ChemicalBook--->CAS DataBase List--->3458-72-8

3458-72-8

3458-72-8 Structure

3458-72-8 Structure
IdentificationMore
[Name]

2-Hydroxy-1,2,3-propanetricarboxylic acid triammonium salt
[CAS]

3458-72-8
[Synonyms]

AMMONIUM CITRATE
AMMONIUM CITRATE, DIBASIC
AMMONIUM HYDROGENCITRATE
CITRIC ACID AMMONIUM SALT
CITRIC ACID, AMMONIUM SALT, DIBASIC
CITRIC ACID, DIAMMONIUM
CITRIC ACID, DIAMMONIUM, DIBASIC
CITRIC ACID DIAMMONIUM SALT
DI-AMMONIUM HYDROGEN CITRATE
2,3-propanetricarboxylicacid,2-hydroxy-triammoniumsalt
Ammonium citrate tribasic anhydrous
Tri-AmmoniumCitrateGr
AmmoniumCitrateTribasicC6H17N3O7
Tri-AmmoniumCitrateExtraPure
Tri-Ammoniumcitrat
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, triammonium salt
2-Hydroxy-1,2,3-propanetricarboxylic acid triammonium salt
Triammonium citrate
Ammonium citrate tribasic, 97+%
CITRIC ACID, TRIAMMONIUM SALT, 97+%, PURE
[EINECS(EC#)]

221-146-3
[Molecular Formula]

C6H14N2O7
[MDL Number]

MFCD00013068
[Molecular Weight]

226.18
[MOL File]

3458-72-8.mol
Chemical PropertiesBack Directory
[Appearance]

Ammonium citrate (various forms) is a white powdery material with a slight ammonia-like odor.
[Melting point ]

185 °C (dec.) (lit.)
[Boiling point ]

100 °C (lit.)
[density ]

1 g/mL at 25 °C(lit.)
[vapor density ]

1.8 (vs air)
[vapor pressure ]

0Pa at 25℃
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

H2O: 1 M at 20 °C, clear, colorless
[form ]

Crystals
[color ]

White to off-white
[PH]

pH(40g/l, 25℃) : 6.0~7.7
[Stability:]

Stable. Incompatible with strong oxidizing agents.
[Water Solubility ]

Soluble in water. Slightly soluble in alcohol.
[BRN ]

3779194
[Major Application]

diagnostic assay manufacturing
[InChI]

1S/C6H8O7.3H3N/c7-3(8)1-6(13,5(11)12)2-4(9)10;;;/h13H,1-2H2,(H,7,8)(H,9,10)(H,11,12);3*1H3
[InChIKey]

YWYZEGXAUVWDED-UHFFFAOYSA-N
[SMILES]

N.N.N.OC(=O)CC(O)(CC(O)=O)C(O)=O
[LogP]

-1.43 at 25℃
[CAS DataBase Reference]

3458-72-8(CAS DataBase Reference)
[EPA Substance Registry System]

3458-72-8(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37:Irritating to eyes and respiratory system .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

GE7545000
[F ]

8
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29181500
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ammonia-->Citric acid
[Preparation Products]

AMMONIUM METATUNGSTATE
Hazard InformationBack Directory
[Potential Exposure]

It is used to make pharmaceuticals; rust-proofing compounds and plasticizers; as a food additive; stabilizing agent.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Contact with strong caustics causes the release of ammonia gas.
[Chemical Properties]

Ammonium citrate (various forms) is a white powdery material with a slight ammonia-like odor.
[Chemical Properties]

white crystalline powder
[Waste Disposal]

May be flushed to sewer with large volumes of water.
[Uses]

Ammonium citrate tribasic is mainly used for chemical analysis, in industry for water treatment, in food industry for buffering agent and emulsifier, for metal surface cleaning (in particular petroleum pipeline cleaning), as a ceramic dispersant,as auxiliary infiltration agent, as detergent material and as soil improvement agent component.Ammonium citrate tribasic is applied in electroplating industry for non cyanide plating complexing agent, used mostly for preparing anti rust agent in machinery industry and as buffering agent. It serves as a chemical reagent in analytical chemistry to determine the efficient phosphate levels in phosphate salts and fertilizer.
[Definition]

ChEBI: A citrate salt in which all three carboxy groups are deprotonated and associated with ammonium ions as counter-cations.
[Agricultural Uses]

Ammonium citrate is a white, granular, water-soluble salt of ammonia and citric acid. It is used in a neutral solution for determining the phosphorus content of phosphate fertilizers (such as calcium hydrogen phosphate (CaHPO4)), that are insoluble in water but dissolve in complexing citrate solutions.
The fertilizer residue, after extraction of watersoluble phosphorus, is re-extracted with a neutral or strongly alkaline solution of 1 normal (1N) ammonium citrate for a prescribed period, and the slurry filtered. Citrate-soluble phosphorus is the phosphorus content in the filtrate and is expressed as a percentage by weight of the fertilizer.
The extraction of phosphate with 1N ammonium citrate is carried out routinely for 30 minutes, first at room temperature and then at 4O℃ For neutral ammonium citrate solution, a temperature of 65℃ is preferred.
Some European countries use an alkaline ammonium citrate solution, which extracts smaller amounts of phosphorus. Some experts consider it to be better correlated with phosphorus uptake and plant growth. However, most countries use a neutral normal ammonium citrate solution for extracting citrate soluble phosphorus.
[Industrial uses]

Ammonium citrate tribasic can serve as an effective leaching agent for extracting lead from lead oxide ore. It has been reported that, under conditions of 800 r/min and 40°C, leaching with a 1.25 mol/L solution of ammonium citrate tribasic for 21 minutes can extract approximately 95% of the lead content from samples with a particle size range of +75 to 96 μm[1].
[References]

[1] Jun-bo Liu. (2018). Evaluation of ammonium citrate tribasic as a leaching reagent for a lead-bearing ore. Physicochemical Problems of Mineral Processing, 55 1, 689–700. https://doi.org/10.5277/ppmp18183
Spectrum DetailBack Directory
[Spectrum Detail]

Ammonium citrate tribasic(3458-72-8)1HNMR
Ammonium citrate tribasic(3458-72-8)IR1
Ammonium citrate tribasic(3458-72-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Citric acid, triammonium salt, pure, 97+%(3458-72-8)
[Alfa Aesar]

Ammonium citrate tribasic, 97+%(3458-72-8)
[Sigma Aldrich]

3458-72-8(sigmaaldrich)
3458-72-8 suppliers list
Company Name: Jiangsu Kolod Food Ingredients Co.,Ltd.  Gold
Telephone: 0518-85110930; 18861330168
Website: http://www.jskolod.com
Company Name: Lianyungang Kexin Chemical Co., Ltd.  Gold
Telephone: 518-85112285 18861332669
Website: www.kolodcn.com
Company Name: Yonghua Chemical Co., Ltd.  Gold
Telephone: 0512-52549999 13706235395
Website: https://www.yonghuachem.com
Company Name: J & K SCIENTIFIC LTD.  
Telephone: 18210857532 18210857532
Website: https://www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: future industrial shanghai co., ltd  
Telephone: 400-0066400 13621662912
Website: http://www.jonln.com
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: Beijing HwrkChemical Technology Co., Ltd  
Telephone: 89508211 18501085097
Website: http://www.hwrkchemical.com
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: Beijing Ouhe Technology Co., Ltd  
Telephone: 13552068683 13522913783
Website: www.ouhetech.cn/
Company Name: Adamas Reagent, Ltd.  
Telephone: 400-6009262 15618770481
Website: www.tansoole.com
Company Name: Shanghai Hanhong Scientific Co.,Ltd.  
Telephone: 021-54306202 13764082696
Website: https://www.hanhongsci.com
Company Name: Shandong Xiya Chemical Co., Ltd  
Telephone: 13355009207 13355009207
Website: http://www.xiyashiji.com
Company Name: Sichuan Kulinan Technology Co., Ltd  
Telephone: 400-1166-196 18981987031
Website: http://www.hx-r.com/
Company Name: China Langchem Inc.  
Telephone: 0086-21-58956006
Website: www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm
Company Name: Tianjin heowns Biochemical Technology Co., Ltd.  
Telephone: 400 638 7771
Website: www.heowns.com
Company Name: Sinopharm Chemical Reagent Co,Ltd.  
Telephone: 86-21-63210123
Website: www.reagent.com.cn
Company Name: Hunan Hui Bai Shi Biotechnology Co., Ltd.  
Telephone: 0731-85526065 13308475853
Website: http://www.hnhbsj.com/
Tags:3458-72-8 Related Product Information
6132-04-3 1185-57-5 53798-97-3 813-93-4 5949-29-1 6132-05-4 114456-61-0 1642-54-2 77-92-9 3012-65-5 3458-72-8 144-29-6 139755-83-2 1336-80-7 112885-42-4