| Identification | Back Directory | [Name]
Tris[2-(4,6-difluorophenyl)pyridinato-C2,N]iridium(III)
| [CAS]
387859-70-3 | [Synonyms]
Ir(Fppy)3
Ir(4,6Fppy)3
Tris(2-(4,6-difuorophenyl)pyridine)iridium(III) | [Molecular Formula]
C33H18F6IrN3 | [MDL Number]
MFCD09842738 | [MOL File]
387859-70-3.mol | [Molecular Weight]
762.74 |
| Chemical Properties | Back Directory | [Melting point ]
401 °C | [storage temp. ]
under inert gas (nitrogen or Argon) at 2–8 °C | [form ]
Powder | [color ]
yellow | [Sensitive ]
air sensitive | [λmax]
347 nm | [InChI]
InChI=1S/3C11H6F2N.Ir/c3*12-8-4-5-9(10(13)7-8)11-3-1-2-6-14-11;/h3*1-4,6-7H;/q3*-1;+3 | [InChIKey]
GJHHESUUYZNNGV-UHFFFAOYSA-N | [SMILES]
FC1C=C(F)C=[C-]2[Ir+3]34(N5=CC=CC=C5C5=C(C=C(F)C=[C-]35)F)(N3=CC=CC=C3C3=C(C=C(F)C=[C-]43)F)N3=CC=CC=C3C=12 |
| Questions And Answer | Back Directory | [Reaction]
- Photoredox catalysis for trifluoromethylation of arenes and heteroarenes.
- Photocatalyst for C–F alkenylation coupling reactions between perfluoroarenes and alkynes.
|
| Hazard Information | Back Directory | [Uses]
Ir(dFppy)3 is a photocatalyst that readily facilitates the decarboxylative arylation of α amino acids using visible light. | [reaction suitability]
core: iridium
reaction type: Photocatalysis
reagent type: catalyst |
|
| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Tel: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
| Company Name: |
LaaJoo
|
| Tel: |
021-60702684 18516024827 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
|