| Identification | More | [Name]
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE | [CAS]
50525-27-4 | [Synonyms]
2,2'-BIPYRIDINE RUTHENOUS DICHLORIDE HEXAHYDRATE
DICHLOROTRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) HEXAHYDRATE
RUTHENIUM-TRIS(2,2'-BIPYRIDYL) DICHLORIDE HEXAHYDRATE
TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) CHLORIDE
TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II) DICHLORIDE HEXAHYDRATE
TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II) HEXAHYDRATE
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(2) CHLORIDE HEXAHYDRATE
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE HEXAHYDRATE
tris(2,2’-bipyridine-n,n’)-,dichloride,hexahydrate,(oc-6-11)-ruthenium(2+
tris(2,2’-bipyridyl)ruthenium
tris(2,2’-bipyridyl)rutheniumchloridehexahydrate
tris(bipyridine)ruthenium(ii)chloridehexahydrate
Ruthenium-tris(2,2′-bipyridyl) dichloride
Tris(2,2′-bipyridine)dichlororuthenium(II) hexahydrate
Tris(2,2'-bipyridine)ruthenium(II) chloride hexahydrate
TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II)HEXAHYDRATE, POWDER
TRIS(2,2'-BIPYRIDYL)DICHLORORUTHENIUM(II) HEXAHYDRATE, 99.95%
TRIS(2,2-BIPYRIDYL)RUTHENIUM (II) CHLORIDE HEXAHYDRATE 98+%
TRIS(2,2'-BIPYRIDYL)RUTHENIUM(II) CHLORIDE 6-HYDRATE
Tris(2,2'-bipyridyl)ruthenium(II)chloridehexahydrate,min.98% | [EINECS(EC#)]
238-266-7 | [Molecular Formula]
C30H36Cl2N6O6Ru | [MDL Number]
MFCD00149670 | [Molecular Weight]
748.62 | [MOL File]
50525-27-4.mol |
| Chemical Properties | Back Directory | [Appearance]
red to orange powder or crystals | [Melting point ]
>300 °C(lit.)
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
DMSO (Slightly), Methanol (Slightly) | [form ]
powder
| [color ]
Red-orange to red | [Stability:]
Stable, but may discolour upon exposure to light. Incompatible with strong oxidizing agents. | [Water Solubility ]
Soluble in water. | [InChI]
InChI=1S/3C10H8N2.ClH.H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;/h3*1-8H;1H;1H2;/q;;;;;+2/p-1 | [InChIKey]
VCIOOYXESNFDKX-UHFFFAOYSA-M | [SMILES]
[Ru+2]123(N4=CC=CC=C4C4=CC=CC=N14)(N1=CC=CC=C1C1=CC=CC=N21)N1=CC=CC=C1C1=CC=CC=N31.[Cl-].O | [CAS DataBase Reference]
50525-27-4(CAS DataBase Reference) | [Storage Precautions]
Light sensitive;Store under inert gas |
| Safety Data | Back Directory | [Risk Statements ]
36/38 | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [RTECS ]
VM2730000
| [F ]
8-10 | [TSCA ]
Yes | [HS Code ]
28439000 | [Storage Class]
11 - Combustible Solids |
| Questions And Answer | Back Directory | [Uses]
Tris (2,2’-bipyridyl) dichlororuthenium hexahydrate (RTDP, Ru (BPY) 3) is an oxygen-sensitive fluorescent stain. It can be used to measure the oxygen concentration of microfluidic chips.
Tris(2,2'-bipyridine)dichlororuthenium(II) hexahydrate is a catalyst used in light-induced redox reactions, and is an important catalyst in studies towards photochemical water splitting. This product is widely applied in fields of photoelectrical chemical components, photovoltaic cells, smart biosensors.
|
| Hazard Information | Back Directory | [Chemical Properties]
red to orange powder or crystals | [General Description]
Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate is a metal complex and is used as an luminescent dye. The metal complex in its ground state can be excited by visible light which leads to the formation of a spin-allowed excited state. This excited state undergoes radiationless deactivation very quickly to form spin-forbidden, long-lived luminescent excited state. It is used widely in electroluminescent devices. | [reaction suitability]
core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst | [Synthesis]
Dried RuCl3 (200 mg, 0.964 mmol) and 2,2′-bipyridine (452 mg, 2.89 mmol) were dissolved in H2O (20 mL). Saturated naapo2h2 (2 ml) was added to the mixture. The resulting mixture was heated to reflux for 30 min. The reaction mixture was filtered. Potassium | [Purification Methods]
Recrystallise it from water, then from MeOH [Ikezawa et al. J Am Chem Soc 108 1589 1986]. |
|
|