| Identification | More | [Name]
TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE)RUTHENIUM (II) DICHLORIDE | [CAS]
36309-88-3 | [Synonyms]
BATHOPHENANTHROLINE RUTHENIUM CHLORIDE
BATHOPHENANTHROLINE RUTHENIUM DICHLORIDE
TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE) RUTHENIUM (II) CHLORIDE
TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE)RUTHENIUM (II) DICHLORIDE
TRIS(4,7-DIPHENYL-1,10-PHENANTHROLIN)RUTHENIUM DICHLORIDE COMPLEX
TRIS(4,7-DIPHENYL-1,10-PHENANTHROLIN)RUTHENIUM(II) DICHLORIDE COMPLEX
TRIS-(BATHOPHENANTHROLINE) RUTHENIUM (II) CHLORIDE
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium(II) dichloride complex
TRIS(4,7-DIPHENYLPHENANTHROLIN)RUTHENIUM(II) CL2 COMPLEX*
TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE)RUTHENIUM(III)DICHLORIDECOMPLEX
Ruthenium II tris(4,7-diphenyl-1,10-phenanthroline) chloride | [Molecular Formula]
C72H48Cl2N6Ru | [MDL Number]
MFCD03095387 | [Molecular Weight]
1169.17 | [MOL File]
36309-88-3.mol |
| Chemical Properties | Back Directory | [Melting point ]
275-279°C (dec.) | [Fp ]
>110°C | [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
DMF: soluble
| [form ]
Powder | [color ]
Light yellow to orange | [Water Solubility ]
Soluble in alcohol and dimethylformamide. Insoluble in water. | [InChI]
InChI=1S/3C24H16N2.2ClH.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;;;/h3*1-16H;2*1H;/q;;;;;+2/p-2 | [InChIKey]
SKZWFYFFTOHWQP-UHFFFAOYSA-L | [CAS DataBase Reference]
36309-88-3(CAS DataBase Reference) |
| Safety Data | Back Directory | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S24/25:Avoid contact with skin and eyes . | [RIDADR ]
3261 | [WGK Germany ]
3
| [F ]
8-10 | [TSCA ]
No | [HS Code ]
29339900 |
| Hazard Information | Back Directory | [Description]
Tris(4,7-diphenyl-1,10-phenanthroline)ruthenium II dichloride complex is a luminescent probe (absorption λmax: 455 nm, luminescence λmax: 613 nm) widely used for detection and quantitation of oxygen.1 The dye is strongly reduced by molecular oxygen as a result of dynamic quenching; thus oxygen detection can be based on either measurement of intensity or decay time.2 This oxygen probe has been used to optimize optical oxygen sensors, to measure oxygen flux through tissues and in skin tumors, and for oxygen imaging.1,3,4,5,6 | [References]
[1] H. . KIM. Synthesis of tris (4,7 -diphenyl -1,10 -phenanthroline )ruthenium (II) complexes possessing a linker arm for use in sol-gel-based optical oxygen sensor[J]. Bulletin of The Korean Chemical Society, 2006, 3 1: 2084-2086. DOI: 10.5012/bkcs.2006.27.12.2084
[2] PAUL. HARTMANN Max E L Marc J P Leiner. Luminescence Quenching Behavior of an Oxygen Sensor Based on a Ru(II) Complex Dissolved in Polystyrene[J]. Analytical Chemistry, 1995, 67 1: 88-93. DOI: 10.1021/ac00097a015
[3] WL RUMSEY DF W JM Vanderkooi. Imaging of phosphorescence: a novel method for measuring oxygen distribution in perfused tissue[J]. Science, 1988, 241 4873. DOI: 10.1126/science.241.4873.1649
[4] G. LIEBSCH. Luminescence Lifetime Imaging of Oxygen, pH, and Carbon Dioxide Distribution Using Optical Sensors[J]. Applied Spectroscopy, 2000, 1 1: 548-559. DOI: 10.1366/0003702001949726
[5] J. R. BACON J. N D. Determination of oxygen concentrations by luminescence quenching of a polymer-immobilized transition-metal complex[J]. Analytical Chemistry, 1987, 59 23: 2780-2785. DOI: 10.1021/ac00150a012
[6] INGO. KLIMANT Otto S W. Oxygen-Sensitive Luminescent Materials Based on Silicone-Soluble Ruthenium Diimine Complexes[J]. Analytical Chemistry, 1995, 67 18: 3160-3166. DOI: 10.1021/ac00114a010 |
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