ChemicalBook--->CAS DataBase List--->467-69-6

467-69-6

467-69-6 Structure

467-69-6 Structure
IdentificationMore
[Name]

9-Hydroxy-9-fluorenecarboxylic acid
[CAS]

467-69-6
[Synonyms]

9-HYDROXY-9-FLUORENECARBOXYLIC ACID
9-HYDROXYFLUOROENE-9-CARBOXYL ACID
FLURENOL
FLURENOL PESTANAL
9-Fluorenol-9-carboxylicacid
9-hydooxy-fluorene-9-carboxylicaci
9-hydroxy-9h-fluorene-9-carboxylicaci
a-Hydroxydiphenyleneaceticacid
flurecol
9-Hydroxy-9-Fluororenecarboxylic Acid
9-hydroxy-fluorene-9-acid
FLURENOL PESTANAL (9-HYDROXYFLUORENE9-CA
9-HYDROXY-9-FLUORENE CARBOXYLI ACID
9-Hydroxy-9-fluorenecarboxylicacid,97%
flurecol (bsi before 1990)
flurenol (bsi,iso)
9-Hydroxy-9H-fluorenecarboxylicacid
9-hydooxy-fluorene-9-carboxylic acid
9-hydroxy-9h-fluorene-9-carboxylic acid
flurenol 9-hydroxy-9H-fluorene-9-carboxylic acid
[EINECS(EC#)]

207-397-1
[Molecular Formula]

C14H10O3
[MDL Number]

MFCD00001137
[Molecular Weight]

226.23
[MOL File]

467-69-6.mol
Chemical PropertiesBack Directory
[Melting point ]

162-166 °C (lit.)
[BRN ]

1314711
[InChI]

1S/C14H10O3/c15-13(16)14(17)11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,17H,(H,15,16)
[InChIKey]

GXAMYUGOODKVRM-UHFFFAOYSA-N
[SMILES]

OC(=O)C1(O)c2ccccc2-c3ccccc13
[CAS DataBase Reference]

467-69-6(CAS DataBase Reference)
[EPA Substance Registry System]

467-69-6(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

N,Xi
[Risk Statements ]

R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S27:Take off immediately all contaminated clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

UN 3082 9/PG 3
[WGK Germany ]

2
[RTECS ]

LL6480000
[TSCA ]

Yes
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29181990
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Aquatic Chronic 2
[Toxicity]

mouse,LD50,oral,> 5gm/kg (5000mg/kg),Pesticide Manual. Vol. 9, Pg. 417, 1991.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Phenanthrenequinone-->ethyl 9-hydroxyfluorene-9-carboxylate-->9H-FLUORENE-9-CARBONYL CHLORIDE,9-CHLORO--->ethyl fluorene-9-carboxylate-->9-Fluorenol-->diethyl fluorene-9,9-dicarboxylate-->methyl 9H-fluorene-9-carboxylate-->FLURENOL-METHYL ESTER-->9-Carboxyfluorene
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

9-Hydroxy-9-fluorenecarboxylic acid(467-69-6).msds
Hazard InformationBack Directory
[Description]

Flurenol is a post-emergence plant growth regulator, often used in conjunction with phenoxy herbicides, to assist in the control of broadleaved weeds. It has a moderate water solubility and a low volatility. It is not usually persistent in soils or waterbodies. Very little data is available for human health but flurenol has a low oral mammalian toxicity. Limited toxicity data is available for biodiversity but data that is available is low to moderate.
[Uses]

9-Hydroxy-9-fluorenecarboxylic acid was used in the synthesis of a hexameric organooxotin prismane.
[Definition]

ChEBI: Flurecol is a member of fluorenes.
[Production Methods]

Flurenol is commercially produced as a plant growth regulator through esterification of fluorene-9-carboxylic acid. The process begins with the synthesis of 9-hydroxyfluorene-9-carboxylic acid, which is then reacted with butanol in the presence of an acid catalyst to form the butyl ester - flurenol. This esterification is typically carried out under reflux conditions in an organic solvent to ensure complete conversion and high yield.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 16, p. 279, 1951 DOI: 10.1021/jo01142a018
[Mechanism of action]

Systemic, synergist, absorbed by leaves and roots. Morphactins PGRs modify growth and development and delay senescence. They work by acting on the position of morphogenesis, which is the process of forming and maintaining the shape of a plant. These compounds inhibit the addition of sieve tubes that are essential for cell division and stem elongation. They are involved in modulating senescence of organs in plants and play a role in plant pathogen resistance.
[Pesticide Type]

Plant Growth Regulator; Herbicide
Spectrum DetailBack Directory
[Spectrum Detail]

9-Hydroxy-9-fluorenecarboxylic acid(467-69-6)1HNMR
9-Hydroxy-9-fluorenecarboxylic acid(467-69-6)IR
9-Hydroxy-9-fluorenecarboxylic acid(467-69-6)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

9-Hydroxy-9-fluorenecarboxylic acid, 97%(467-69-6)
[Sigma Aldrich]

467-69-6(sigmaaldrich)
[TCI AMERICA]

9-Hydroxyfluorene-9-carboxylic Acid,>95.0%(T)(467-69-6)
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