ChemicalBook--->CAS DataBase List--->367-11-3

367-11-3

367-11-3 Structure

367-11-3 Structure
IdentificationMore
[Name]

1,2-Difluorobenzene
[CAS]

367-11-3
[Synonyms]

1,2-DIFLUOROBENZENE
O-DIFLUOROBENZENE
1,2-Difluorbenzol
1,2-difluroethylene
Benzene, o-difluoro-
benzene,1,2-difluoro-
Benzene,o-difluoro-
difluorobenzene
o-difluoro-benzen
ortho-Difluorobenzene
2-Difluorobenzene
1,2-Difluorobenzene,98+%
o-Difluorobenzene,99%
1,2-Difluorobenzene 98%
1,2-Dfluorobenzene
[EINECS(EC#)]

206-680-7
[Molecular Formula]

C6H4F2
[MDL Number]

MFCD00000284
[Molecular Weight]

114.09
[MOL File]

367-11-3.mol
Chemical PropertiesBack Directory
[Appearance]

colourless liquid
[Melting point ]

−34 °C(lit.)
[Boiling point ]

92 °C(lit.)
[density ]

1.158 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.443(lit.)
[Fp ]

36 °F
[storage temp. ]

Flammables area
[solubility ]

Chloroform, Methanol
[form ]

Liquid
[color ]

Clear colorless
[Specific Gravity]

1.158
[Stability:]

Stable. Incompatible with strong oxidizing agents. Highly flammable. Note low flash point.
[Water Solubility ]

Not miscible or difficult to mix in water.
[BRN ]

1905113
[Dielectric constant]

14.26
[CAS DataBase Reference]

367-11-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzene, 1,2-difluoro-(367-11-3)
[Storage Precautions]

Heat sensitive
[EPA Substance Registry System]

367-11-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

F,Xn
[Risk Statements ]

R11:Highly Flammable.
R20:Harmful by inhalation.
[Safety Statements ]

S7:Keep container tightly closed .
S16:Keep away from sources of ignition-No smoking .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S7/9:Keep container tightly closed and in a well-ventilated place .
[RIDADR ]

UN 1993 3/PG 2
[WGK Germany ]

3
[RTECS ]

CZ5655000
[Hazard Note ]

Flammable
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29036990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Fluoroboric acid
[Preparation Products]

2,3-Difluorophenylboronic acid-->Benzeneacetonitrile, 2-fluoro-alpha,alpha-dimethyl--->2-Chloro-1-(3,4-difluoro-phenyl)-ethanone-->2,3-Difluorobenzaldehyde-->2,3-Difluorophenol-->CHEMBRDG-BB 4003866-->(S)-2-(3,4-Difluorophenyl)oxirane-->1,2-difluoro-4,5-dinitrobenzene-->(1R,2R)-2-(3,4-difluorophenyl)cyclopropane carboxaMide-->4,7-Bis(5-broMothiophen-2-yl)-5,6-difluorobenzo[c][1,2,5] thiadiazole-->(1S)-2-chloro-1-(3,4-difluorophenyl)-1-ethanol-->(1R,2R)-2-(3,4-difluorophenyl)cyclopropanecarboxylic acid-->2-Bromo-4,5-difluorobenzonitrile-->3,4-Difluorobenzyl chloride-->METHYL 3,4-DIFLUOROBENZOATE-->1,4-DIBROMO-2,3-DIFLUOROBENZENE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,2-Difluorobenzene(367-11-3).msds
Hazard InformationBack Directory
[Chemical Properties]

colourless liquid
[Uses]

1,2-Difluorobenzene is used in electrochemical analysis of transition metal complexes. 1,2-difluorobenzene is also a potent inhibitor of NMDA receptor.
[Definition]

ChEBI: A difluorobenzene carrying fluoro groups at positions 1 and 2.
[General Description]

1,2-Difluorobenzene undergoes defluorination under very mild conditions by H2 in the presence of NaOAc over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst.
Spectrum DetailBack Directory
[Spectrum Detail]

1,2-Difluorobenzene(367-11-3)MS
1,2-Difluorobenzene(367-11-3)1HNMR
1,2-Difluorobenzene(367-11-3)13CNMR
1,2-Difluorobenzene(367-11-3)IR1
1,2-Difluorobenzene(367-11-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,2-Difluorobenzene, 98%(367-11-3)
[Alfa Aesar]

1,2-Difluorobenzene, 98+%(367-11-3)
[Sigma Aldrich]

367-11-3(sigmaaldrich)
[TCI AMERICA]

1,2-Difluorobenzene,>98.0%(GC)(367-11-3)
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