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99-06-9

99-06-9 Structure

99-06-9 Structure
IdentificationMore
[Name]

3-Hydroxybenzoic acid
[CAS]

99-06-9
[Synonyms]

3-HYDROXYBENZOIC ACID
M-HYDROXYBENZOIC ACID
RARECHEM AL BO 0049
3-Carboxyphenol
3-hydroxy-benzoicaci
Acido m-idrossibenzoico
acidom-idrossibenzoico
Benzoic acid, m-hydroxy-
Kyselina 3-hydroxybenzoova
kyselina3-hydroxybenzoova
meta-Hydroxybenzoic acid
m-Hba
m-hydroxy-benzoicaci
m-Salicylic acid
m-salicylicacid
m-Hydroxybenzoic Acid 3-Hydroxybenzoic Acid
m-HydroxybenzoicacidM-HydroxybenzoicAcid
3-Hydroxybenzoicacid,97%
3-Hydroxide benzoic acid
m-Hydroxybenzoic
[EINECS(EC#)]

202-726-5
[Molecular Formula]

C7H6O3
[MDL Number]

MFCD00002506
[Molecular Weight]

138.12
[MOL File]

99-06-9.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powder
[Melting point ]

200-203 °C (lit.)
[mp ]

201 °C
[Boiling point ]

213.5°C (rough estimate)
[density ]

1.4850
[FEMA ]

4431 | 3-HYDROXYBENZOIC ACID
[refractive index ]

1.4600 (estimate)
[Fp ]

220 °C
[storage temp. ]

Store below +30°C.
[form ]

Powder
[pka]

4.06(at 19℃)
[color ]

White to off-white
[PH]

3 (H2O)Aqueous solution
[Water Solubility ]

slightly soluble
[BRN ]

508160
[InChIKey]

IJFXRHURBJZNAO-UHFFFAOYSA-N
[Uses]

Intermediate for plasticizers, resins, light stabiliziers, petroleum additives, pharmaceuticals.
[CAS DataBase Reference]

99-06-9(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzoic acid, 3-hydroxy-(99-06-9)
[EPA Substance Registry System]

99-06-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

3
[RTECS ]

DH1924980
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HS Code ]

29182990
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Sulfuric acid-->Sodium sulfate-->Acetic anhydride-->FUMING SULFURIC ACID-->Oxygen-->m-Cresol-->Benzoic acid-->Mesitylene-->Methyl 3-hydroxybenzoate-->3-Iodobenzoic acid-->3-Benzyloxybenzaldehyde-->Methyl 3-methoxybenzoate-->4-Hydroxybenzoic acid-->3-Carboxyphenylboronic acid-->Shikimic acid-->3-Bromobenzoic acid
【Preparation Products】

Fomesafen-->Acifluorfen-->Lactofen-->3-Methoxybenzoic acid-->3-ACETOXYBENZOIC ACID-->3-Hydroxy-2,4,6-tribromobenzoic acid-->3,5-Dimethylbenzoyl chloride-->3-BUTOXY-4-NITROBENZOIC ACID-->3-BUTOXY-4-NITROBENZOYL CHLORIDE-->3-ALLYLOXY-BENZOIC ACID
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Hydroxybenzoic acid(99-06-9).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powder
[Definition]

ChEBI: A monohydroxybenzoic acid that is benzoic acid substituted by a hydroxy group at position 3. It has been isolated from Taxus baccata.
[Reactions]

m-Hydroxybenzoic Acid, of the three hydroxybenzoic acids, the metaisomer is of least commercial importance. Unlike salicylic acid, m-hydroxybenzoic acid does not undergo the Friedel-Crafts reaction. It can be converted in 80% yield to m-aminophenol by the Schmidt reaction, which involves treating the acid with hydrazoic acid in trichloroethylene in the presence of sulfuric acid at 40 °C.
[Synthesis Reference(s)]

Tetrahedron Letters, 9, p. 3845, 1968 DOI: 10.1016/S0040-4039(01)99116-6
[Purification Methods]

Crystallise the hydroxyacid from absolute EtOH. [Beilstein 10 IV 315.]
Spectrum DetailBack Directory
[Spectrum Detail]

3-Hydroxybenzoic acid(99-06-9) 13C NMR
3-Hydroxybenzoic acid(99-06-9) Raman
3-Hydroxybenzoic acid(99-06-9) IR1
3-Hydroxybenzoic acid(99-06-9) MS
3-Hydroxybenzoic acid(99-06-9) IR2
3-Hydroxybenzoic acid(99-06-9) 1H NMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Hydroxybenzoic acid, 99%(99-06-9)
[Alfa Aesar]

3-Hydroxybenzoic acid, 99%(99-06-9)
[Sigma Aldrich]

99-06-9(sigmaaldrich)
[TCI AMERICA]

3-Hydroxybenzoic Acid,>98.0%(LC)(T)(99-06-9)
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