ChemicalBook--->CAS DataBase List--->3934-87-0

3934-87-0

3934-87-0 Structure

3934-87-0 Structure
IdentificationMore
[Name]

5-Hydroxyvanillin
[CAS]

3934-87-0
[Synonyms]

3,4-DIHYDROXY-5-METHOXYBENZALDEHYDE
5-hydroxyvanillin
5-METHOXY-3,4-DIHYDROXYBENZALDEHYDE
AKOS BBS-00007007
3,4-dihydroxy-5-methoxy-benzaldehyd
5-methoxy-protocatechualdehyd
5-Methoxyprotocatechualdehyde
Benzaldehyde, 3,4-dihydroxy-5-methoxy-
Protocatechualdehyde, 5-methoxy-
3,4-Dihydroxy-5-methoxybenzaldehdye
3-METHOXY-4,5-DIHYDROXYBENZALDEHYDE
4,5-Dihydroxy-3-methoxybenzaldehyde
[EINECS(EC#)]

223-513-3
[Molecular Formula]

C8H8O4
[MDL Number]

MFCD00016610
[Molecular Weight]

168.15
[MOL File]

3934-87-0.mol
Chemical PropertiesBack Directory
[Melting point ]

131-134°C
[Boiling point ]

339.9±37.0 °C(Predicted)
[density ]

1.378±0.06 g/cm3(Predicted)
[storage temp. ]

Inert atmosphere,2-8°C
[form ]

solid
[pka]

7.63±0.23(Predicted)
[color ]

Light grey/ brown
[Cosmetics Ingredients Functions]

HAIR DYEING
[InChI]

InChI=1S/C8H8O4/c1-12-7-3-5(4-9)2-6(10)8(7)11/h2-4,10-11H,1H3
[InChIKey]

RRKMWVISRMWBAL-UHFFFAOYSA-N
[SMILES]

C(=O)C1=CC(OC)=C(O)C(O)=C1
[LogP]

1.050 (est)
[CAS DataBase Reference]

3934-87-0(CAS DataBase Reference)
[NIST Chemistry Reference]

3,4-Dihydroxy-5-methoxybenzaldehyde(3934-87-0)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

CU5620000
[HS Code ]

2912490090
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Copper-->Vanillin-->5-Bromovanillin
[Preparation Products]

8-Methoxy-2,3-dihydro-1,4-benzodioxine-6-carbaldehyde
Hazard InformationBack Directory
[Chemical Properties]

Crystallized. Melting point 130-131°C (132.5-134°C).
[Uses]

3,4-Dihydroxy-5-methoxybenzaldehyde may be used for the preparation of 3,4-dihydroxy-6-methoxy-β-nitrostyrene and 5-hydroxyconiferyl alcohol.
[Synthesis Reference(s)]

Synthetic Communications, 18, p. 507, 1988 DOI: 10.1080/00397918808060744
[General Description]

3,4-Dihydroxy-5-methoxybenzaldehyde can be obtained by reactting 5-iodovaniliin with sodium hydroxide and copper sulfate solution.
[Synthesis]

The bromination reaction of vanillal and bromine generate 5-bromovanillal, which is then reacted with sodium hydroxide solution under the participation of copper powder to give 5-Hydroxyvanillin.
Spectrum DetailBack Directory
[Spectrum Detail]

5-Hydroxyvanillin(3934-87-0)1HNMR
5-Hydroxyvanillin(3934-87-0)IR
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

3934-87-0(sigmaaldrich)
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