| Identification | More | [Name]
Leaf acetate | [CAS]
3681-71-8 | [Synonyms]
ACETIC ACID CIS-3-HEXEN-1-YL ESTER
ACETIC ACID CIS-3-HEXENYL ESTER
C3 HEXENYL ACETATE
CIS-3-HEXEN-1-YL ACETATE
CIS-3-HEXENYL ACETATE
FEMA 3171
HEX-3(CIS)-ENYL ACETATE
LEAF ACETATE
VERDURAL
(Z)-3-HEXENYL ACETATE
(3Z)-3-Hexenyl acetate
(Z)-3-hexen-1-ol acetate
(Z)-3-Hexen-1-yl, acetate
(Z)-3-hexenol acetate
(Z)-hex-3-en-1-yl acetate
(Z)-Hex-3-enyl acetate
3(Z)-hexenyl acetate
3-Hexen-1-ol,acetate,(Z)-
3-Hexenol acetate, cis
3-hexenylacetate | [EINECS(EC#)]
222-960-1 | [Molecular Formula]
C4H6O4Pb | [MDL Number]
MFCD00036563 | [Molecular Weight]
325.29 | [MOL File]
3681-71-8.mol |
| Chemical Properties | Back Directory | [Boiling point ]
75-76 °C23 mm Hg(lit.) | [density ]
0.897 g/mL at 25 °C(lit.)
| [vapor pressure ]
2.14hPa at 25℃ | [FEMA ]
3171 | [refractive index ]
n20/D 1.427(lit.)
| [Fp ]
135 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
neat | [color ]
Colorless to Almost colorless | [Odor]
at 10.00 % in dipropylene glycol. fresh green sweet fruity banana apple grassy | [biological source]
synthetic | [Odor Type]
green | [Water Solubility ]
1.11g/L at 20℃ | [JECFA Number]
134 | [BRN ]
1721854 | [Henry's Law Constant]
3.1×10-2 mol/(m3Pa) at 25℃, Karl et al. (2003) | [Major Application]
flavors and fragrances | [Cosmetics Ingredients Functions]
FRAGRANCE
PERFUMING
FLAVOURING | [InChI]
1S/C8H14O2/c1-3-4-5-6-7-10-8(2)9/h4-5H,3,6-7H2,1-2H3/b5-4- | [InChIKey]
NPFVOOAXDOBMCE-PLNGDYQASA-N | [SMILES]
[H]\C(CC)=C(/[H])CCOC(C)=O | [LogP]
2.7 at 30℃ | [CAS DataBase Reference]
3681-71-8(CAS DataBase Reference) | [NIST Chemistry Reference]
3-Hexen-1-ol, acetate, (Z)-(3681-71-8) | [EPA Substance Registry System]
3681-71-8(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS02 | [Signal word ]
Warning | [Hazard statements ]
H226 | [Precautionary statements ]
P210-P233-P240-P241-P242-P243 | [Risk Statements ]
R36/38:Irritating to eyes and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3272 3/PG 3
| [WGK Germany ]
2
| [RTECS ]
MP8425050
| [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29153900 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Flam. Liq. 3 | [Toxicity]
Both the acute oral LD50 value in
rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Wohl, 1974). |
| Hazard Information | Back Directory | [Description]
cis-3-Hexen-1 -y 1-acetate has a powerful green, floral note reminiscent of banana. It may be prepared by acetylation of the corresponding alcohol. | [Chemical Properties]
(Z)-3-Hexenyl Acetate has been identified in many fruit aromas and
green tea. It is a prototype for green odors and is often used in combination with
(Z)-3-hexenol. | [Chemical Properties]
cis-3-Hexen-1-yl acetate has a powerful, green, fruity, floral note reminiscent of banana.
| [Chemical Properties]
Colorless liquid | [Occurrence]
Reported found in apple, bilberry, guava, strawberry, black and green tea, yellow and purple passion fruit,
citrus peel oils, melon, peach, raspberry, pear, pineapple, melon, celery, tomato, corn mint oil, spearmint oil, brandies, grape wines,
soybeans, olive, plum, plumcot, starfruit, mango, cauliflower, dill, lovage, corn oil, nectarines, Chinese quince and chamomile oil. | [Uses]
Leaf Acetate increased leaf-feeding herbivores’ egg predation rates by a generalist predator. As a consequence, a plant could reduce the number of herbivores by more than 90% by releasing volatiles. | [Definition]
ChEBI: An acetate ester that results from the formal condensation of acetic acid with (Z)-hex-3-en-1-ol. | [Preparation]
By acetylation of the corresponding alcohol
| [Taste threshold values]
Taste characteristics at 10 ppm: green, fruity, apple and pear with fresh tropical nuances | [Synthesis Reference(s)]
Canadian Journal of Chemistry, 65, p. 2327, 1987 DOI: 10.1139/v87-388 | [Flammability and Explosibility]
Flammable |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
jiliang chemicals
|
| Telephone: |
21-62165282 |
| Website: |
http://www.jiliangchem.com |
|