ChemicalBook--->CAS DataBase List--->870987-63-6

870987-63-6

870987-63-6 Structure

870987-63-6 Structure
IdentificationBack Directory
[Name]

hexafluorophosphate
[CAS]

870987-63-6
[Synonyms]

Ir[dF(CF3)ppy]2(dtbbpy)PF6
4-tert-butyl-2-(4-tert-butyl-2-pyridyl)pyridine
bis[3,5-Difluoro-2-[5-(trifluoromethyl)-2-pyridyl]phenyl]ruthenium(1+)
(4,4'-Di-t-butyl-2,2'-bipyridine)bis[3,5-difluoro-2-[5-trifluoromethyl-2-pyridinyl-kN)phenyl-kC]iridium(III) hexafluorophosphate
[Molecular Formula]

C42H34F16IrN4P
[MDL Number]

MFCD27952556
[MOL File]

870987-63-6.mol
[Molecular Weight]

144.964
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[storage temp. ]

Inert atmosphere,2-8°C
[solubility ]

Chloroform (Slightly)
[form ]

crystal
[color ]

yellow
[CAS DataBase Reference]

870987-63-6
Safety DataBack Directory
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[TSCA ]

No
Questions And AnswerBack Directory
[Reaction]

  1. Visible light photoredox-catalyzed cascade cyclizations of α-bromochalcones or α-bromocinnamates with heteroarenes.
  2. Enantioselective α-benzylation of aldehydes via photoredox organocatalysis.
Reactions of 870987-63-6
Hazard InformationBack Directory
[Uses]

(Ir[dF(CF3)ppy]2(dtbpy))PF6 is a cyclometalated iridium(III) complex that can be used in visible-light mediated photocatalytic organic transformations.It has been used to achieve late-stage incorporation of alkyl groups to a variety of biologically active heterocycles.
Spectrum DetailBack Directory
[Spectrum Detail]

hexafluorophosphate(870987-63-6)1HNMR
hexafluorophosphate(870987-63-6)31PNMR
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