| Identification | More | [Name]
tert-Butyl(triphenylphosphoranylidene)acetate | [CAS]
35000-38-5 | [Synonyms]
LABOTEST-BB LT00233234
(TERT-BUTOXYCARBONYLMETHYLENE)TRIPHENYLPHOSPHORANE
TERT-BUTYL (TRIPHENYLPHOSPHORANYLIDENE)ACETATE
(TRIPHENYL-LAMBDA5-PHOSPHANYLIDENE)-ACETIC ACID TERT-BUTYL ESTER
(tert-butoxycarbonylmethylene)triphenyl-phosphora
tert-Butyl (triphenylphosphoranylidene)acetate~(Carbo-tert-butoxymethylene)triphenylphosphorane
TRIPHENYLPHORANYLIDENE ACETIC ACID 1,1-DIMETHYLETHYL ESTER
(Carbo-tert-butoxymethylene)triphenylphosphorane
Triphenylphoranylidene
Acetic acid, (triphenylphosphoranylidene)-, 1,1-dimethylethyl ester
(tert-butoxycarbonylmethylene)triphenylphosphorane, 98 %
tert-Butyl 2-tri(phenyl)phosphoranylideneacetate | [EINECS(EC#)]
412-880-7 | [Molecular Formula]
C24H25O2P | [MDL Number]
MFCD00075545 | [Molecular Weight]
376.43 | [MOL File]
35000-38-5.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystalline powder | [Melting point ]
152-155 °C(lit.)
| [Boiling point ]
503.5±33.0 °C(Predicted) | [density ]
1.203(20.0000℃) | [storage temp. ]
Refrigerator (+4°C) | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
Crystalline Powder | [color ]
White | [Water Solubility ]
Sparingly soluble in water. | [BRN ]
2759875 | [InChI]
InChI=1S/C24H25O2P/c1-24(2,3)26-23(25)19-27(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-19H,1-3H3 | [InChIKey]
ZWZUFQPXYVYAFO-UHFFFAOYSA-N | [SMILES]
C(OC(C)(C)C)(=O)C=P(C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1 | [CAS DataBase Reference]
35000-38-5(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
  
GHS06,GHS08,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H301-H317-H319-H373-H411 | [Precautionary statements ]
P273-P280-P301+P310+P330-P302+P352-P305+P351+P338-P314 | [Hazard Codes ]
T,N | [Risk Statements ]
R25:Toxic if swallowed.
R36:Irritating to the eyes.
R43:May cause sensitization by skin contact.
R48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3464 6.1/PG 2
| [WGK Germany ]
3
| [REACH Registrations]
Active | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
29319090 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral
Aquatic Chronic 2
Eye Irrit. 2
Skin Sens. 1
STOT RE 2 |
| Hazard Information | Back Directory | [Chemical Properties]
white crystalline powder | [Uses]
(tert-Butoxycarbonylmethylene)triphenylphosphorane is a chemical used in the synthesis of aldose reductase inhibitors, a podophyllotoxin derivative and tautomycin, a podophyllotoxin derivative and tautomycin. It Is also used in medicinal chemistry. | [Definition]
ChEBI: Tert-butyl (triphenylphosphoranylidene)acetate is a phosphine. | [reaction suitability]
reaction type: C-C Bond Formation |
|
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