ChemicalBook--->CAS DataBase List--->14284-92-5

14284-92-5

14284-92-5 Structure

14284-92-5 Structure
IdentificationBack Directory
[Name]

Rhodium(III) 2,4-pentanedionate
[CAS]

14284-92-5
[Synonyms]

Rhodium(III) 2,4-pen
Rhodiumpentanedionate
Rhodium acetylacetonate
Rhodium(Ⅲ) acetylacetonate
RHODIUM(III)PENTANEDIONATE
rhodium 2,4-pentanedionate
RHODIUM(LLL) ACETYLACETONATE
diuM(III) 2,4-pentanedionate
Tris(acetylacetonato)rhodium
RHODIUM(III) ACETYLACETONATE
Rhodium tris(acetylacetonate)
Tris(2,4-pentanedionato)rhodium
Rhodiumacetylacetonateyellowxtl
RHODIUM(III) 2,4-PENTANEDIONATE
RhodiuM(III) acetylacetonate 97%
Rhodium(III) acetylacetonate,97%
Rhodium(III) acetylacetonateTIPOF
Tris(acetylacetonate)RhodiuM(III)
TRIS(ACETYLACETONATO)RHODIUM (III)
Rhodium, tris(2,4-pentanedionato)-
Tris(2,4-pentanedionato-O,O')-rhodium
tris(pentane-2,4-dionato-O,O')rhodium
Premion99.99%(metalsbasis),Rh25.2%min
RHODIUM(III) ACETYLACETONATE (25% RH)
rhodium(iii) 2,4-pentanedionate, premion
2,4-PENTANEDIONE, RHODIUM(III) DERIVATIVE
Rhodium(III)acetylacetonate,97+%(99.9%-Rh)
4-pentanedionato-o,o’)-tris((oc-6-11)-rhodiu
RhodiuM(III) acetylacetonate,98% Rh(CH3COCHCOCH3)3
Rhodium, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-
2,4-Pentanedione rhodium(III) derivative, Rh(acac)3
Rhodium(III) acetylacetonate, 99.99% trace metals basis
Rhodium(III)acetylacetonate or Rhodium(III)2,4-pentanedionate
tris-(2,4 Pentanedionate) RhodiuM (III) [hodiuM Acetylacetonate
Tris(acetylacetonato)rhodium(III) dec. 260 Sublm. 240/0.1 mm
tris-(2,4 Pentanedionate) RhodiuM (III) [“RhodiuM Acetylacetonate”]
Rhodium(Iii) 2,4-Pentanedionate, Premion (Metals Basis), Rh 25.2% Min
Rhodium(III) 2,4-pentanedionate, Premion, 99.99% (metals basis), Rh 25.2% min
Rhodium(III) 2,4-pentanedionate, Premion(R), 99.99% (metals basis), Rh 25.2% min
Rhodium(III) acetylacetonate,2,4-Pentanedione rhodium(III) derivative, Rh(acac)3
[EINECS(EC#)]

238-192-5
[Molecular Formula]

C15H21O6Rh
[MDL Number]

MFCD00083144
[MOL File]

14284-92-5.mol
[Molecular Weight]

400.23
Chemical PropertiesBack Directory
[Appearance]

Yellow/Orange Crystals
[Melting point ]

263-264 °C(lit.)
[Boiling point ]

>280°C
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Powder
[color ]

Yellow to yellow-orange
[Specific Gravity]

1.607
[Water Solubility ]

insoluble
[Exposure limits]

ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
[InChI]

InChI=1S/3C5H8O2.Rh/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3+;
[InChIKey]

DGOINFUDFBWCMX-MUCWUPSWSA-K
[SMILES]

[Rh](O/C(/C)=C/C(=O)C)(O/C(/C)=C/C(=O)C)O/C(/C)=C/C(=O)C
[CAS DataBase Reference]

14284-92-5
[NIST Chemistry Reference]

Rhodium, tris(2,4-pentanedionato-o,o')-(14284-92-5)
[EPA Substance Registry System]

Rhodium, tris(2,4-pentanedionato-.kappa. O,.kappa.O')-, (OC-6-11)-(14284-92-5)
Hazard InformationBack Directory
[Chemical Properties]

Yellow/Orange Crystals
[Uses]

Rhodium(III) 2,4-pentanedionate is used in catalytic reagents for organic synthesis. Rhodium(III) 2,4-pentanedionate is useful for hydrosilylation of a variety of organic substrates like alkenes, terminal or internal acetylenes, conjugated dienes, alpha, beta -unsaturated aldehydes and allylic compounds. It performs the role of a catalyst in well-known reactions such as transformation processes including hydrogenation, ethanol steam reforming, CO oxidation, and NOx reduction. Rhodium acetylacetonate, as the organic solvent-soluble source of rhodium metal ions, can be used to prepare monodisperse size/shape controlled Rh nanocrystals. Rh nanocrystal monolayers have been reported to show high activity for hydrogenation of vinylcyclohexene to selectively produce ethylcyclohexene. The size/shape controlled nanocrystals find a variety of applications in oil refining processes, chemical synthesis and fuel cell technology.
[reaction suitability]

reagent type: catalyst
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H302+H312+H332-H315-H319-H335-H361
[Precautionary statements ]

P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338-P308+P313
[Hazard Codes ]

Xn
[Risk Statements ]

20/21/22-36/37/38-40-63
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
[TSCA ]

Yes
[HS Code ]

28439000
Spectrum DetailBack Directory
[Spectrum Detail]

Rhodium(III) 2,4-pentanedionate(14284-92-5)FT-IR
Rhodium(III) 2,4-pentanedionate(14284-92-5)IR
Rhodium(III) 2,4-pentanedionate(14284-92-5)Raman
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