| Identification | More | [Name]
[1,3-Bis(diphenylphosphino)propane]nickel(II) chloride | [CAS]
15629-92-2 | [Synonyms]
1,3-BIS(DIPHENYLPHOSPHINE)PROPANE NICKEL(II) CHLORIDE
[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]DICHLORONICKEL(II)
1,3-BIS(DIPHENYLPHOSPHINO)PROPANE NICKEL (II) CHLORIDE
[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]NICKEL(II) DICHLORIDE
DICHLORO[1,3-BIS(DIPHENYLPHOSPHINO)PROPANE]NICKEL(II)
(1,3-Bis[Diphenylphosphino]Propane)Dichloronickel
Dichloro[bis(1,3-diphenylphosphino)propane]nickel(II)
1,3-BIS-(DIPHENYLPHOSPHINO)-PROPAN-
1,3-Bis(dipenylphosphino)propanenickel(II) chloride
Dichloro[1,3-Bis-(Diphenylphos
1,3-Bis(diphenylphosphino)propanenickel(II)chloride,99%
1.3-Bis(dipheny phosphine) propane nickel(II)chloride
DICHLORO[1,3-BIS-(DIPHENYLPHOSPHINO)PROPANE] NICKE
NICL2(DPPP)/ 1,3-BIS(DIPHENY PHOSPHINE) PROPANE NICKEL(II)CHLORIDE
NiCl2(DPPP)NiCl2(DPPP)
1,3-Bis-(diphenylphosphino)-propane nickel chloride
1,3-Bis(diphenyl phosphine)propane nickel(II)dichloride
Dichlorobis(1,3-diphenylphosphino)propaneünickel(II), C 59.9%
(1,3-dppp)NiCl2, 1,3-Bis(diphenylphosphino)propane nickel(II) chloride | [EINECS(EC#)]
605-052-3 | [Molecular Formula]
C27H26Cl2NiP2 | [MDL Number]
MFCD00015318 | [Molecular Weight]
542.04 | [MOL File]
15629-92-2.mol |
| Chemical Properties | Back Directory | [Appearance]
red to red-brown powder or crystals | [Melting point ]
213 °C (dec.)(lit.)
| [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
crystal | [color ]
red | [Water Solubility ]
insoluble | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [Detection Methods]
Elemental Analysis | [Exposure limits]
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 | [InChI]
InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2 | [InChIKey]
ZBQUMMFUJLOTQC-UHFFFAOYSA-L | [SMILES]
P(C1=CC=CC=C1)(CCCP(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[Ni](Cl)Cl | [CAS DataBase Reference]
15629-92-2(CAS DataBase Reference) | [Storage Precautions]
Moisture sensitive |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS07,GHS08 | [Signal word ]
Danger | [Hazard statements ]
H315-H317-H319-H334-H335-H350 | [Precautionary statements ]
P201-P280-P302+P352-P305+P351+P338-P308+P313 | [Hazard Codes ]
T,Xn | [Risk Statements ]
R49:May cause cancer by inhalation.
R36/37/38:Irritating to eyes, respiratory system and skin .
R42/43:May cause sensitization by inhalation and skin contact .
R40:Limited evidence of a carcinogenic effect. | [Safety Statements ]
S53:Avoid exposure-obtain special instruction before use .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S24:Avoid contact with skin .
S22:Do not breathe dust . | [RIDADR ]
3282 | [WGK Germany ]
3
| [F ]
10-21 | [TSCA ]
No | [HS Code ]
29319099 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Carc. 1A
Eye Irrit. 2
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
red to red-brown powder or crystals | [Uses]
suzuki reaction | [Application]
Catalyst for:
Synthesis of block-copolythiophenes
Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acids
Solid state metathesis polycondensation
Polymerization of poly(3-alkoxythiophene)s
Diastereoselective Nozaki-Hiyama-Kishi coupling reactions of C1-C19 fragment of macrolide antibiotic aplyronine A
Transfer condensation polymerization of conjugated polymers
[1,3-Bis(diphenylphosphino)propane]dichloronickel(II) can be used as a precursor to synthesize metal-fullerene coordination complexes by reduction method. | [reaction suitability]
core: nickel
reaction type: Cross Couplings
reagent type: catalyst |
| Questions And Answer | Back Directory | [Reaction]
- Nickel catalyst used in the N-heterocycle-directed cross-coupling of fluorinated arenes with organozinc reagents.
- Nickel catalyst used in the (E)-selective semihydrogenation of internal alkynes.
- Nickel catalyst used in the borylation of halides and pseudohalides.
|
|
|