ChemicalBook--->CAS DataBase List--->50296-37-2

50296-37-2

50296-37-2 Structure

50296-37-2 Structure
IdentificationMore
[Name]

Bromotris(dimethylamino)phosphonium hexafluorophosphate
[CAS]

50296-37-2
[Synonyms]

BROMOTRIS(DIMETHYLAMINO)PHOSPHONIUM HEXAFLUOROPHOSPHATE
BROP
Bromotris(dimethylamino)phosphoniumHexafluorophos
BROMO-TRIS(DIMETHYLAMINO)PHOSPHONIUM HEXAFLUOROPHOSPHATE (BROP)
BROP BROMOTRIS(DIMETHYLAMINO)PHOSPHONIUM HEXAFLUOROPHOSPHATE
Bromotris(dimethylamino)phosphonium hexafluorophosphate, 98+% (AT)
[Molecular Formula]

C6H18BrF6N3P2
[MDL Number]

MFCD00191864
[Molecular Weight]

388.07
[MOL File]

50296-37-2.mol
Chemical PropertiesBack Directory
[Melting point ]

>300 °C(lit.)
[storage temp. ]

Keep in dark place,Inert atmosphere,Room temperature
[form ]

powder to crystal
[color ]

White to Almost white
[Sensitive ]

Light Sensitive
[Major Application]

peptide synthesis
[InChI]

InChI=1S/C6H18BrN3P.F6P/c1-8(2)11(7,9(3)4)10(5)6;1-7(2,3,4,5)6/h1-6H3;/q+1;-1
[InChIKey]

XELPBWPBGHCIKX-UHFFFAOYSA-N
[SMILES]

[P-](F)(F)(F)(F)(F)F.[P+](Br)(N(C)C)(N(C)C)N(C)C
[CAS DataBase Reference]

50296-37-2(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

T
[Risk Statements ]

R45:May cause cancer.
R34:Causes burns.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3263 8/PG 2
[WGK Germany ]

3
[F ]

10-21
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29299090
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Carc. 1B
Skin Corr. 1B
Hazard InformationBack Directory
[Chemical Properties]

White to off-white powder
[Uses]

Reagent for:
Conjugate addition of nitroalkanes to an acrylate equivalent
A novel polymer supported approach to nucleoside modification
Asymmetric hydrogenations
Peptide coupling
Pyrrolidine hydroxylation
Synthesis of cyclic PNA-based compound directed against HIV-1 TAR RNA
[reaction suitability]

reaction type: Coupling Reactions
Spectrum DetailBack Directory
[Spectrum Detail]

Bromotris(dimethylamino)phosphonium hexafluorophosphate(50296-37-2)1HNMR
Bromotris(dimethylamino)phosphonium hexafluorophosphate(50296-37-2)IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bromotris(dimethylamino)phosphonium hexafluorophosphate, 98+%(50296-37-2)
[Sigma Aldrich]

50296-37-2(sigmaaldrich)
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