulk of the resulting white solid product was collected by diafiltration. The solids were washed with ethyl acetate to give a final 1.35 g of white solid product ethoxycarbonyl ethyltriphenylphosphonium bromide in 80.5% yield. | [References]
[1] European Journal of Organic Chemistry, 2016, vol. 2016, # 12, p. 2110 - 2114
[2] Chemistry - A European Journal, 2015, vol. 21, # 20, p. 7408 - 7412
[3] Tetrahedron, 2010, vol. 66, # 26, p. 4745 - 4759
[4] Journal of Organic Chemistry, 1984, vol. 49, # 22, p. 4293 - 4295
[5] Patent: CN103864753, 2016, B. Location in patent: Paragraph 0087; 0110-0111 |
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