ChemicalBook--->CAS DataBase List--->3658-80-8

3658-80-8

3658-80-8 Structure

3658-80-8 Structure
IdentificationMore
[Name]

Dimethyl trisulfide
[CAS]

3658-80-8
[Synonyms]

DIMETHYL TRISULFIDE
DIMETHYL TRISULPHIDE
FEMA 3275
METHYL TRISULFIDE
METHYL TRITHIO METHANE
1,3-Dimethyltrisulfane
2,3,4-Trithiapentane
CH3SSSCH3
dimethyl trisufide
DMTS
Trisulfide,dimethyl
DIMETHYL TRISULFIDE 98+%
Trimethyl trisulfide, 98+%
Dimethyl pertrisulfide
Dimethyltrisulfane
[EINECS(EC#)]

222-910-9
[Molecular Formula]

C2H6S3
[MDL Number]

MFCD00039808
[Molecular Weight]

126.26
[MOL File]

3658-80-8.mol
Chemical PropertiesBack Directory
[Appearance]

clear yellow liquid
[Melting point ]

−68 °C(lit.)
[Boiling point ]

58 °C15 mm Hg(lit.)
[density ]

1.202 g/mL at 25 °C(lit.)
[FEMA ]

3275
[refractive index ]

n20/D 1.602(lit.)
[Fp ]

133 °F
[storage temp. ]

Store at -20°C
[solubility ]

Chloroform (Sparingly), Methanol (Slightly)
[form ]

Liquid
[color ]

Clear yellow
[Odor]

at 0.10 % in propylene glycol. sulfurous cooked onion savory meaty
[biological source]

synthetic
[Odor Type]

alliaceous
[Water Solubility ]

Insoluble in water.
[JECFA Number]

582
[BRN ]

1731604
[Major Application]

flavors and fragrances
[InChI]

1S/C2H6S3/c1-3-5-4-2/h1-2H3
[InChIKey]

YWHLKYXPLRWGSE-UHFFFAOYSA-N
[SMILES]

CSSSC
[LogP]

2.93
[CAS DataBase Reference]

3658-80-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Trisulfide, dimethyl(3658-80-8)
[EPA Substance Registry System]

3658-80-8(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Warning
[Hazard statements ]

H226-H302-H315-H319-H335
[Precautionary statements ]

P210-P301+P312+P330-P302+P352-P305+P351+P338
[Hazard Codes ]

Xn
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R36/38:Irritating to eyes and skin .
R20/22:Harmful by inhalation and if swallowed .
R10:Flammable.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[F ]

10-23
[TSCA ]

Yes
[HazardClass ]

3.2
[PackingGroup ]

III
[HS Code ]

29309090
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

clear yellow liquid
[Chemical Properties]

Dimethyl trisulfide has a powerful, diffusive, penetrating odor reminiscent of fresh onion
[Occurrence]

Reported as occurring in the volatile portion of fresh onion juice; the major aroma component in cooked vegetables of the Brassica genus. Also reported found in kohlrabi, cabbage, onion, garlic, shallots, leek, peas, mustard, tomato, wheaten bread, cheeses, milk, cooked chicken, pork, beef, hop oil, beer, brandies, whiskey, sherry, grape wine, cocoa, coffee, roasted peanuts, mushrooms, broccoli, cauliflower, brussels sprouts, radishes, pumpkin, sweet corn, asparagus, black tea, shellfish and squid.
[Uses]

Dimethyl trisulfide is reported as a major aroma component in cooked Brassicaceous vegetables. Trap baits containing dimethyl trisulfide have been used to capture Calliphora loewi and other blowflies. Dimethyl trisulfide along with dimethyl sulfide and dimethyl disulfide have been confirmed as volatile compounds given off by the fly-attracting plant known as dead-horse arum (Helicodiceros muscivorus). These flies are attracted to the odor of fetid meat and help pollinate this plant.
[Definition]

ChEBI: Dimethyl trisulfide is an organic trisulfide.
[Preparation]

It is produced by the microorganism, L. cremoris S2.
[Taste threshold values]

Taste characteristics at 2.0 ppm: sulfureous, alliaceous, gassy, savory and meaty with a fresh, vegetative nuance
[Synthesis Reference(s)]

Tetrahedron Letters, 30, p. 2995, 1989 DOI: 10.1016/S0040-4039(00)99178-0
[storage]

Store at -20°C
Spectrum DetailBack Directory
[Spectrum Detail]

Dimethyl trisulfide(3658-80-8)1HNMR
Dimethyl trisulfide(3658-80-8)FT-IR
Dimethyl trisulfide(3658-80-8)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Dimethyl trisulfide, 98+%(3658-80-8)
[Sigma Aldrich]

3658-80-8(sigmaaldrich)
[TCI AMERICA]

Dimethyl Trisulfide,>98.0%(GC)(3658-80-8)
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