| Identification | More | [Name]
TRANS-2-METHYL-2-BUTENAL | [CAS]
497-03-0 | [Synonyms]
2-METHYL-2-BUTENAL
FEMA 3407
TIGLALDEHYDE
TIGLIC ALDEHYDE
TIGLINALDEHYDE
TRANS-2,3-DIMETHYLACROLEIN
TRANS-2-METHYL-2-BUTENAL
(2E)-2-Methyl-2-butenal
(E)-2-Methyl-2-butenal
(E)-2-methylbut-2-en-1-al
(E)-2-methylbut-2-enal
2,2-Dimethylacrolein
2-Butenal,2-methyl-,(2E)-
2-Butenal,2-methyl-,(E)-
2-methyl-(E)-2-butenal
2-methyl-,(E)-2-Butenal
2-methyl-2(E)-butenal
2-Methyl-2-butenal, (E)
2-Methyl-2-butenal, trans
2-Methylcrotonaldehyde | [EINECS(EC#)]
207-833-0 | [Molecular Formula]
C5H8O | [MDL Number]
MFCD00006977 | [Molecular Weight]
84.12 | [MOL File]
497-03-0.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colorless to yellow liquid | [Melting point ]
-101.15°C (estimate) | [Boiling point ]
116-119 °C752 mm Hg(lit.)
| [density ]
0.871 g/mL at 25 °C(lit.)
| [FEMA ]
3407 | [refractive index ]
n20/D 1.448(lit.)
| [Fp ]
65 °F
| [storage temp. ]
Flammables area | [solubility ]
soluble in Chloroform | [form ]
Liquid | [color ]
Clear colorless to yellow | [Odor]
at 0.10?%?in?dipropylene glycol. strong green fruit | [biological source]
synthetic | [Water Solubility ]
Soluble in water | [Sensitive ]
Air Sensitive | [JECFA Number]
1201 | [BRN ]
1698207 | [Stability:]
Air sensitive, Light Sensitive | [Major Application]
flavors and fragrances | [InChI]
1S/C5H8O/c1-3-5(2)4-6/h3-4H,1-2H3/b5-3+ | [InChIKey]
ACWQBUSCFPJUPN-HWKANZROSA-N | [SMILES]
C\C=C(/C)C=O | [LogP]
1.065 (est) | [CAS DataBase Reference]
497-03-0(CAS DataBase Reference) | [EPA Substance Registry System]
trans-2-Methylcrotonaldehyde (497-03-0) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS02,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H225-H315-H319-H335 | [Precautionary statements ]
P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
R10:Flammable. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 1989 3/PG 2
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29121990 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Description]
2-Methyl-2-butenal has a penetrating, powerful green ethereal
odor. May be prepared by condensation of acetaldehyde and propionaldehyde. | [Chemical Properties]
clear colorless to yellow liquid | [Uses]
Tiglic aldehyde was used in the concise total synthesis of 7-demethylpiericidin A1. It was used as starting reagent during the synthesis of:
- alkyl-branched tetraene hydrocarbons, pheromone component for dried fruit beetle
- E,E-2,4-dimethyl-2,4-hexa dienal, volatile constituents of the defensive secretions of Leiobunum nigripalpi
- 4-methyl-2,4-hexadiene-1-ol
| [General Description]
trans-2-Methyl-2-butenal is one of the major volatile constituents of coriander and olive oil. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|